The difficulty of tracing the streams of porphyries to their ancient and doubtless numerous eruptive sources, may be partly explained by the very general disturbance which the Cordillera in most parts has suffered; but I strongly suspect that there is a more specific cause, namely, THAT THE ORIGINAL POINTS OF ERUPTION TEND TO BECOME THE POINTS OF INJECTION. This in itself does not seem improbable; for where the earth’s crust has once yielded, it would be liable to yield again, though the liquified intrusive matter might not be any longer enabled to reach the submarine surface and flow as lava. I have been led to this conclusion, from having so frequently observed that, where part of an unstratified mountain-mass resembled in mineralogical character the adjoining streams or strata, there were several other kinds of intrusive porphyries and andesitic rocks injected into the same point. As these intrusive mountain-masses form most of the axes-lines in the Cordillera, whether anticlinal, uniclinal, or synclinal, and as the main valleys have generally been hollowed out along these lines, the intrusive masses have generally suffered much denudation. Hence they are apt to stand in some degree isolated, and to be situated at the points where the valleys abruptly bend, or where the main tributaries enter. On this view of there being a tendency in the old points of eruption to become the points of subsequent injection and disturbance, and consequently of denudation, it ceases to be surprising that the streams of lava in the porphyritic claystone conglomerate formation, and in other analogous cases, should most rarely be traceable to their actual sources.

IQUIQUE, SOUTHERN PERU.

Differently from what we have seen throughout Chile, the coast here is formed not by the granitic series, but by an escarpment of the porphyritic conglomerate formation, between two and three thousand feet in height. (The lowest point, where the road crosses the coast-escarpment, is 1,900 feet by the barometer above the level of the sea.) I had time only for a very short examination; the chief part of the escarpment appears to be composed of various reddish and purple, sometimes laminated, porphyries, resembling those of Chile; and I saw some of the porphyritic breccia-conglomerate; the stratification appeared but little inclined. The uppermost part, judging from the rocks near the famous silver mine of Huantajaya, consists of laminated, impure, argillaceous, purplish-grey limestone, associated, I believe, with some purple sandstone. (Mr. Bollaert has described “Geological Proceedings” volume 2 page 598, a singular mass of stratified detritus, gravel, and sand, eighty-one yards in thickness, overlying the limestone, and abounding with loose masses of silver ore. The miners believe that they can attribute these masses to their proper veins.) In the limestone shells are found: the three following species were given me:—

Lucina Americana, E. Forbes. Terebratula inca, E. Forbes. Terebratula aenigma, D’Orbigny.

This latter species we have seen associated with the fossils of which lists have been given in this chapter, in two places in the valley of Coquimbo, and in the ravine of Maricongo at Copiapo. Considering this fact, and the superposition of these beds on the porphyritic conglomerate formation; and, as we shall immediately see, from their containing much gypsum, and from their otherwise close general resemblance in mineralogical nature with the strata described in the valley of Copiapo, I have little doubt that these fossiliferous beds of Iquique belong to the great cretaceo-oolitic formation of Northern Chile. Iquique is situated seven degrees latitude north of Copiapo; and I may here mention, that an Ammonites, nov. species, and an Astarte, nov. species, were given me from the Cerro Pasco, about ten degrees of latitude north of Iquique, and M. D’Orbigny thinks that they probably indicate a Neocomian formation. Again, fifteen degrees of latitude northward, in Colombia, there is a grand fossiliferous deposit, now well known from the labours of Von Buch, Lea, d’Orbigny, and Forbes, which belongs to the earlier stages of the cretaceous system. Hence, bearing in mind the character of the few fossils from Tierra del Fuego, there is some evidence that a great portion of the stratified deposits of the whole vast range of the South American Cordillera belongs to about the same geological epoch.

Proceeding from the coast escarpment inwards, I crossed, in a space of about thirty miles, an elevated undulatory district, with the beds dipping in various directions. The rocks are of many kinds,—white laminated, sometimes siliceous sandstone,—purple and red sandstone, sometimes so highly calcareous as to have a crystalline fracture,—argillaceous limestone,—black calcareous slate-rock, like that so often described at Copiapo and other places,—thinly laminated, fine-grained, greenish, indurated, sedimentary, fusible rocks, approaching in character to the so- called pseudo-honestone of Chile, including thin contemporaneous veins of gypsum,—and lastly, much calcareous, laminated porcelain jasper, of a green colour, with red spots, and of extremely easy fusibility: I noticed one conformable stratum of a freckled-brown, feldspathic lava. I may here mention that I heard of great beds of gypsum in the Cordillera. The only novel point in this formation, is the presence of innumerable thin layers of rock-salt, alternating with the laminated and hard, but sometimes earthy, yellowish, or bright red and ferruginous sandstones. The thickest layer of salt was only two inches, and it thinned out at both ends. On one of these saliferous masses I noticed a stratum about twelve feet thick, of dark-brown, hard brecciated, easily fusible rock, containing grains of quartz and of black oxide of iron, together with numerous imperfect fragments of shells. The problem of the origin of salt is so obscure, that every fact, even geographical position, is worth recording. (It is well known that stratified salt is found in several places on the shores of Peru. The island of San Lorenzo, off Lima, is composed of a pile of thin strata, about eight hundred feet in thickness, composed of yellowish and purplish, hard siliceous, or earthy sandstones, alternating with thin layers of shale, which in places passes into a greenish, semi-porcellanic, fusible rock. There are some thin beds of reddish mudstone, and soft ferruginous rotten-stones, with layers of gypsum. In nearly all these varieties, especially in the softer sandstones, there are numerous thin seams of rock-salt: I was informed that one layer has been found two inches in thickness. The manner in which the minutest fissures of the dislocated beds have been penetrated by the salt, apparently by subsequent infiltration, is very curious. On the south side of the island, layers of coal and of impure limestone have been discovered. Hence we here have salt, gypsum, and coal associated together. The strata include veins of quartz, carbonate of lime, and iron pyrites; they have been dislocated by an injected mass of greenish-brown feldspathic trap. Not only is salt abundant on the extreme western limits of the district between the Cordillera and the Pacific, but, according to Helms, it is found in the outlying low hills on the eastern flank of the Cordillera. These facts appear to me opposed to the theory, that rock-salt is due to the sinking of water, charged with salt, in mediterranean spaces of the ocean. The general character of the geology of these countries would rather lead to the opinion, that its origin is in some way connected with volcanic heat at the bottom of the sea: see on this subject Sir R. Murchison “Anniversary Address to the Geological Society” 1843 page 65.) With the exception of these saliferous beds, most of the rocks as already remarked, present a striking general resemblance with the upper parts of the gypseous or cretaceo-oolitic formation of Chile.

METALLIFEROUS VEINS.

I have only a few remarks to make on this subject: in nine mining districts, some of them of considerable extent, which I visited in CENTRAL Chile, I found the PRINCIPAL veins running from between [N. and N.W.] to [S. and S.E.] (These mining districts are Yaquil near Nancagua, where the direction of the chief veins, to which only in all cases I refer, is north and south; in the Uspallata range, the prevailing line is N.N.W. and S.S.E.; in the C. de Prado, it is N.N.W. and S.S.E.; near Illapel, it is N. by W. and S. by E.; at Los Hornos the direction varies from between [N. and N.W.] to [S. and S.E.]; at the C. de los Hornos (further northward), it is N.N.W. and S.S.E.; at Panuncillo, it is N.N.W. and S.S.E.; and, lastly, at Arqueros, the direction is N.W. and S.E.): in some other places, however, their courses appeared quite irregular, as is said to be generally the case in the whole valley of Copiapo: at Tambillos, south of Coquimbo, I saw one large copper vein extending east and west. It is worthy of notice, that the foliation of the gneiss and mica-slate, where such rocks occur, certainly tend to run like the metalliferous veins, though often irregularly, in a direction a little westward of north. At Yaquil, I observed that the principal auriferous veins ran nearly parallel to the grain or imperfect cleavage of the surrounding GRANITIC rocks. With respect to the distribution of the different metals, copper, gold, and iron are generally associated together, and are most frequently found (but with many exceptions, as we shall presently see) in the rocks of the lower series, between the Cordillera and the Pacific, namely, in granite, syenite, altered feldspathic clay-slate, gneiss, and as near Guasco mica-schist. The copper-ores consist of sulphurets, oxides, and carbonates, sometimes with laminae of native metal: I was assured that in some cases (as at Panuncillo S.E. of Coquimbo), the upper part of the same vein contains oxides, and the lower part sulphurets of copper. (The same fact has been observed by Mr. Taylor in Cuba: “London Philosophical Journal” volume 11 page 21.) Gold occurs in its native form; it is believed that, in many cases, the upper part of the vein is the most productive part: this fact probably is connected with the abundance of this metal in the stratified detritus of Chile, which must have been chiefly derived from the degradation of the upper portions of the rocks. These superficial beds of well-rounded gravel and sand, containing gold, appeared to me to have been formed under the sea close to the beach, during the slow elevation of the land: Schmidtmeyer remarks that in Chile gold is sought for in shelving banks at the height of some feet on the sides of the streams, and not in their beds, as would have been the case had this metal been deposited by common alluvial action. (“Travels in Chile” page 29.) Very frequently the copper-ores, including some gold, are associated with abundant micaceous specular iron. Gold is often found in iron-pyrites: at two gold mines at Yaquil (near Nancagua), I was informed by the proprietor that in one the gold was always associated with copper-pyrites, and in the other with iron-pyrites: in this latter case, it is said that if the vein ceases to contain iron-pyrites, it is yet worth while to continue the search, but if the iron-pyrites, when it reappears, is not auriferous, it is better at once to give up working the vein. Although I believe copper and gold are most frequently found in the lower granitic and metamorphic schistose series, yet these metals occur both in the porphyritic conglomerate formation (as on the flanks of the Bell of Quillota and at Jajuel), and in the superincumbent strata. At Jajuel I was informed that the copper-ore, with some gold, is found only in the greenstones and altered feldspathic clay-slate, which alternate with the purple porphyritic conglomerate. Several gold veins and some of copper- ore are worked in several parts of the Uspallata range, both in the metamorphosed strata, which have been shown to have been of probably subsequent origin to the Neocomian or gypseous formation of the main Cordillera, and in the intrusive andesitic rocks of that range. At Los Hornos (N.E. of Illapel), likewise, there are numerous veins of copper- pyrites and of gold, both in the strata of the gypseous formation and in the injected hills of andesite and various porphyries.

Silver, in the form of a chloride, sulphuret, or an amalgam, or in its native state, and associated with lead and other metals, and at Arqueros with pure native copper, occurs chiefly in the upper great gypseous or cretaceo-oolitic formation which forms probably the richest mass in Chile. We may instance the mining districts of Arqueros near Coquimbo, and of nearly the whole valley of Copiapo, and of Iquique (where the principal veins run N.E. by E. and S.W. by W.), in Peru. Hence comes Molina’s remark, that silver is born in the cold and solitary deserts of the Upper Cordillera. There are, however, exceptions to this rule: at Paral (S.E. of Coquimbo) silver is found in the porphyritic conglomerate formation; as I suspect is likewise the case at S. Pedro de Nolasko in the Peuquenes Pass. Rich argentiferous lead is found in the clay-slate of the Uspallata range; and I saw an old silver-mine in a hill of syenite at the foot of the Bell of Quillota: I was also assured that silver has been found in the andesitic and porphyritic region between the town of Copiapo and the Pacific. I have stated in a previous part of this chapter, that in two neighbouring mines at Arqueros the veins in one were productive when they traversed the singular green sedimentary beds, and unproductive when crossing the reddish beds; whereas at the other mine exactly the reverse takes place; I have also described the singular and rare case of numerous particles of native silver and of the chloride being disseminated in the green rock at the distance of a yard from the vein. Mercury occurs with silver both at Arqueros and at Copiapo: at the base of C. de los Hornos (S.E. of Coquimbo, a different place from Los Hornos, before mentioned) I saw in a syenitic rock numerous quartzose veins, containing a little cinnabar in nests: there were here other parallel veins of copper and of a ferrugino-auriferous ore. I believe tin has never been found in Chile.

From information given me by Mr. Nixon of Yaquil (At the Durazno mine, the gold is associated with copper-pyrites, and the veins contain large prisms of plumbago. Crystallised carbonate of lime is one of the commonest minerals in the matrix of the Chilean veins.), and by others, it appears that in Chile those veins are generally most permanently productive, which, consisting of various minerals (sometimes differing but slightly from the surrounding rocks), include parallel strings RICH in metals; such a vein is called a veta real. More commonly the mines are worked only where one, two, or more thin veins or strings running in a different direction, intersect a POOR “veta real:” it is unanimously believed that at such points of intersection (cruceros), the quantity of metal is much greater than that contained in other parts of the intersecting veins. In some cruceros or points of intersection, the metals extend even beyond the walls of the main, broad, stony vein. It is said that the greater the angle of intersection, the greater the produce; and that nearly parallel strings attract each other; in the Uspallata range, I observed that numerous thin auri-ferruginous veins repeatedly ran into knots, and then branched out again. I have already described the remarkable manner in which rocks of the Uspallata range are indurated and blackened (as if by a blast of gunpowder) to a considerable distance from the metallic veins.