“Monsieur the Comte de Buffon, in a journey to Dijon, in the summer of 1773, having caused me to remark in half a drachm of plati na, which M. de Baume had sent him in 1768, grains in form of buttons, others flatter, and some black and scaly; and having separated by the loadstone those which are attractable from those which appeared not so, I tried to form Prussian blue with both. I sprinkled the fuming nitrous acid on the non-attractable parts, which weighed 21/2 grains. Six hours after I put distilled water on the acid, and sprinkled alkaline liquor, saturated with a colouring matter; however there was not a single atom of blue, the platina had only a little more brightness. I alike sprinkled the fuming acid on the remaining platina, part of which was attractable, the same Prussian alkali precipitated a blue feculency, which covered the bottom of a pretty large bason. The platina, after this operation, shewed like the first. I washed and dried it, and found it had not lost 1/4 of a grain, or 1/138 part; having examined it in this state I perceived a grain of beautiful yellow, which was pure gold.
“M. de Fourcy had lately told the world, that the dissolution of gold was thrown down in a blue precipitate by the Prussian alkali, and had placed this circumstance in a table of affinity; I was tempted to repeat this experi ment, and sprinkled, in consequence, the phlogisticated alkaline liquor in the dissolution of gold, but the colour of this dissolution did not change, which made me suspect that the dissolution of gold made use of by M. de Fourcy might possibly not have been so pure.
“At the same time the Comte de Buffon having given me a sufficient quantity of platina to make further assays, I undertook to separate it from all foreign bodies by a good front; and I have here subjoined the processes and their results.
EXPERIMENTS.
“I. Having put a drachm of platina, in a cupel, into a furnace, I kept up the fire two hours, when the covers sunk down, the supporters having run, nevertheless the platina was only agglutinated; it stuck to the cupel, and had left spots of a rusty colour. The platina was then tarnished, even a little black, and had only augmented a quarter of a grain in weight; a quantity very small in comparison with that which other chemists have observed. What surprised me still more was, that this drachm of platina, as well as that I used for other experiments, had been successively carried away by the load stone, and made a portion of 6/7 of eight ounces, of which the Comte de Buffon has before spoken.
“II. Half a drachm of the same platina, exposed to the same fire in a cupel, was also agglutinated; I adhered to the cupel, on which it had left spots of a rusty colour; the augmentation of weight was found to be nearly in the same proportion, and the surface as black.
“III. I put this half drachm into a new cupel, but instead of a cover I placed over it a leaden crucible. This I kept in the most extreme heat for four hours; when it was cooled I found the crucible soldered to the support, and having broken it I perceived that nothing had penetrated into the internal part of the crucible, which appeared to be only more glossy than before. The cupel had preserved its form and position; it was a little cracked, but not enough to admit of any penetration; the platina was also not adherent to it, though agglutinated, but in a much more intimate manner than in the first experiments; the grains were less angular, the colour more clear, and the brilliancy more metallic. But what was the most remarkable during the operation, there issued from its surface, probably in the first moments of its refrigeration, three drops of water, one of which, that arose perfectly spherical, was carried up on a small pedicle of the vitreous and transparent matter. It was of an uniform colour, with a slight tint of red, which did not deprive it of any transparency; the smallest of the other two drops had likewise a pedicle, and the other none, but was only attached to the platina by its external surface.
“IV. I endeavoured to assay the platina, and for that intent put a drachm of the grains taken up by the loadstone into a cupel, with two drachms of lead. After having kept up a very strong fire for two hours, I found an adherent button, covered with a yellowish and spungeous crust of two drachms twelve grains weight, which announces that the platina had retained one drachm twelve grains of lead. I put this button into another cupel in the same furnace, observing to turn it, by which it only lost twelve grains in two hours; its colour and form were very little changed. The same piece of platina was put into Macquer’s furnace, and a fire kept up for three hours, when I was obliged to take it out, because the bricks began to run. The platina was become more metallic, but it, nevertheless, adhered to the cupel, and this time it lost 34 grains. I threw it into the fuming nitrous acid to assay it, and there arising a little effervescence, I added distilled water thereon. The platina lost two grains, and I remarked some small holes, like those which its flying off might occasion.
“There then remained only 22 grains of lead in the platina. I began to form a hope of vitrifying this remaining portion of lead, for which purpose I put the same piece of platina into a new cupel, and by the care I took for the admission of air, and other precautions, the activity of the fire was so greatly augmented that it required a supply every eleven minutes; to this degree of heat we kept for four hours, and then permitted it to cool.
“I perceived the next morning that the leaden crucible had resisted, and that the supporters were only glazed by the cinders. I found a piece in the cupel, not adhering, of a uniform colour, approaching more the colour of tin than any other metal, but only a little ragged. It weighed exactly one drachm. All, therefore, announced that this platina had endured an absolute fusion, and that it was perfectly pure, for if we suppose it still contained lead, we must then admit that it had lost exactly as much of its substance as it had gained of foreign matter; and such a precision cannot be the effect of pure chance.