In all of these cases, it is clear that the origin of the ores is in some way related to igneous processes, and presumably most of the ores are deposited from the primary hot solutions accompanying and following the intrusion of the igneous rocks; but thus far it has been difficult to find definite and positive evidence as to the precise processes involved. None of these deposits have undergone any important secondary enrichment at the surface. Their sizes, shapes, and distribution are governed by conditions of igneous intrusion, more or less modified, as in the Adirondacks, by later deformation.
Iron ores due to weathering of igneous rocks. A small part of the world's iron ores, less than 1 per cent of the total production, are the result of surface alteration of serpentine rocks. These ores are mined principally in Cuba (Fig. 12). Here they have been developed on a plateau-like area on which erosion is sluggish. The process of formation has been one of oxidation of the iron minerals and leaching of most of the other constituents, leaving the iron concentrated near the surface in blanket-like deposits. The minerals of the original rock contained alumina, which, like the iron, is insoluble under weathering conditions, and hence the Cuban iron ores are high in alumina. They also contain small quantities of nickel and chromium which have been concentrated with the iron. A large part of the iron minerals, especially where close to the surface, have been gathered into small shot-like nodules called pisolites. It is thought that the solution and redeposition of the iron by organic acids from plant roots may be at least a contributing cause in the formation of this pisolitic texture.
Fig. 12. Representing in terms of weight the mineralogical changes in the katamorphism of serpentine rock to iron ore, on the assumption that alumina has remained constant, eastern Cuba.[ToList]
The Cuban iron ores are similar in their origin to laterites, which are surface accumulations of clay, bauxite, and iron oxide minerals, resulting from the weathering of iron-bearing, commonly igneous, rocks. The typical laterites carry more clay and bauxite than the Cuban iron ores, but this is due merely to the fact that the original rocks commonly carry more materials which weather to clay. In fact the Cuban iron ores are themselves, broadly speaking, laterites.
Iron ores due to weathering of sulphide ores. A relatively minute portion of the world's iron ore comes from the "gossans" or "iron caps" over deposits of iron sulphides. The gossans are formed by oxidation and leaching of other minerals from the deposits, leaving limonite or hematite in concentrated masses (see pp. 46-47).
MANGANESE ORES
Economic Features
Manganese ores are used mainly in the manufacture of steel, the alloys spiegeleisen and ferromanganese being added to the molten steel after treatment in the Bessemer converter and open-hearth furnace in order to recarburize and purify the metal. The alloy ferromanganese is also used in the production of special manganese steels. Manganese ore is used in relatively small amounts in dry batteries, in the manufacture of manganese chemicals, in glass making, and in pigments. Steel uses 95 per cent of the total manganese consumed, batteries and chemicals 5 per cent. On an average each ton of steel in the United States requires 14 pounds of metallic manganese, equivalent to 40 pounds of manganese ore.