I suspended some ortho toluidine sulphonic acid in denatured alcohol, and passed in a rapid current of nitrous fumes, generated by dropping concentrated nitric acid into a saturated solution of sodium nitrite, for fifteen minutes. The suspension became slightly warm, and rather pasty at the end. I allowed it to stand a half hour, and at the end of that time it had become very thick and pasty. I then filtered it off by suction, washed with ether, and dried.
Experiment 2.
The procedure used was the same as above using ethyl alcohol in place of denatured alcohol, but for some reason no diazotization appeared to take place. The acid was filtered off and used again.
Experiment 3.
A saturated water solution of the acid was made by boiling some of it up with water, cooling and filtering. No precipitate appeared on passing in nitrous fumes.
Experiment 4.
Some of the acid was dissolved in sodium carbonate solution, sodium nitrite solution added, and after cooling, concentrated hydrochloric acid added drop by drop. Nitrous fumes were given off, but no precipitate appeared.
Experiment 5.
This seems to be the best method and the one employed hereafter in the preparation of all the material subsequently used. The solid ortho toluidine sulphonic acid is suspended in concentrated hydrochloric acid and vigorously stirred. The solution becomes warm and the crystals change in appearance, probably due to the formation of the hydrochloride. The mass is then cooled to 5°, and sodium nitrite solution added slowly with stirring. Immediate reaction takes place, and the mass becomes very pasty as in the first experiment. After obtaining a reaction with starch iodide paper the mixture was allowed to stand a half hour, then filtered by suction, washed with ether and dried. In appearance it was identical with the diazo compound obtained in experiment 1, and can be kept in the same way.
That it was a diazo compound was shown as follows: It was spotted on a piece of filter paper with an alkaline solution of H acid—a red coloration indicates the formation of a red azo dyestuff.