A layer, formed by the union of minute brown sphærulites, intersecting two other similar layers: the whole represented of nearly the natural size.
One of the commonest transitional rocks deserves in several respects a further description. It is of a very complicated nature, and consists of numerous thin, slightly tortuous layers of a pale-coloured feldspathic stone, often passing into an imperfect pitchstone, alternating with layers formed of numberless little globules of two varieties of obsidian, and of two kinds of sphærulites, embedded in a soft or in a hard pearly base. The sphærulites are either white and translucent, or dark brown and opaque; the former are quite spherical, of small size, and distinctly radiated from their centre. The dark brown sphærulites are less perfectly round, and vary in diameter from the twentieth to the thirtieth of an inch; when broken they exhibit towards their centres, which are whitish, an obscure radiating structure; two of them when united sometimes have only one central point of radiation; there is occasionally a trace of or a hollow crevice in their centres. They stand either separately, or are united two or three or many together into irregular groups, or more commonly into layers, parallel to the stratification of the mass. This union in many cases is so perfect, that the two sides of the layer thus formed, are quite even; and these layers, as they become less brown and opaque, cannot be distinguished from the alternating layers of the pale-coloured feldspathic stone. The sphærulites, when not united, are generally compressed in the plane of the lamination of the mass; and in this same plane, they are often marked internally, by zones of different shades of colour, and externally by small ridges and furrows. In the upper part of figure No. 6, the sphærulites with the parallel ridges and furrows are represented on an enlarged scale, but they are not well executed; and in the lower part, their usual manner of grouping is shown. In another specimen, a thin layer formed of the brown sphærulites closely united together, intersects, as represented in figure No. 7, a layer of similar composition; and after running for a short space in a slightly curved line, again intersects it, and likewise a second layer lying a little way beneath that first intersected. The small nodules also of obsidian are sometimes externally marked with ridges and furrows, parallel to the lamination of the mass, but always less plainly than the sphærulites. These obsidian nodules are generally angular, with their edges blunted: they are often impressed with the form of the adjoining sphærulites, than which they are always larger; the separate nodules seldom appear to have drawn each other out by exerting a mutually attractive force. Had I not found in some cases, a distinct centre of attraction in these nodules of obsidian, I should have been led to have considered them as residuary matter, left during the formation of the pearlstone, in which they are embedded, and of the sphærulitic globules.
The sphærulites and the little nodules of obsidian in these rocks so closely resemble, in general form and structure, concretions in sedimentary deposits, that one is at once tempted to attribute to them an analogous origin. They resemble ordinary concretions in the following respects: in their external form,—in the union of two or three, or of several, into an irregular mass, or into an even-sided layer,—in the occasional intersection of one such layer by another, as in the case of chalk-flints,—in the presence of two or three kinds of nodules, often close together, in the same basis,—in their fibrous, radiating structure, with occasional hollows in their centres,—in the co-existence of a laminary, concretionary, and radiating structure, as is so well developed in the concretions of magnesian limestone, described by Professor Sedgwick.[[24]] Concretions in sedimentary deposits, it is known, are due to the separation from the surrounding mass of the whole or part of some mineral substance, and its aggregation round certain points of attraction. Guided by this fact, I have endeavoured to discover whether obsidian and the sphærulites (to which may be added marekanite and pearlstone, both of them occurring in nodular concretions in the trachytic series) differ in their constituent parts, from the minerals generally composing trachytic rocks. It appears from three analyses, that obsidian contains on an average 76 per cent of silica; from one analysis, that sphærulites contain 79·12; from two, that marekanite contains 79·25; and from two other analyses, that pearlstone contains 75·62 of silica.[[25]] Now, the constituent parts of trachyte, as far as they can be distinguished consist of feldspar, containing 65·21 of silica; or of albite, containing 69·09; of hornblende, containing 55·27,[[26]] and of oxide of iron: so that the foregoing glassy concretionary substances all contain a larger proportion of silica than that occurring in ordinary feldspathic or trachytic rocks. D’Aubuisson,[[27]] also, has remarked on the large proportion of silica compared with alumina, in six analyses of obsidian and pearlstone given in Brongniart’s “Mineralogy.” Hence I conclude, that the foregoing concretions have been formed by a process of aggregation, strictly analogous to that which takes place in aqueous deposits, acting chiefly on the silica, but likewise on some of the other elements of the surrounding mass, and thus producing the different concretionary varieties. From the well-known effects of rapid cooling[[28]] in giving glassiness of texture, it is probably necessary that the entire mass, in cases like that of Ascension, should have cooled at a certain rate; but considering the repeated and complicated alterations of nodules and thin layers of a glassy texture with other layers quite stony or crystalline, all within the space of a few feet or even inches, it is hardly possible that they could have cooled at different rates, and thus have acquired their different textures.
[24] “Geological Transactions,” vol. 3, part i, p. 37.
[25] The foregoing analyses are taken from Beudant “Traité de Minéralogie,” tome ii, p. 113; and one analysis of obsidian from Phillips’s “Mineralogy.”
[26] These analyses are taken from Von Kobell’s “Grundzüge der Mineralogie,” 1838.
[27] “Traité de Géogn.,” tome ii, p. 535.
[28] This is seen in the manufacture of common glass, and in Gregory Watts’s experiments on molten trap; also on the natural surfaces of lava-streams, and on the side-walls of dikes.
The natural sphærulites in these rocks[[29]] very closely resemble those produced in glass, when slowly cooled. In some fine specimens of partially devitrified glass, in the possession of Mr. Stokes, the sphærulites are united into straight layers with even sides, parallel to each other, and to one of the outer surfaces, exactly as in the obsidian. These layers sometimes interbranch and form loops; but I did not see any case of actual intersection. They form the passage from the perfectly glassy portions, to those nearly homogeneous and stony, with only an obscure concretionary structure. In the same specimen, also, sphærulites differing slightly in colour and in structure, occur embedded close together. Considering these facts, it is some confirmation of the view above given of the concretionary origin of the obsidian and natural sphærulites, to find that M. Dartigues,[[30]] in his curious paper on this subject, attributes the production of sphærulites in glass, to the different ingredients obeying their own laws of attraction and becoming aggregated. He is led to believe that this takes place, from the difficulty in remelting sphærulitic glass, without the whole be first thoroughly pounded and mixed together; and likewise from the fact, that the change takes place most readily in glass composed of many ingredients. In confirmation of M. Dartigues’ view, I may remark, that M. Fleuriau de Bellevue[[31]] found that the sphærulitic portions of devitrified glass were acted on both by nitric acid and under the blowpipe, in a different manner from the compact paste in which they were embedded.
[29] I do not know whether it is generally known, that bodies having exactly the same appearance as sphærulites, sometimes occur in agates. Mr. Robert Brown showed me in an agate, formed within a cavity in a piece of silicified wood, some little specks, which were only just visible to the naked eye: these specks, when placed by him under a lens of high power, presented a beautiful appearance: they were perfectly circular, and consisted of the finest fibres of a brown colour, radiating with great exactness from a common centre. These little radiating stars are occasionally intersected, and portions are quite cut off by the fine, ribbon-like zones of colour in the agate. In the obsidian of Ascension, the halves of a sphærulite often lie in different zones of colour, but they are not cut off by them, as in the agate.