[2] Some of the rounded fragments in the porphyritic conglomerate near the Baths of Cauquenes, were marked with radii and concentric zones of different shades of colour: any one who did not know that pebbles, for instance flint pebbles from the chalk, are sometimes zoned concentrically with their worn and rounded surfaces, might have been led to infer, that these balls of porphyry were not true pebbles, but had originated in concretionary action.)
All the varieties of porphyritic conglomerates and breccias pass into each other, and by innumerable gradations into porphyries no longer retaining the least trace of mechanical origin: the transition appears to have been effected much more easily in the finer-grained, than in the coarser-grained varieties. In one instance, near Cauquenes, I noticed that a porphyritic conglomerate assumed a spheroidal structure, and tended to become columnar. Besides the porphyritic conglomerates and the perfectly characterised porphyries, of metamorphic origin, there are other porphyries, which, though differing not at all or only slightly in composition, certainly have had a different origin: these consist of pink or purple claystone porphyries, sometimes including grains of quartz,—of greenstone porphyry, and of other dusky rocks, all generally porphyritic with fine, large, tabular, opaque crystals, often placed crosswise, of feldspar cleaving like albite (judging from several measurements), and often amygdaloidal with silex, agate, carbonate of lime, green and brown bole.[[3]] These several porphyritic and amygdaloidal varieties never show any signs of passing into masses of sedimentary origin: they occur both in great and small intrusive masses, and likewise in strata alternating with those of the porphyritic conglomerate, and with the planes of junction often quite distinct, yet not seldom blended together. In some of these intrusive masses, the porphyries exhibit, more or less plainly, a brecciated structure, like that often seen in volcanic masses. These brecciated porphyries could generally be distinguished at once from the metamorphosed, porphyritic breccia-conglomerates, by all the fragments being angular and being formed of the same variety, and by the absence of every trace of aqueous deposition. One of the porphyries above specified, namely, the greenstone porphyry with large tabular crystals of albite, is particularly abundant, and in some parts of the Cordillera (as near St. Jago) seemed more common even than the purplish porphyritic conglomerate. Numerous dikes likewise consist of this greenstone porphyry; others are formed of various fine-grained trappean rocks; but very few of claystone porphyry: I saw no true basaltic dikes.
[3] This bole is a very common mineral in the amygdaloidal rocks; it is generally of a greenish-brown colour, with a radiating structure; externally it is black with an almost metallic lustre, but often coated by a bright green film. It is soft and can be scratched by a quill; under the blowpipe swells greatly and becomes scaly, then fuses easily into a black magnetic bead. This substance is evidently similar to that which often occurs in submarine volcanic rocks. An examination of some very curious specimens of a fine porphyry (from Jajuel) leads me to suspect that some of these amygdaloidal balls, instead of having been deposited in pre-existing air-vesicles, are of concretionary origin; for in these specimens, some of the pea-shaped little masses (often externally marked with minute pits) are formed of a mixture of green earth with stony matter, like the basis of the porphyry, including minute imperfect crystals of feldspar; and these pea-shaped little masses are themselves amygdaloidal with minute spheres of the green earth, each enveloped by a film of white, apparently feldspathic, earthy matter: so that the porphyry is doubly amygdaloidal. It should not, however, be overlooked, that all the strata here have undergone metamorphic action, which may have caused crystals of feldspar to appear, and other changes to be effected, in the originally simple amygdaloidal balls. Mr. J. D. Dana, in an excellent paper on Trap-rocks (Edin. New Phil. Journ., vol. xli, p. 198), has argued with great force, that all amygdaloidal minerals have been deposited by aqueous infiltration. I may take this opportunity of alluding to a curious case, described in my work on “Volcanic Islands,” of an amygdaloid with many of its cells only half filled up with a mesotypic mineral.
M. Rose has described an amygdaloid, brought by Dr. Meyen (“Reise um Erde,” Th. I, s. 316) from Chile, as consisting of crystallised quartz, with crystals of stilbite within, and lined externally by green earth.
In several places in the lower part of the series, but not everywhere, thick masses of a highly feldspathic, often porphyritic, slaty rock occur interstratified with the porphyritic conglomerate; I believe in one or two cases blackish limestone has been found in a similar position. The feldspathic rock is of a pale grey or greenish colour; it is easily fusible; where porphyritic, the crystals of feldspar are generally small and vitreous: it is distinctly laminated, and sometimes includes parallel layers of epidote;[[4]] the lamination appears to be distinct from stratification. Occasionally this rock is somewhat curious; and at one spot, namely, at the C. of Quillota, it had a brecciated structure. Near the mines of Jajuel, in a thick stratum of this feldspathic, porphyritic slate, there was a layer of hard, blackish, siliceous, infusible, compact clay-slate, such as I saw nowhere else; at the same place I was able to follow for a considerable distance the junction between the slate and the conformably underlying porphyritic conglomerate, and they certainly passed gradually into each other. Wherever these slaty feldspathic rocks abound, greenstone seems common; at the C. of Quillota a bed of well-crystallised greenstone lay conformably in the midst of the feldspathic slate, with the upper and lower junctions passing insensibly into it. From this point, and from the frequently porphyritic condition of the slate, I should perhaps have considered this rock as an erupted one (like certain laminated feldspathic lavas in the trachytic series), had I not seen in Tierra del Fuego how readily true clay-slate becomes feldspathic and porphyritic, and had I not seen at Jajuel the included layer of black, siliceous clay-slate, which no one could have thought of igneous origin. The gentle passage of the feldspathic slate, at Jajuel, into the porphyritic conglomerate, which is certainly of aqueous origin, should also be taken in account.
