Nitrobenzol is frequently adulterated with spirit of wine, which is recognized by shaking the oil with fat oil of almonds; in the presence of spirit of wine a turbid mixture is formed. By shaking nitrobenzol containing spirit of wine with an equal volume of water in a graduated cylinder, its volume decreases.
Oil of mirbane is much used for perfuming soaps, but even the finest quality of it cannot replace oil of bitter almonds for fine soaps and perfumery. Great care has to be exercised in storing, as well as in working, nitrobenzol, it igniting very readily, and it is also poisonous. Even the vapors, when inhaled for some time, may produce symptoms of poisoning, which consist in the skin acquiring a leaden color, and heavy feelings in the limbs with cold extremities, especially the hands and feet.
Fruit Ethers. At the London Exhibition, in 1851, various products called apple oil, pear oil, pine-apple oil, etc., were shown. They were examined by A. W. Hofmann, and found to consist of solutions of certain ethers in alcohol. Since then the manufacture has greatly increased and large quantities are now brought into commerce under the name of fruit ethers or fruit essences.
Fruit ethers are fluids possessing an agreeable, refreshing odor closely resembling that of some fruits. For this reason they are used in confectionery, in the manufacture of liqueurs and also as a substitute for volatile oils, in the manufacture of perfumery. Chemically, fruit ethers are combinations of an organic acid—acetic, butyric, valerianic, etc.—with a so-called alcohol radicle, such as ethyl and amyl. The preparation of fruit ethers being connected with many difficulties, is seldom attempted by perfumers, especially as products of an excellent quality can at a low rate be procured from chemical laboratories making a specialty of their manufacture. However, for the sake of completeness, a brief description of the fabrication of the principal ethers used in their preparation shall here be given.
Acetic amyl ether or amyl acetate, C5H11O.C2H3O, is prepared by mixing 1 part of amyl alcohol with 1 part of concentrated sulphuric acid, and distilling the mixture with 2 parts of potassium acetate. The distillate is washed with water, to which some carbonate of soda has been added, and then rectified over magnesia. It forms a colorless liquid of an agreeable fruity odor. It boils, according to Kopp, at 280° F. and, at 59° F., its specific gravity is 0.8692.
For use in perfumery, the ether is best prepared, according to Fehling's directions, by heating for some time at a temperature of 212° F. 1 part of glacial acetic acid with ½ part of sulphuric acid and one part of amyl alcohol. By then adding water the ether is separated. By this process distillation is avoided.
Acetic ethyl ether or ethyl acetate, C2H3O.O.C2H5. Acetic ether is formed by the decomposition of sodium acetate by ethyl sulphuric acid:—
| SO2 | ┌OC2H5 └OH | + | C2H3O.ONa | = |
| Ethyl sulphuric acid. | Sodium acetate. | |||
| SO2 | ┌ONa └OH | + | C2H3O.OC2H5 | |
| Acid sodium sulphate. | Acetic ether. | |||