A close correspondence between the percentage compositions of the stellar atmosphere and the crust of the earth would not, perhaps, be expected, since both sources form a negligible fraction of the body of which they are a part. There is every reason to suppose, on observational and theoretical grounds, that the composition of the earth varies with depth below the surface; and the theory of thermodynamical equilibrium would appear to lead to the result that the heavier atoms should, on the average, gravitate to the center of a star. If, however, the earth originated from the surface layers of the sun,[484] the percentage composition of the whole earth should resemble the composition of the solar (and therefore of a typical stellar) atmosphere. But the mass of the earth alone is considerably in excess of the mass of the reversing layer of the sun.[485] Eddington,[486] quoting von Zeipel,[487] has pointed out that an effect of rotation of a star will be to keep the constituents well mixed, so that the outer portions of the sun or of a star are probably fairly representative of the interior. Considering the possibility of atomic segregation both in the earth and in the star, it appears likely that the earth’s crust is representative of the stellar atmosphere.
The most obvious conclusion that can be drawn from [Table XXVIII] is that all the commoner elements found terrestrially, which could also, for spectroscopic reasons, be looked for in the stellar atmosphere, are actually observed in the stars. The twenty-four elements that are commonest in the crust of the earth,[488] in order of atomic abundance, are oxygen, silicon, hydrogen, aluminum, sodium, calcium, iron, magnesium, potassium, titanium, carbon, chlorine, phosphorus, sulphur, nitrogen, manganese, fluorine, chromium, vanadium, lithium, barium, zirconium, nickel, and strontium.
The most abundant elements found in stellar atmospheres, also in order of abundance, are silicon, sodium, magnesium, aluminum, carbon, calcium, iron, zinc, titanium, manganese, chromium, potassium, vanadium, strontium, barium, (hydrogen, and helium). All the atoms for which quantitative estimates have been made are included in this list. Although hydrogen and helium are manifestly very abundant in stellar atmospheres, the actual values derived from the estimates of marginal appearance are regarded as spurious.
The absence from the stellar list of eight terrestrially abundant elements can be fully accounted for. The substances in question are oxygen, chlorine, phosphorus, sulphur, nitrogen, fluorine, zirconium, and nickel, and none of these elements gives lines of known series relations in the region ordinarily photographed.
The
“triplets” of neutral oxygen, in the red, should prove accessible in the near future; the point of disappearance of these lines would not be difficult to estimate, and they would furnish a value for the stellar abundance of oxygen. The lines of ionized oxygen, which have not yet been analyzed into series, are conspicuous in the
stars,[489] and the element is probably present in large quantities.
Sulphur and nitrogen both lack suitable lines in the region usually studied; the analyzed spectrum of neutral sulphur is in the green and red,[490] or in the far ultra-violet,[491] and the neutral nitrogen spectrum has not as yet been arranged in series. Both sulphur and nitrogen appear, in hotter stars, in the once and twice ionized conditions,[492] and are probably abundant elements in stellar atmospheres.