Occurrence of Potash in the Soil.
From what has been said regarding the richness in potash of certain commonly occurring minerals, such as felspar, it is only natural to infer that most soils must contain large quantities of this substance; and this is so. The wonder is that potash, when applied as an artificial manure, should have such a marked effect in increasing the fertility of the soil, as is often the case. We must remember, however, that although a soil may contain large quantities of potash, there may be a very small percentage of the whole in an available form for the plant's needs.
Potash chiefly in insoluble Condition in Soils.
Potash occurs almost entirely in soils in a very insoluble form—viz., combined with silica as a silicate of potash. It is only by the slow disintegration of potash rocks that the potash they contain is set free for plant uses. When it is applied as an artificial manure, on the other hand, it is in a soluble form. In most soils the amount soluble in water probably lies between .001 and .009 per cent; that soluble in dilute acid solutions from .1 to .5 per cent; and that insoluble from .2 to 3.5 per cent of the soil. It is highly probable that a certain quantity of potash in the soil may exist in combination with humic and ulmic acids, forming insoluble potassium humates and ulmates.
Potash in Plants.
Of all the ash ingredients of plants, potash is the most abundant, as it forms on an average about 50 per cent of the total ash of plants—about 90 per cent of the alkalies. The ash of plants, indeed, was for long the chief source of potash. Certain plants remove very large quantities from the soil. Of these roots, potatoes, the vine, the tobacco-plant, and hops may be mentioned as examples. It is present in large quantities in the grain of cereals, although, as we have already pointed out, not to the same proportional extent as phosphoric acid. It is found in the plant's extremities, such as twigs and new leaves, in greatest abundance.[129]
Potash in the Animal Tissue.
It is also found in all parts of the animal body. Especially rich in potash salts are the blood corpuscles, which contain about ten times the amount contained in the serum. It is found in especial abundance in the fleece of sheep, which may contain more potash than that in the whole body of the sheep. Animal urine also contains potash in considerable quantities.
Sources of Loss of Potash.
The capacity of the soil to retain soluble potash compounds, while not equal to its capacity for retaining phosphoric acid, is yet very much in excess of its capacity for retaining nitrates. The result is, that potash is only found in comparatively minute traces in drainage water.[130] Taking the same example as we already cited in illustration of the loss of phosphoric acid, we find that the amount carried away in the course of a year in the waters of the Elbe from Bohemia is 97,000,000 lb. (43,300 tons).