Relative Importance.

In Chapter VI. we pointed out that of the three manurial ingredients potash was the one most abundantly occurring, and that, consequently, the necessity of adding it in the form of an artificial manure existed less frequently than in the case of nitrogen or phosphoric acid. It was further pointed out that, under the ordinary conditions of agriculture, a greater restoration to the soil of the potash removed in the crops was made in the straw used in farmyard manure than was the case with regard to the other two ingredients. Despite these facts, there are many cases where the addition of potassic manures is of the highest importance in increasing plant-growth. It will be well, therefore, to devote a little space to considering our different potassic manures and their respective action.

Scottish Soils supplied with Potash.

Potassic manures are not so valuable in this country since experience has shown that most Scottish soils are abundantly supplied with this manurial ingredient. Moreover, under the conditions of most European farming, there seems to be a steady gain to the soil of potash. In America, however, the action of potash as a manure seems to be more strikingly illustrated. Indeed, wherever forage crops or straw are sold off the farm in large quantities, or where beets, cabbages, carrots, potatoes, onions, &c., are also grown in large quantities, the necessity for potash manuring generally arises.

Sources of Potassic Manures.

The value of potash as a manure first came to be recognised from the favourable action of wood-ashes. Of course their favourable action is not due solely to potash, as they contain, in addition to the other ash ingredients of the plant, phosphates; and their value as a manure may also be said to depend not a little on their indirect action. They contain a certain percentage of caustic alkali, which promotes the decomposition of the nitrogenous matter of the soil. But making due allowance for these other valuable properties, the chief value of wood-ashes is undoubtedly due to the potash they contain. Hence the use of the commercial article called potash, which is a mixture of potassium carbonate and hydrate, and which is obtained from wood-ashes, was formerly common to a considerable extent as a manure, especially for clover. Barilla, a rich potassic manure prepared by burning certain strand plants, especially the saltwort, was also in the past largely exported from Sicily and Spain. Kelp, a product got by burning sea-weed in Scotland, is also a rich potassic manure. Since, however, the discovery of the Stassfurt mines, all potassic manures have come from these.

Stassfurt Potash Salts.

Huge salt deposits exist at Stassfurt in Germany. They have been formed by the evaporation of an inland sea. Salt was first discovered in these deposits in 1839, but for long the presence of potash salts was little suspected, and it was not until 1862 that the potash salts were worked. We have already, in the Appendix to Chapter VI., given a list of the chief potash minerals occurring in the Stassfurt deposits. These minerals are found in layers, the lowest layer consisting of almost pure salt; while immediately above this we have a layer of salt mixed with the mineral polyhallite (containing potassium sulphate) of about 100 feet thick. Above this last layer there is a layer of about 90 feet, containing kieserite (magnesium sulphate) mixed with potassium and magnesium chlorides; and above this again is a layer (90 feet) of carnallite, which furnishes the chief source of the potash salts used for manurial purposes.

At first the crude salts, as obtained direct from the deposits, were sold as manures under the name of Abraum salts. Now, however, they are purified. Of potash salts in 1888 some 25,000 tons were exported from Stassfurt for manurial purposes. Of these salts there may be mentioned, viz., kainit, an impure form of the sulphate, containing on an average about 12 per cent of potash, and the muriate and the sulphate—both salts, in a more or less pure form, being used. A word or two may be added on the effect of the two forms of potash—viz., as the sulphate and as the muriate.

Relative Merits of Sulphate and Muriate of Potash.