The salt rests almost always on a thick bed of black muddy sand, which is fetid, probably from the decay of the burrowing worms inhabiting it. (Professor Ehrenberg examined some of this muddy sand, but was unable to find in it any infusoria.) In a salina, situated about fifteen miles above the town of El Carmen on the Rio Negro, and three or four miles from the banks of that river, I observed that this black mud rested on gravel with a calcareous matrix, similar to that spread over the whole surrounding plains: at Port S. Julian the mud, also, rested on the gravel: hence the depressions must have been formed anteriorly to, or contemporaneously with, the spreading out of the gravel. I was informed that one small salina occurs in an alluvial plain within the valley of the Rio Negro, and therefore its origin must be subsequent to the excavation of that valley. When I visited the salina, fifteen miles above the town, the salt was beginning to crystallise, and on the muddy bottom there were lying many crystals, generally placed crossways of sulphate of soda (as ascertained by Mr. Reeks), and embedded in the mud, numerous crystals of sulphate of lime, from one to three inches in length: M. d’Orbigny states that some of these crystals are acicular and more than even nine inches in length (“Voyage Geolog.” page 64.); others are macled and of great purity: those I found all contained some sand in their centres. As the black and fetid sand overlies the gravel, and that overlies the regular tertiary strata, I think there can be no doubt that these remarkable crystals of sulphate of lime have been deposited from the waters of the lake. The inhabitants call the crystals of selenite, the padre del sal, and those of the sulphate of soda, the madre del sal; they assured me that both are found under the same circumstances in several of the neighbouring salinas; and that the sulphate of soda is annually dissolved, and is always crystallised before the common salt on the muddy bottom. (This is what might have been expected; for M. Ballard asserts “Acad. des Sciences” October 7, 1844, that sulphate of soda is precipitated from solution more readily from water containing muriate of soda in excess, than from pure water.) The association of gypsum and salt in this case, as well as in the superficial deposits of Iquique, appears to me interesting, considering how generally these substances are associated in the older stratified formations.
Mr. Reeks has analysed for me some of the salt from the salina near the Rio Negro; he finds it composed entirely of chloride of sodium, with the exception of 0.26 of sulphate of lime and of 0.22 of earthy matter: there are no traces of iodic salts. Some salt from the salina Chiquitos, in the Pampean formation, is equally pure. It is a singular fact, that the salt from these salinas does not serve so well for preserving meat, as sea-salt from the Cape de Verde Islands; and a merchant at Buenos Ayres told me that he considered it as 50 per cent less valuable. The purity of the Patagonian salt, or absence from it of those other saline bodies found in all sea- water, is the only assignable cause for this inferiority; a conclusion which is supported by the fact lately ascertained, that those salts answer best for preserving cheese which contain most of the deliquescent chlorides. (“Horticultural and Agricultural Gazette” 1845 page 93.) (It would probably well answer for the merchants of Buenos Ayres (considering the great consumption there of salt for preserving meat) to import the deliquescent chlorides to mix with the salt from the salinas: I may call attention to the fact, that at Iquique, a large quantity of muriate of lime, left in the MOTHER-WATER during the refinement of the nitrate of soda, is annually thrown away.)
With respect to the origin of the salt in the salinas, the foregoing analysis seems opposed to the view entertained by M. d’Orbigny and others, and which seems so probable considering the recent elevation of this line of coast, namely, that it is due to the evaporation of sea-water and to the drainage from the surrounding strata impregnated with sea-salt. I was informed (I know not whether accurately) that on the northern side of the salina on the Rio Negro, there is a small brine spring which flows at all times of the year: if this be so, the salt in this case at least, probably is of subterranean origin. It at first appears very singular that fresh water can often be procured in wells, and is sometimes found in small lakes, quite close to these salinas. (Sir W. Parish states “Buenos Ayres” etc. pages 122 and 170, that this is the case near the great salinas westward of the S. Ventana. I have seen similar statements in an ancient MS. Journal lately published by S. Angelis. At Iquique, where the surface is so thickly encrusted with saline matter, I tasted water only slightly brackish, procured in a well thirty-six yards deep; but here one feels less surprise at its presence, as pure water might percolate under ground from the not very distant Cordillera.) I am not aware that this fact bears particularly on the origin of the salt; but perhaps it is rather opposed to the view of the salt having been washed out of the surrounding superficial strata, but not to its having been the residue of sea-water, left in depressions as the land was slowly elevated.
CHAPTER IV.
ON THE FORMATIONS OF THE PAMPAS.
Mineralogical constitution.—Microscopical structure.—Buenos Ayres, shells embedded in tosca-rock.—Buenos Ayres to the Colorado.—San Ventana.—Bahia Blanca; M. Hermoso, bones and infusoria of; P. Alta, shells, bones and infusoria of; co-existence of the recent shells and extinct mammifers.—Buenos Ayres to Santa Fé.—Skeletons of Mastodon.—Infusoria.—Inferior marine tertiary strata, their age.—Horse’s tooth.—BANDA ORIENTAL.—Superficial Pampean formation.—Inferior tertiary strata, variation of, connected with volcanic action; Macrauchenia Patachonica at San Julian in Patagonia, age of, subsequent to living mollusca and to the erratic block period. SUMMARY.—Area of Pampean formation.—Theories of origin.—Source of sediment.—Estuary origin.—Contemporaneous with existing mollusca.—Relations to underlying tertiary strata.—Ancient deposit of estuary origin.—Elevation and successive deposition of the Pampean formation.—Number and state of the remains of mammifers; their habitation, food, extinction, and range.—Conclusion.—Localities in Pampas at which mammiferous remains have been found.
