From Combarbala to Coquimbo, I traversed the country in a zigzag direction, crossing and recrossing the porphyritic conglomerate and finding in the granitic districts an unusual number of mountain-masses composed of various intrusive, porphyritic rocks, many of them andesitic. One common variety was greenish-black, with large crystals of blackish albite. At Panuncillo a short N.N.W. and S.S.E. ridge, with a nucleus formed of greenstone and of a slate-coloured porphyry including crystals of glassy feldspar, deserves notice, from the very singular nature of the almost vertical strata composing it. These consist chiefly of a finer and coarser granular mixture, not very compact, of white carbonate of lime, of protoxide of iron and of yellowish garnets (ascertained by Professor Miller), each grain being an almost perfect crystal. Some of the varieties consist exclusively of granules of the calcareous spar; and some contain grains of copper ore, and, I believe, of quartz. These strata alternate with a bluish, compact, fusible, feldspathic rock. Much of the above granular mixture has, also, a pseudo-brecciated structure, in which fragments are obscurely arranged in planes parallel to those of the stratification, and are conspicuous on the weathered surfaces. The fragments are angular or rounded, small or large, and consist of bluish or reddish compact feldspathic matter, in which a few acicular crystals of feldspar can sometimes be seen. The fragments often blend at their edges into the surrounding granular mass, and seem due to a kind of concretionary action.
These singular rocks are traversed by many copper veins, and appear to rest conformably on the granular mixture (in parts as fine-grained as a sandstone) of quartz, mica, hornblende, and feldspar; and this on fine- grained, common gneiss; and this on a laminated mass, composed of pinkish ORTHITIC feldspar, including a few specks of hornblende; and lastly, this on granite, which together with andesitic rocks, form the surrounding district.
COQUIMBO: MINING DISTRICT OF ARQUEROS.
At Coquimbo the porphyritic conglomerate formation approaches nearer to the Pacific than in any other part of Chile visited by me, being separated from the coast by a tract only a few miles broad of the usual plutonic rocks, with the addition of a porphyry having a red euritic base. In proceeding to the mines of Arqueros, the strata of porphyritic conglomerate are at first nearly horizontal, an unusual circumstance, and afterwards they dip gently to S.S.E. After having ascended to a considerable height, we come to an undulatory district in which the famous silver mines are situated; my examination was chiefly confined to those of S. Rosa. Most of the rocks in this district are stratified, dipping in various directions, and many of them are of so singular a nature, that at the risk of being tedious I must briefly describe them. The commonest variety is a dull-red, compact, finely brecciated stone, containing much iron and innumerable white crystallised particles of carbonate of lime, and minute extraneous fragments. Another variety is almost equally common near S. Rosa; it has a bright green, scanty basis, including distinct crystals and patches of white carbonate of lime, and grains of red, semi-micaceous oxide of iron; in parts the basis becomes dark green, and assumes an obscure crystalline arrangement, and occasionally in parts it becomes soft and slightly translucent like soapstone. These red and green rocks are often quite distinct, and often pass into each other; the passage being sometimes affected by a fine brecciated structure, particles of the red and green matter being mingled together. Some of the varieties appear gradually to become porphyritic with feldspar; and all of them are easily fusible into pale or dark-coloured beads, strongly attracted by the magnet. I should perhaps have mistaken several of these stratified rocks for submarine lavas, like some of those described at the Puente del Inca, had I not examined, a few leagues eastward of this point, a fine series of analogous but less metamorphosed, sedimentary beds belonging to the gypseous formation, and probably derived from a volcanic source.
This formation is intersected by numerous metalliferous veins, running, though irregularly, N.W. and S.E., and generally at right angles to the many dikes. The veins consist of native silver, of muriate of silver, an amalgam of silver, cobalt, antimony, and arsenic, generally embedded in sulphate of barytes. (See the Report on M. Domeyko’s account of those mines, in the “Comptes Rendus” tome 14 page 560.) I was assured by Mr. Lambert, that native copper without a trace of silver has been found in the same vein with native silver without a trace of copper. At the mines of Aristeas, the silver veins are said to be unproductive as soon as they pass into the green strata, whereas at S. Rosa, only two or three miles distant, the reverse happens; and at the time of my visit, the miners were working through a red stratum, in the hope of the vein becoming productive in the underlying green sedimentary mass. I have a specimen of one of these green rocks, with the usual granules of white calcareous spar and red oxide of iron, abounding with disseminated particles of glittering native and muriate of silver, yet taken at the distance of one yard from any vein,—a circumstance, as I was assured, of very rare occurrence.
A SECTION EASTWARD, UP THE VALLEY OF COQUIMBO.
After passing for a few miles over the coast granitic series, we come to the porphyritic conglomerate, with its usual characters, and with some of the beds distinctly displaying their mechanical origin. The strata, where first met with, are, as before stated, only slightly inclined; but near the Hacienda of Pluclaro, we come to an anticlinal axis, with the beds much dislocated and shifted by a great fault, of which not a trace is externally seen in the outline of the hill. I believe that this anticlinal axis can be traced northwards, into the district of Arqueros, where a conspicuous hill called Cerro Blanco, formed of a harsh, cream-coloured euritic rock, including a few crystals of reddish feldspar, and associated with some purplish claystone porphyry, seems to fall on a line of elevation. In descending from the Arqueros district, I crossed on the northern border of the valley, strata inclined eastward from the Pluclaro axis: on the porphyritic conglomerate there rested a mass, some hundred feet thick, of brown argillaceous limestone, in parts crystalline, and in parts almost composed of Hippurites Chilensis, d’Orbigny; above this came a black calcareous shale, and on it a red conglomerate. In the brown limestone, with the Hippurites, there was an impression of a Pecten and a coral, and great numbers of a large Gryphaea, very like, and, according to Professor E. Forbes, probably identical with G. Orientalis, Forbes MS.,—a cretaceous species (probably upper greensand) from Verdachellum, in Southern India. These fossils seem to occupy nearly the same position with those at the Puente del Inca,—namely, at the top of the porphyritic conglomerate, and at the base of the gypseous formation.
A little above the Hacienda of Pluclaro, I made a detour on the northern side of the valley, to examine the superincumbent gypseous strata, which I estimated at 6,000 feet in thickness. The uppermost beds of the porphyritic conglomerate, on which the gypseous strata conformably rest, are variously coloured, with one very singular and beautiful stratum composed of purple pebbles of various kinds of porphyry, embedded in white calcareous spar, including cavities lined with bright-green crystallised epidote. The whole pile of strata belonging to both formations is inclined, apparently from the above-mentioned axis of Pluclaro, at an angle of between 20 and 30 degrees to the east. I will here give a section of the principal beds met with in crossing the entire thickness of the gypseous strata.
Firstly: above the porphyritic conglomerate formation, there is a fine- grained, red, crystalline sandstone.
Secondly: a thick mass of smooth-grained, calcareo-aluminous, shaly rock, often marked with dendritic manganese, and having, where most compact, the external appearance of honestone. It is easily fusible. I shall for the future, for convenience’ sake, call this variety pseudo-honestone. Some of the varieties are quite black when freshly broken, but all weather into a yellowish-ash coloured, soft, earthy substance, precisely as is the case with the compact shaly rocks of the Peuquenes range. This stratum is of the same general nature with many of the beds near Los Hornos in the Illapel section. In this second bed, or in the underlying red sandstone (for the surface was partially concealed by detritus), there was a thick mass of gypsum, having the same mineralogical characters with the great beds described in our sections across the Cordillera.