In the ultimate decomposition of organic matter the carbon appears in the form of carbon dioxid which when combined with water forms carbonic acid. Though this is a very weak acid, its solvent action is very important.
But, in addition to the various organic acids and carbonic acid, we have also to consider the formation of nitric acid in connection with the decomposition of organic manures. Nitric acid is one of the strongest known, and in solvent power it is excelled by no single acid. The nitrogen contained in crop residues and other organic manures is chiefly in chemical combination with carbon, oxygen and hydrogen, much of it in insoluble protein compounds. Normally this organic nitrogen is transformed in the soil, first into ammonia nitrogen, next into nitrite nitrogen, and lastly into nitrate nitrogen, these three transformations being effected by biochemical action produced by different kinds of living microscopic organisms called bacteria. Though detectable amounts of free nitric acid do not accumulate during this process of nitrification, the soluble nitrate or final product is formed by the action of nitric acid upon a mineral base, such as calcium, magnesium, or potassium, which may have been in the soil in insoluble form, so that the nitrogen must pass through the form of nitric acid in the transformation into nitrates.
While the organic matter applied to the soil contains about twenty times as much carbon as nitrogen, and while corresponding amounts of carbonic acid and important amounts of intermediate organic acids must be formed, it is of much interest to know that even the nitric acid formed in the transformation of organic nitrogen to nitrate nitrogen in sufficient quantity for a given crop is seven times as much acid as would be required to convert raw rock phosphate into soluble phosphate to furnish the phosphorus required for the same crop. A knowledge of this definite quantitative relationship should help us to appreciate the possibilities of decaying organic manures in the important matter of making plant food available, including potassium, calcium and magnesium as well as phosphorus and nitrogen.
The value of rye, rape, buckwheat and other non-legumes when used as green manures is very largely due to the liberation of plant food by their decomposition in contact with the natural phosphates, potash and other minerals contained in the soil. The farmer has no more important business than that of making plant food available, especially by supplying liberal amounts of decaying organic matter.
The following suggestions are offered to the land owner:
To enrich the soil apply liberal amounts of limestone, organic manures and phosphorus.
To enrich the seller apply small amounts of high-priced "complete" commercial fertilizers.
Thus the average of seventy-three "Cooperative Fertilizer Tests on Clay and Loam Soils," extending into thirty-eight different counties in Indiana (Bulletin 155), shows 13 cents as the farmer's profit from each dollar spent for "complete" fertilizers used for corn, oats, wheat, timothy, and potatoes, if valued in the field at 40 cents a bushel for corn, 30 cents for oats, 80 cents for wheat, 50 cents for potatoes, and at $10 a ton for hay, over and above the extra expense for harvesting and marketing the increase, and of course the soil grows poorer, because the crops harvested removed much more plant food than the fertilizers supplied.