There are three stages in the scorification process; roasting, fusion, and scorification. During the first, the heat should be moderate until fumes cease to be given off; during the second, the heat is raised and a play of colors is seen on the surface of the lead; in the closing stage, the heat is lowered for a time until the slag covers the lead, when it is again raised for a short time and the scorifier removed. Brittle buttons may be due to arsenic, antimony, zinc or litharge, and must be re-scorified before cupellation, with more lead.
Take the cupel slowly from the fire to avoid "spitting," by which portions of the buttons are lost. Watch closely for the brightening.
Silver is volatile at a high heat, but when the muffle is almost white, the metal well fused and clean, the fumes rising slowly, and the cupel a cherry red, all is going smoothly. If the fumes rise rapidly, the muffle is too hot. On the other hand, dense, falling fumes show the temperature is too low. Lead that is poor in silver stands the highest heat without vitiating the assay.
When the material in the cupel "freezes," i.e., the absorption by the cupel stops, reject the assay and try again, giving more heat or more lead.
Gold. Practically, the metal most prospectors seek is gold. It is so enormously valuable and constitutes so very small a percentage of any ore, that care must be taken or it may escape detection and be lost. Panning is the miner's method. He crushes his ore thoroughly, and places it in the pan with water; then, with a motion easy to learn but difficult to describe, he swirls the water around, allowing a little of it to escape at each revolution, carrying with it the rubbish, until finally he has a little black sand and perhaps a few grains of yellow substance, which is gold. Mica, or fool's gold, puzzles nobody but the ignoramus. True, it looks like gold in certain positions and lights, but gold will beat out thin under the hammer, just as lead would, while mica will break up into a floury powder. Mica is very light, while gold is very heavy; so there is no excuse for confounding the two. If an ore contains sulphurets and gold, the latter may be coated with some sulphur or arsenic, which would prevent the gold from amalgamating. The only remedy for this is roasting. No single acid will dissolve gold, but a solution known as aqua regia, made up of three parts of hydrochloric acid and one part of nitric acid, dissolves it. If to the solution so obtained you add some sulphate of iron, you will get a precipitate which is metallic gold, although it does not look like it, as it is brown in color; but if you place this precipitate in a crucible and heat, you will get a yellow bead of pure gold. Another test for gold is to take the solution as above obtained and add thereto a solution of chloride of tin, when you obtain a purple coloration that has been called the purple of Cassius.
Gold may be distinguished from all other metals by the three following tests: It is yellow; it may be flattened by the hammer; it is not acted upon by nitric acid.
Pure gold is soft, and the point of a knife will scratch it deeply. Pounded in a mortar, the pulverized mineral should be passed through a cheese-cloth screen stretched over a loop of wood. If the course contains much pyrite, it must be roasted before washing in the pan and amalgamating. Sample well, weigh out two pounds, put it in a black iron pan, with four ounces of mercury, four ounces of salt, four ounces of soda and a half gallon of boiling water. Stir with a green stick, and agitate until the mercury has been able to reach all the gold. Pan off into another dish so as to lose no mercury, squeeze the amalgam through chamois leather or new calico previously wetted. The pill of hard amalgam may be placed on a shovel over the fire or in a clay tobacco pipe and retorted.
Gold is readily acted upon by the mixture of nitric and hydrochloric acids known as aqua regia, or by any solution producing chlorine. Some of the mixtures which attack it are bisulphate of soda, nitrate of soda and common salt, hydrochloric acid and potassium chlorate, and bleaching powder. The action is more rapid in hot than in cold solutions, and impure gold is more easily dissolved than pure.
Mercury dissolves gold rapidly at ordinary temperatures, the amalgam being solid, pasty or liquid. Gold rubbed with mercury is immediately penetrated by it. An amalgam containing 90 per cent. of mercury is liquid; 87.5 per cent., pasty; 85 per cent., crystalline. These amalgams heated gradually to a bright red heat lose all their mercury, and hardly any gold. About one-tenth of 1 per cent. of mercury remains in the gold until it is refined by melting.
The veins from which the gold of the world is won do not, on an average, hold the precious metal in greater proportion than one part of gold in 70,000 parts of veinstone. Under favorable conditions a proportion not one-fifth as rich as this, may yield a rich return. In hydraulic mining on a large scale, one part of gold in 15,000,000 parts of gravel has paid a dividend.