Why are lemons sour?

How do acids act?

Some acids are very powerful. There is one, called hydrofluoric acid, that will eat through glass and has to be kept in wax bottles; and all acids tend to eat or corrode metals. You saw what hydrochloric acid did to the zinc shavings when you wanted to make a balloon; or, to be more accurate, you saw what the zinc shavings did to the acid, for the hydrogen gas that bubbled off was driven out of the acid by the zinc. Then the zinc combined with the rest of the acid to form what chemists call a salt.

If we were to let the soft metal, sodium, act on hydrochloric acid, we should get hydrogen also; but the salt that formed would be regular table salt (NaCl). You cannot do this experiment, however, as the sodium does its work so violently that it is dangerous.

Experiment 105. To be done by the teacher before the class. If acid spatters on any one's skin or clothes, wash it of immediately with ammonia or a strong soda solution.

Fig. 182. Etching copper with acid.

Drop a little candle grease on a piece of copper about 3/4 inch wide and 2 or 3 inches long. In the flame of a Bunsen burner, gently heat the end of the copper that has the candle grease (paraffin) on it, so that the paraffin will spread out all over the end. Let it harden. With a nail, draw a design in the paraffin on the copper, scratching through the thin coat of paraffin to the copper below. Pour a couple of drops of concentrated nitric acid on the paraffin-covered end of the piece of copper, and spread the acid with a match so that it can get down into the scratches. Let it stand by an open window for 5 or 10 minutes. Do not inhale the brown fumes that are given off. They are harmless in small amounts, but if breathed directly they are very irritating. Now wash off the acid by holding the copper under the hydrant, and scrape off the paraffin.

The nitric acid did to the copper in this experiment exactly what the hydrochloric acid did to the zinc shavings when you made the toy balloon. The copper drove the hydrogen out of the nitric acid and incidentally broke down some of the nitric acid to make the brown gas, and then the copper joined the rest of the nitric acid to make a salt called copper nitrate. This salt is green, and it dissolves in water. When you washed the copper, the green salt was washed away and a dent remained in the copper where the copper salt had been.

Here is a more practical experiment showing the action of acid on metal: