CHAPTER III.
THE POSITION OF NITROGEN IN AGRICULTURE.
Of manurial ingredients, nitrogen is by far the most important, and on the presence and character of the nitrogen it contains, the fertility of a soil may be said to be most largely dependent. Most soils, as a rule, are better supplied with available ash ingredients than with available nitrogen compounds. The expensive nature of most artificial nitrogenous manures also gives to nitrogen the first position from an economic point of view. A thorough study, therefore, of the different forms in which it exists in nature, of the numerous and complicated changes it undergoes in the soil, by which it is prepared for the plant's needs, of the relation of its different forms to plant-life, and of the natural sources of its loss and gain, is of the highest importance if we are to hope to understand the difficult question of soil-fertility.
The Rothamsted Experiments and the Nitrogen question.
The position of nitrogen in agriculture is a question of great difficulty and complexity. It has engaged much attention, and has had devoted to its elucidation much elaborate and painstaking research. To the Rothamsted experiments we owe most of the information we possess on the subject, and the facts contained in this chapter are almost entirely derived from the results of these famous experiments, as embodied in the memoirs and writings of Messrs Lawes, Gilbert, and Warington.
Different forms in which Nitrogen exists in Nature.
We have already referred to the nitrogen question in the historical introduction. In order, however, to have a comprehensive view of the subject, it may be well to recapitulate some of the facts there mentioned.
Nitrogen, as we have already seen, exists in the "free" or elementary condition, as nitrates and nitrites, as ammonia, and in a large number of different organic forms.
Nitrogen in the Air.
It occurs in greatest abundance (amounting to about 80 per cent) in the first of these forms in the air. That this free nitrogen, which is practically unlimited in quantity,[63] has originally been the source of all its other forms, is of course obvious. But this conversion of free nitrogen into the various compound forms in which it occurs throughout the mineral, vegetable, and animal kingdoms, has been a process effected by a variety of indirect methods, and only at the expense of a vast amount of time. For practical purposes, the free nitrogen of the air may be regarded chiefly as a non-available source for most bodies containing it. It may be described as of all forms of nitrogen the least active, as far as plant-life is concerned.