The Life of Sir Isaac Newton

by David Brewster

“For the production of black,” says he, “the corpuscles must be less than any of those which exhibit colours. For at all greater sizes there is too much light reflected to constitute this colour. But if they be supposed a little less than is requisite to reflect the white and very faint blue of the first order, they will reflect so very little light as to appear intensely black, and yet may perhaps variously refract[20] it to and fro within themselves so long, until it happens to be stifled and lost, by which means they will appear black in all positions of the eye, without any transparency.”

This very remarkable passage exhibits, in a striking manner, the perplexity in which our author was involved by the difficulties of his subject. As the particles which produce blackness by reflection are necessarily so small as to exclude the existence of any reflective forces, he cannot ascribe the loss of the intromitted light, as he does in the case of white opacity, to “a multitude of reflections;” and therefore he is compelled to have recourse to refracting forces to perform the same office. The reluctance with which he avails himself of this expedient is well marked in the mode of expression which he adopts; and I am persuaded that when he wrote the above passage, he felt the full force of the objections to this hypothesis, which cannot fail to present themselves. As the size of the particles which produce blackness are intermediate between those which produce transparency and those which produce colour, approaching closely to the latter, it is difficult to conceive why they should refract the intromitted light, while the greater and smaller particles, and even those almost of the same size, should be destitute of that property. It is, besides, not easy to understand how a refraction can take place within bodies which shall stifle all the light, and prevent it from emerging. Nay, we may admit the existence of such refractions, and yet understand how, by a compensation in their direction, the refracted rays may all emerge from the opaque body.

The force of these objections is tacitly recognised in Pemberton’s View of Sir Isaac Newton’s Philosophy;[21] and as Newton not only read and approved of that work, but even perused a great part of it along with its author, we may fairly consider the opinion there stated to be his own.

“For producing black, the particles ought to be smaller than for exhibiting any of the colours, viz. of a size answering to the thickness of the bubble, whereby reflecting little or no light, it appears colourless; but yet they must not be too small, for that will make them transparent through deficiency of reflections in the inward parts of the body, sufficient to stop the light from going through it; but they must be of a size bordering upon that disposed to reflect the faint blue of the first order, which affords an evident reason why blacks usually partake a little of that colour.” In this passage all idea of refraction is abandoned, and that precise degree of size is assumed for the particles which leaves a small power of reflection, which is deemed sufficient to prevent the body from becoming transparent; that is, sufficient to render it opaque or black.

The last objection which we shall state to this theory is one to which we attach great weight, and, as it is founded on discoveries and views which have been published since the time of Newton, we venture to believe, that, had he been aware of them, he would never have proposed the theory which we are considering.

When light falls upon a thin film such as AEC, [fig. 9], p. 80, so as to produce the colours of thin plates, it follows, from Sir Isaac Newton’s theory of fits, that a portion of the light is, as usual, reflected at the first surface AE,[22] while the light which forms the coloured image is that which is reflected from the second surface EC, so that all the colours of thin plates are diluted with the white light reflected from the first surface. Now, in the modern theory, which ascribes the colours of thin plates to the interference of the light reflected from the second surface EC, with the light reflected from the first surface AE, the resulting tint arises from the combination of these two pencils, and consequently there is no white light reflected from the surface AE. In like manner, when the thickness of the film is such that the two interfering pencils completely destroy one another, and produce black, there is not a ray of light reflected from the first surface. Here, then, we have a criterion for deciding between the theory of fits and the theory of interference; for if there is no white light reflected from the first surface AE, the theory of fits must be rejected. In a remarkable phenomenon of blackness arising from minute fibres, which I have had occasion to describe, there was no perceptible reflection from the surface of the fibres;[23] and M. Fresnel describes an experiment made to determine the same point, and states the result of it to have been unequivocally in favour of the doctrine of interference.

In order to apply this important fact, let us take a piece of coal, one of the blackest and most opaque of all substances, and which does not reflect to the eye a single ray out of those which enter its substance. The size of its particles is so small, that they are incapable of reflecting light. When a number of these particles are placed together, so as to form a surface, and other particles behind them, so as to form a solid, they will not acquire by this process the power of reflection; and consequently, a piece of coal so composed should be destitute of the property of reflecting light from its first surface. But this is not the case,—light is abundantly reflected from the first surface of the coal, and consequently, its elementary particles must possess the same power. Hence the blackness of coal must be ascribed to some other cause than to the minuteness of its transparent atoms.

To transparent bodies this argument has a similar application. As their atoms are still less than those of black bodies, their inability to reflect light is still greater, and hence arises their transparency. But the particles forming the surface of such bodies do reflect light, and, therefore, their transparency must have another origin.

In the case of coloured bodies, too, the particles forming their surfaces reflect white light like those of all other bodies, so that these particles cannot produce colour on the same principles as those of thin plates. In many of those cases of colour which seem to depend upon the minuteness of the particles of the body, the reflection of white light may nevertheless be observed, but this will be found to arise from a thin transparent film, behind which the colorific particles are placed.

Whatever answer may be given to these objections, we think it will be admitted by those who have studied the subject most profoundly, that a satisfactory theory of the colours of natural bodies is still a desideratum in science. How far we may be able to approach to it in the present state of optics the reader will judge from the following views.