Figure 9.—Florida river-pebble phosphate mining. (From Carroll D. Wright, The Phosphate Industry of the United States ..., plate facing page 64.)
The insight into the importance of phosphorus in organisms, especially since Liebig’s time, is reflected in the work of Friedrich Nietzsche (1844-1900). This “re-valuator of all values” who modestly said of himself: “I am dynamite!” once explained the human temperaments as caused by the inorganic salts they contain: “The differences in temperament are perhaps caused more by the different distribution and quantities of the inorganic salts than by everything else. Bilious people have too little sodium sulfate, the melancholics are lacking in potassium sulfate and phosphate; too little calcium phosphate in the phlegmatics. Courageous natures have an excess of iron phosphate.” (See volume 12 of Nietzsche’s Works, edit. Naumann-Kröner, Leipzig, 1886.) In this strange association of inorganic salts with human temperaments, the role of iron phosphate as a producer of courage is particularly interesting. What would a modern philosopher conclude if he followed the development of insight into the composition and function of complex phosphate compounds in organisms?
From Inorganic to Organic Phosphates
By the middle of the 19th century, the source of phosphorus in natural phosphates and the chemistry of its oxidation products had been established. The main difficulty that had to be overcome was that these oxidation products existed in so many forms, not only several stages of oxidation, but, in addition, aggregations and condensations of the phosphoric acids. Once the fundamental chemistry of these acids was elucidated, the attention of chemists and physiologists turned to the task of finding the actual state in which phosphorus compounds were present in the organisms. It had been a great advance when it had been shown that plants need phosphates in their soil. This led to the next question concerning the materials in the body of the plant for which phosphates were being used and into which they were incorporated. Similarly, the knowledge that animals attain their phosphates from the digested plant food called, in the next step of scientific inquiry, for information on the nature of phosphates produced from this source.
The method used in this inquiry was to subject anatomically separated parts of the organisms to chemical separations. The means for such separations had to be more gentle than the strong heat and destructive chemicals that had been considered adequate up to then. The interpretation of the new results naturally relied on the general advance of chemistry, the development of new methods for isolating substances of little stability, of new concepts concerning the arrangements of atoms in the molecules, and of new apparatus to measure their rates of change.
Figure 10.—Electric furnace for producing elemental phosphorus, invented by Thomas Parker of Newbridge, England, and assigned to The Electric Construction Corporation of the same place. The drawing is part of United States patent 482,586 (September 13, 1892). The furnace was patented in England on October 29, 1889 (no. 17,060); in France on June 23, 1890 (no. 206,566); in Germany on June 17, 1890 (no. 55,700); and in Italy on October 23, 1890 (no. 431). The following explanation is cited from the U.S. patent:
Figure 1 [shown here] is a vertical section of the furnace, and Fig. 2 is a diagram to illustrate the means for regulating the electro-motive force or quantity of current across the furnace.
F is the furnace containing the charge to be treated. It has an inlet-hopper at a, with slides AA, by which the charge can be admitted without opening communication between the interior of the furnace and the outer air.
B is a screw conveyer by which the charge is pushed forward into the furnace.
c´c´ are the electrodes, consisting of blocks or cylinders or the like of carbon fixed in metal socket-pieces c c, to which the electric-circuit wires d from the dynamo D are affixed. The current, as aforesaid, may be either continuous or alternating. c2c2 are rods of metal or carbon, which are used to establish the electric circuit through the furnace, the said rods being inserted into holes in conductors c3 (in contact with the socket-pieces c) and in the furnace, as shown.
g is the outlet for the gas or vapor, h the slag-tap hole, and x the opening for manipulating the charge, the said openings being closed by clay or otherwise when the furnace is at work.
I use coke or other form of carbon in the charge between the electrodes c´, the said coke being in contact with the said electrodes, so that complete incandescence is insured.
A means for varying the electro-motive force or quantity of current across the furnace with the varying resistance of the charge is illustrated by the diagram, Fig. 2. c´ c2 indicate the electrodes in the furnace, as in Fig. 1, and D is the dynamo and T its terminals. E represents the exciting-circuit. R R are resistances, and R S is the resistance-switch, which is operated to put in more or less resistance at R as the resistance of the charge in the furnace lessens or increases. This switch may be automatically operated, and a suitable arrangement for the purpose is a current-regulator such as is described in the specification of English Letters Patent No. 14,504, of September 14, 1889, granted to William Henry Douglas and Thomas Hugh Parker.