The United States is independent of foreign sources for bromine. The entire domestic tonnage is produced from brines pumped in Michigan, Ohio, West Virginia, and Pennsylvania. A large part of the output is not actually marketed as bromine, but in the form of potassium and sodium bromides and other salts. During the war considerable quantities of bromine materials were exported to Great Britain, France, and Italy.
Geologic Features
Bromine is very similar chemically to chlorine, and is found under much the same conditions, though usually in smaller quantities. The natural silver bromide (bromyrite) and the combined silver chloride and bromide (embolite) are fairly common in the oxide zones of silver ores, but are not commercial sources of bromine.
Bromine occurs in sea water in appreciable amounts, as well as in some spring waters and many natural brines. When natural salt waters evaporate, bromine is one of the last materials to be precipitated, and the residual "mother liquors" or bitterns frequently show a considerable concentration of the bromine. Where complete evaporation takes place, as in the case of the Stassfurt salt deposits (p. 113), the bromine salts are crystallized out in the final stages along with the salts of sodium, magnesium, and potassium. The larger part of the world's bromine has come from the mother liquor resulting from the solution and fractional evaporation of these Stassfurt salts.
The bromine obtained from salt deposits in the eastern United States is doubtless of a similar origin. It is produced as a by-product of the salt industry, the natural or artificial brines being pumped from the rocks (p. 295), and the bromides being extracted either from the mother liquors or directly from the unconcentrated brines.
FULLER'S EARTH
Economic Features
Fuller's earth is used chiefly for bleaching, clarifying, or filtering mineral and vegetable oils, fats, and greases. The petroleum industry is the largest consumer. Minor uses are in the manufacture of pigments for printing wall papers, in detecting coloring matters in certain food-products, and as a substitute for talcum powder.
Fuller's earths are in general rather widely distributed. The principal producers are the United States, England, and the other large consuming countries of Europe. The only important international trade in this commodity consists of exports from the United States to various countries for treating mineral oils, and exports from England for treating vegetable oils.
There is a large surplus production in the United States of fuller's earth of a grade suitable for refining mineral oils, but an inadequate production of material for use in refining edible oils, at least by methods and equipment now in most general use. However, the imports needed from England are more than offset by our exports to Europe of domestic earth particularly adapted to the petroleum industry. Production in the United States comes almost entirely from the southern states; Florida produces over three-fourths of the total and other considerable producers are Texas, Georgia, California, and Arkansas. Imports from England are normally equivalent to about a third of the domestic production.