The Pampean formation is highly interesting from its vast extent, its disputed origin, and from the number of extinct gigantic mammifers embedded in it. It has upon the whole a very uniform character: consisting of a more or less dull reddish, slightly indurated, argillaceous earth or mud, often, but not always, including in horizontal lines concretions of marl, and frequently passing into a compact marly rock. The mud, wherever I examined it, even close to the concretions, did not contain any carbonate of lime. The concretions are generally nodular, sometimes rough externally, sometimes stalactiformed; they are of a compact structure, but often penetrated (as well as the mud) by hair-like serpentine cavities, and occasionally with irregular fissures in their centres, lined with minute crystals of carbonate of lime; they are of white, brown, or pale pinkish tints, often marked by black dendritic manganese or iron; they are either darker or lighter tinted than the surrounding mass; they contain much carbonate of lime, but exhale a strong aluminous odour, and leave, when dissolved in acids, a large but varying residue, of which the greater part consists of sand. These concretions often unite into irregular strata; and over very large tracts of country, the entire mass consists of a hard, but generally cavernous marly rock: some of the varieties might be called calcareous tuffs.
Dr. Carpenter has kindly examined under the microscope, sliced and polished specimens of these concretions, and of the solid marl-rock, collected in various places between the Colorado and Santa Fe Bajada. In the greater number, Dr. Carpenter finds that the whole substance presents a tolerably uniform amorphous character, but with traces of incipient crystalline metamorphosis; in other specimens he finds microscopically minute rounded concretions of an amorphous substance (resembling in size those in oolitic rocks, but not having a concentric structure), united by a cement which is often crystalline. In some, Dr. Carpenter can perceive distinct traces of shells, corals, Polythalamia, and rarely of spongoid bodies. For the sake of comparison, I sent Dr. Carpenter specimens of the calcareous rock, formed chiefly of fragments of recent shells, from Coquimbo in Chile: in one of these specimens, Dr. Carpenter finds, besides the larger fragments, microscopical particles of shells, and a varying quantity of opaque amorphous matter; in another specimen from the same bed, he finds the whole composed of the amorphous matter, with layers showing indications of an incipient crystalline metamorphosis: hence these latter specimens, both in external appearance and in microscopical structure, closely resemble those of the Pampas. Dr. Carpenter informs me that it is well known that chemical precipitation throws down carbonate of lime in the opaque amorphous state; and he is inclined to believe that the long-continued attrition of a calcareous body in a state of crystalline or semi-crystalline aggregation (as, for instance, in the ordinary shells of Mollusca, which, when sliced, are transparent) may yield the same result. From the intimate relations between all the Coquimbo specimens, I can hardly doubt that the amorphous carbonate of lime in them has resulted from the attrition and decay of the larger fragments of shell: whether the amorphous matter in the marly rocks of the Pampas has likewise thus originated, it would be hazardous to conjecture.
For convenience’ sake, I will call the marly rock by the name given to it by the inhabitants, namely, Tosca-rock; and the reddish argillaceous earth, Pampean mud. This latter substance, I may mention, has been examined for me by Professor Ehrenberg, and the result of his examination will be given under the proper localities.
I will commence my descriptions at a central spot, namely, at Buenos Ayres, and thence proceed first southward to the extreme limit of the deposit, and afterwards northward. The plain on which Buenos Ayres stands is from thirty to forty feet in height. The Pampean mud is here of a rather pale colour, and includes small nearly white nodules, and other irregular strata of an unusually arenaceous variety of tosca-rock. In a well at the depth of seventy feet, according to Ignatio Nunez, much tosca-rock was met with, and at several points, at one hundred feet deep, beds of sand have been found. I have already given a list of the recent marine and estuary shells found in many parts on the surface near Buenos Ayres, as far as three or four leagues from the Plata. Specimens from near Ensenada, given me by Sir W. Parish, where the rock is quarried just beneath the surface of the plain, consist of broken bivalves, cemented by and converted into white crystalline carbonate of lime. I have already alluded, in the first chapter, to a specimen (also given me by Sir W. Parish) from the A. del Tristan, in which shells, resembling in every respect the Azara labiata, d’Orbigny, as far as their worn condition permits of comparison, are embedded in a reddish, softish, somewhat arenaceous marly rock: after careful comparison, with the aid of a microscope and acids, I can perceive no difference between the basis of this rock and the specimens collected by me in many parts of the Pampas. I have also stated, on the authority of Sir W. Parish, that northward of Buenos Ayres, on the highest parts of the plain, about forty feet above the Plata, and two or three miles from it, numerous shells of the Azara labiata (and I believe of Venus sinuosa) occur embedded in a stratified earthy mass, including small marly concretions, and said to be precisely like the great Pampean deposit. Hence we may conclude that the mud of the Pampas continued to be deposited to within the period of this existing estuary shell. Although this formation is of such immense extent, I know of no other instance of the presence of shells in it.