, is effectively much larger than one which is giving rise to
. As was early suggested by Bohr,[81] the production of the higher members of the series must depend upon the possibility of existence of the corresponding outer orbits. As a preliminary assumption it appears probable that the existence of the larger orbits will depend on the proximity of neighboring atoms, and hence on the pressure.
The theoretical questions involved are very complex, and the present discussion is merely tentative. When the idea that the maximum number of lines that could be produced was a function of the pressure was first set forth, the available laboratory evidence appeared all to be in its favor. The maximum number of Balmer lines that had been produced in the vacuum tube was five, while it was well known that over twenty could be traced in absorption in some stellar atmospheres. Since that time, however, the work of R. W. Wood[82] has produced forty-seven lines of the Balmer absorption series of sodium in the laboratory at considerable pressures, and evidently the simple theory, relying on the mutual distances of the atoms to determine the number of lines that can be produced, cannot be applied in this case. The matter has been discussed by Franck,[83] who points out that the outermost effective orbit in the sodium atom that gives the forty-seventh line must embrace large numbers of other atoms. He suggests that collisions are chiefly responsible for the production of the absorption lines.
Even though the simple theory is inapplicable to the laboratory conditions, it is not necessarily invalid in the stellar atmosphere, where conditions are far more simple, and where, in particular, the effects of collisions are negligible. There appears, moreover, to be a distinct observational correlation between the pressure and the number of observable hydrogen lines. The importance of the wave-length of the beginning of the continuous absorption, which lies just to the red of the last Balmer line observed, and extends toward the violet, was first indicated by Wright,[84] who recorded that the absorption head was farther to the red in
Lyrae than in
Cygni. This fact is obviously reflated to the difference in pressure in the atmospheres of the two stars, one of which is a normal