[4] This mineral is extremely common in all the formations of Chile; in the gneiss near Valparaiso and in the granitic veins crossing it, in the injected greenstone crowning the C. of Quillota, in some granitic porphyries, in the porphyritic conglomerate, and in the feldspathic clay-slates.
The alternating strata of porphyries and porphyritic conglomerate, and with the occasionally included beds of feldspathic slate, together make a grand formation; in several places within the Cordillera, I estimated its thickness at from six to seven thousand feet. It extends for many hundred miles, forming the western flank of the Chilean Cordillera; and even at Iquique in Peru, 850 miles north of the southernmost point examined by me in Chile, the coast-escarpment which rises to a height of between two and three thousand feet is thus composed. In several parts of Northern Chile this formation extends much further towards the Pacific, over the granitic and metamorphic lower rocks, than it does in Central Chile; but the main Cordillera may be considered as its central line, and its breadth in an east and west direction is never great. At first the origin of this thick, massive, long but narrow formation, appeared to me very anomalous: whence were derived, and how were dispersed the innumerable fragments, often of large size, sometimes angular and sometimes rounded, and almost invariably composed of porphyritic rocks? Seeing that the interstratified porphyries are never vesicular and often not even amygdaloidal, we must conclude that the pile was formed in deep water; how then came so many fragments to be well rounded and so many to remain angular, sometimes the two kinds being equally mingled, sometimes one and sometimes the other preponderating? That the claystone, greenstone, and other porphyries and amygdaloids, which lie conformably between the beds of conglomerate, are ancient submarine lavas, I think there can be no doubt; and I believe we must look to the craters whence these streams were erupted, as the source of the breccia-conglomerate; after the great explosion, we may fairly imagine that the water in the heated and scarcely quiescent crater would remain for a considerable time[[5]] sufficiently agitated to triturate and round the loose fragments, few or many in number, would be shot forth at the next eruption, associated with few or many angular fragments, according to the strength of the explosion. The porphyritic conglomerate being purple or reddish, even when alternating with dusty-coloured or bright green porphyries and amygdaloids, is probably an analogous circumstance to the scoriæ of the blackish basalts being often bright red. The ancient submarine orifices whence the porphyries and their fragments were ejected having been arranged in a band, like most still active volcanoes, accounts for the thickness, the narrowness, and linear extension of this formation.
[5] This certainly seems to have taken place in some recent volcanic archipelagos, as at the Galapagos, where numerous craters are exclusively formed of tuff and fragments of lava.
This whole great pile of rock has suffered much metamorphic action, as is very obvious in the gradual formation and appearance of the crystals of albitic feldspar and of epidote—in the bending together of the fragments—in the appearance of a laminated structure in the feldspathic slate—and, lastly, in the disappearance of the planes of stratification, which could sometimes be seen on the same mountain quite distinct in the upper part, less and less plain on the flanks, and quite obliterated at the base. Partly owing to this metamorphic action, and partly to the close relationship in origin, I have seen fragments of porphyries—taken from a metamorphosed conglomerate—from a neighbouring stream of lava—from the nucleus or centre (as it appeared to me) of the whole submarine volcano—and lastly from an intrusive mass of quite subsequent origin, all of which were absolutely undistinguishable in external characters.
One other rock, of plutonic origin, and highly important in the history of the Cordillera, from having been injected in most of the great axes of elevation, and from having apparently been instrumental in metamorphosing the superincumbent strata, may be conveniently described in this preliminary discussion. It has been called by some authors Andesite: it mainly consists of well-crystallised white albite[[6]] (as determined with the goniometer in numerous specimens both by Professor Miller and myself), of less perfectly crystallised green hornblende, often associated with much mica, with chlorite and epidote, and occasionally with a few grains of quartz: in one instance in Northern Chile, I found crystals of orthitic or potash feldspar, mingled with those of albite. Where the mica and quartz are abundant, the rock cannot be distinguished from granite; and it may be called andesitic granite. Where these two minerals are quite absent, and when, as often then happens, the crystals of albite are imperfect and blend together, the rock may be called andesitic porphyry, which bears nearly the same relation to andesitic granite that euritic porphyry does to common granite. These andesitic rocks form mountain masses of a white colour, which, in their general outline and appearance—in their joints—in their occasionally including dark-coloured, angular fragments, apparently of some pre-existing rock—and in the great dikes branching from them into the superincumbent strata, manifest a close and striking resemblance to masses of common granite and syenite: I never, however, saw in these andesitic rocks, those granitic veins of segregation which are so common in true granites. We have seen that andesite occurs in three places in Tierra del Fuego; in Chile, from S. Fernando to Copiapo, a distance of 450 miles, I found it under most of the axes of elevation; in a collection of specimens from the Cordillera of Lima in Peru, I immediately recognised it; and Erman[[7]] states that it occurs in Eastern Kamtschatka. From its wide range, and from the important part it has played in the history of the Cordillera, I think this rock has well deserved its distinct name of Andesite.
[6] I here, and elsewhere, call by this name, those feldspathic minerals which cleave like albite: but it now appears (Edin. New Phil. Journal., vol. xxiv, p. 181) that Abich has analysed a mineral from the Cordillera, associated with hornblende and quartz (probably the same rock with that here under discussion), which cleaves like albite, but which is a new and distinct kind, called by him Andesine. It is allied to leucite, with the greater proportion of its potash replaced by lime and soda. This mineral seems scarcely distinguishable from albite, except by analysis.