A process has lately been invented (English patent, No. 11,333, 1884), by Prof. Lunge, which involves the use of acetic acid. The quantity required is, however, very small, as during the process of bleaching it becomes regenerated. The free lime in the bleaching powder solution should first be {115} nearly neutralised with a cheaper acid, such as hydrochloric or sulphuric, followed then by the addition of the acetic acid. This process, we are informed, gives excellent results with high-class material, such as the best cotton and linen rags; it is, however, not to be recommended for such materials as straw or esparto.
For the bleaching of rags the process invented by Thompson (English patent, No. 595, 1883) has proved very effective. The method consists in saturating the material with a weak solution of bleaching powder, and then exposing them to the action of carbonic acid gas. In this way the bleaching action is made very rapid and effective.
Electrolytic Bleaching.
The electrolysing vat consists of a rectangular vessel of slate or other suitable material. The negative electrode may be constructed of zinc; for the positive it is necessary to employ platinum.
The electrolysed solution has been found to possess very remarkable properties, which have considerable bearing upon the economy of the process. If a solution be taken of equal {116} oxidising efficiency with one of calcium hypochlorite, as indicated by the arsenious acid test (see p. [206]), it is found that the former possesses greater bleaching efficiency than the latter in the proportion of 5 to 3. Moreover, the bleaching is much more rapid, and the loss of weight which the substances undergo is less, for equal degrees of whiteness obtained.
It has been shown that by the electrolytic method the bleaching of paper pulp can be effected at nearly one-half the cost of bleaching powder. The process is now being industrially carried out. Those interested in the subject are referred to a paper by the authors in the ‘Journal of the Society of Chemical Industry’ for April 1887.
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CHAPTER VIII. BEATING.
The bleached pulp is now ready for the final treatment. If it were attempted to make paper from the pulp in the state in which it leaves the “potchers” or “steeping” chests, it would be found to be wanting in evenness of texture and uniformity of surface. This result can only be secured by an elaborate process of comminution or disintegration. This is in effect the result produced by the action of the “beaters.”
They resemble in general appearance the breaking engines previously described; the roll, however, carries more knives, and it is usually let down much nearer to the bed-plate. In the case of fibrous substances, whose ultimate fibres are relatively short (see table, p. [39]), it is only necessary to split up the filaments into their constituent fibres: esparto, straw, and wood are of this class. In the case of straw, the disintegration is for the most part accomplished in the boiling and bleaching processes, and therefore but little work devolves upon the beater. Esparto and wood require a certain amount of beating, but this should be regulated to the drawing asunder of the individual fibres, any cutting of the fibres being carefully avoided. This is accomplished by adjusting the distance of the roll from the bed-plate, so that by the friction of the fibres upon themselves, when passing over the plate, a kind of rubbing or “brushing” is produced. If a carefully-made paper of esparto or wood be examined by the microscope, it will be found that the majority of the fibres preserve the pointed or slightly rounded ends {118} characteristic of bast cells. On the other hand, it is obvious that cotton, whose ultimate fibres have a length of 20 to 40 mm., and flax (25–30 mm.), with other similar fibres, will require to be broken up into short fragments in order to develop to the fullest the felting property of the pulp. Not only are the fibres reduced to the most favourable dimensions, but in cotton and linen a further contributory advantage accrues; for on account of the internal structure of the ultimate fibres they tend to split up at the point of rupture into a number of fibrillæ, which, in the case of cotton, take the form of a network; and in case of linen, are seen as a bundle of distinct fibres parallel to and continuous with the fibre. This gives to ends of the fragments a ragged contour, which has considerable influence on the felting power of the pulp, and therefore on the strength of the paper into which it is made.