Effect of Varying Potassium Iodide.—An excess of iodide is always required to keep the iodine in solution; a larger excess has little effect.

Iodide added1 gram20 grams
"Hypo" required20.4 c.c.20.5 c.c.20.6 c.c.

The 20 c.c. of iodine used, itself contained 0.5 gram of potassium iodide.

Effect of Foreign Salts.

Bicarbonate of soda added0.5 gram1.5 gram5.0 grams
"Hypo" required20.4 c.c.18.2 c.c.17.1 c.c.16.0 c.c.

The solution obviously must be free from bicarbonate of soda. This should be remembered, since when titrating arsenic assays with iodine it must be present; and students must avoid confounding the two titrations.

In some other experiments, in which 10 grams each of the salts were taken, the following results were obtained:—

Salt addedAmClAmNO3Am2SO4
"Hypo" required20.4 c.c.20.5 c.c.20.3 c.c.20.2 c.c.
Salt addedNaClNaNO3Na2SO4
"Hypo" required20.3 c.c.20.4 c.c.20.4 c.c.

Effect of Varying Iodine.