Table 5 gives a comparison of the results obtained by the two methods.

TABLE 5.—COMPARISON OF RESULTS BY METHODS 1 AND 2

Method 1Method 2
Research Council Spec.16.3118.85
Merck & Co. 4.56 3.92
Heyden Chemical Works 0.68 0.97

The results obtained in Method 1 (the percolation method) apparently are reliable and, as the method is the more simple, may be given preference.

COMBINED TRIBROMPHENOL (TRIBROMPHENATE)

The amount of tri­brom­phenol existing in the specimen in combination was calculated by subtracting from the per cent. of total tri­brom­phenol determined, the per cent. of free tri­brom­phenol found by Method 1.

The figures obtained are given in Table 6.

TABLE 6.—THE TRIBROMPHENATE CONTENT OF BISMUTH TRIBROMPHENATE

Per Cent. of
Combined
Tribromphenol
Research Council Specimen43.13
Merck & Co.53.19
Heyden Chemical Works20.36