Caustic
soda.
+
CaO.
Lime.
At the particular degree of dilution which occurs in a beater, the bleach is decomposed almost entirely according to the first of the equations; from which, on calculating, it will be seen that 158 parts of sodium thiosulphate are equivalent to 286 parts of calcium hypochlorite. As commercial sodium thiosulphate contains 36·3 per cent. of water, and bleaching powder 70 per cent. of calcium hypochlorite, on the basis of 35 per cent. available chlorine it follows that 248 parts of the former are required to neutralize 409 parts of the latter.
Within the last few years other forms of “antichlor” have been introduced, such, for example, as the various sulphites. The most important of these is sodium sulphite, which has been manufactured by a patent process at a cheap rate, by Gaskell, Deacon, & Co., Widnes. Their product contained as much as 75 per cent. of Na2SO3, ordinary crystallized sodium sulphite containing only 50 per cent.
Sulphites are converted by the action of bleach into sulphates, thus:—
Ca(OCl)2
Calcium
hypochlorite.
+