Concentrated and dilute Nitric Acid Red Red-Yellow
" Sulphuric Acid . . Black Dark Purple
Dilute " " Red Brown Purple
Potassium Chromate . . . . Black
Stannous Chloride Violet Yellow
Tartaric Acid . . . . . Gray-Brown Yellow
Sulphate of Copper . . . . Dark Gray
Tannin . . . . . . Yellow-Red Yellow
Potash Dark Red Yellow
Potassium Permanganate Light-Brown Yellow
" Iodide . . . . . Red-Yellow
Pyrogallic Acid . . . . Yellow-Brown Yellow
Chrome-yellow . . . . . Dark Violet
Sodium (Salt) Violet Red
Sulphate of Iron Gray to Black
Alum . . . . . . . Violet Red,Brown. Faint Red
BRAZIL WOOD. MADDER.
Concentrated Hydrochloric Acid Light Red Pale Yellow
Dilute " " Light Red Pale Yellow
Concentrated and dilute Nitric Acid Dark Purple Pale Yellow
" Sulphuric Acid . . Red Pale Yellow
Dilute " " Purple Pale Yellow
Potassium Chromate . . . . - -
Stannous Chloride Light Red Light Red
Tartaric Acid . . . . . Red Yellow Pale Yellow
Sulphate of Copper . . . . - -
Tannin . . . . . . No Change Pale Yellow
Potash Crimson Light Red
Potassium Permanganate - -
Iodide . . . . . - -
Pyrogallic Acid . . . . - -
Chrome-yellow . . . . . - -
Sodium (Salt) - Red
Sulphate of Iron Dark Violet -
Alum . . . . . . . - Faint Red
CHAPTER XIX.
FRAUDULENT INK BACK GROUNDS.
DETECTION OF ALTERATIONS IN DOCUMENTS BY CHEMICAL TESTS WHICH APPLY SOLELY TO THE PAPER—ACCURACY OF RESULTS OBTAINED BY USE OF IODINE EXCELS THAT OF ALL OTHER CHEMICALS—IT APPLIES BEST TO LINEN PAPER—MODERN HARD PAPER DOES NOT GIVE COMPLETE INFORMATION—EFFECT OF IODINE ON MARKS MADE BY A STYLUS OR GLASS PEN.
FIFTY years ago and long before the employment of the fugitive "anilines" for ink uses, and "wood pulp" as a material for paper, two French chemists, Chevallier and Lassiagne, published in the Journal de Chimie Medical, an article "On the Means to be Employed for Detecting and Rendering Perceptible Fraudulent Alterations in Public and Private Documents," which as translated is valuable enough to quote in full:
"The numerous experiments which have been already tried at various times, have made known the processes which may frequently be put in practice for causing the reappearance of traces of writing effaced by chemical reactions, and for throwing light on the work of the guilty. But there are cases in which all the means proposed for this purpose fail, and then the criminal may escape justice from the want of conclusive material proofs. If, as has already been proved, it is not always possible to cause the reappearance of the effaced writing, for which written words have with a fraudulent intent been substituted, at least, as our experiments demonstrates, we may recognize, by some effects which are manifest on the surface of the altered paper, the places where the criminal act has been performed, circumscribe them by a simple chemical reaction visible to the least practiced eye, and even measure their extent. In a word, the visible alterations produced on a deed are susceptible, owing to the partial modifications which the surface of the paper has undergone, of being differently affected by certain chemical actions, and of being rendered visible. The following experiments, made in a judicial investigation, furnish us with the following facts:
"1st. The surface of paper sized in the ordinary way, or letter paper, no longer presents with certain reactions, the same uniformity where it has been either accidently moistened in several places by various liquids, or left in contact for a certain time with agents capable of removing or destroying the characters which have been traced on it with ink.