In the early days of coal-mining the explosions caused by this gas soon received the serious attention of the scientific men of the age. In the Philosophical Transactions of the Royal Society we find a record of a gas explosion in 1677. The amusing part of such records was that the explosions were ascribed by the miners to supernatural agencies. Little attention seemed to have been paid to the fact, which has since so thoroughly been established, that the explosions were caused by accumulations of gas, mixed in certain proportions with air. As a consequence, tallow candles with an exposed flame were freely used, especially in Britain. These were placed in niches in the workings, where they would give to the pitman the greatest amount of light. Previous to the introduction of the safety-lamp, workings were tested before the men entered them, by "trying the candle". Owing to the specific gravity of fire-damp (.555) being less than that of air, it always finds a lodgement at the roofs of the workings, so that, to test the condition of the air, it was necessary to steadily raise the candle to the roof at certain places in the passages, and watch carefully the action of the flame. The presence of fire-damp would be shown by the flame assuming a blue colour, and by its elongation; the presence of other gases could be detected by an experienced man by certain peculiarities in the tint of the flame. This testing with the open flame has almost entirely ceased since the introduction of the perfected Davy lamp.
The use of candles for illumination soon gave place in most of the large collieries to the introduction of small oil-lamps. In the less fiery mines on the Continent, oil-lamps of the well-known Etruscan pattern are still in use, whilst small metal lamps, which can conveniently be attached to the cap of the worker, occasionally find favour in the shallower Scotch mines. These lamps are very useful in getting the coal from the thinner seams, where progress has to be made on the hands and feet. At the close of the last century, as workings began to be carried deeper, and coal was obtained from places more and more infested with fire-damp, it soon came to be realised that the old methods of illumination would have to be replaced by others of a safer nature.
It is noteworthy that mere red heat is insufficient in itself to ignite fire-damp, actual contact with flame being necessary for this purpose. Bearing this in mind, Spedding, the discoverer of the fact, invented what is known as the "steel-mill" for illuminating purposes. In this a toothed wheel was made to play upon a piece of steel, the sparks thus caused being sufficient to give a moderate amount of illumination. It was found, however, that this method was not always trustworthy, and lamps were introduced by Humboldt in 1796, and by Clanny in 1806. In these lamps the air which fed the flame was isolated from the air of the mine by having to bubble through a liquid. Many miners were not, however, provided with these lamps, and the risks attending naked lights went on as merrily as ever.
In order to avoid explosions in mines which were known to give off large quantities of gas, "fiery" pits as they are called, Sir Humphrey Davy in 1815 invented his safety lamp, the principle of which can be stated in a few words.
If a piece of fine wire gauze be held over a gas-jet before it is lit, and the gas be then turned on, it can be lit above the gauze, but the flame will not pass downwards towards the source of the gas; at least, not until the gauze has become over-heated. The metallic gauze so rapidly conducts away the heat, that the temperature of the gas beneath the gauze is unable to arrive at the point of ignition. In the safety-lamp the little oil-lamp is placed in a circular funnel of fine gauze, which prevents the flame from passing through it to any explosive gas that may be floating about outside, but at the same time allows the rays of light to pass through readily. Sir Humphrey Davy, in introducing his lamp, cautioned the miners against exposing it to a rapid current of air, which would operate in such a way as to force the flame through the gauze, and also against allowing the gauze to become red-hot. In order to minimise, as far as possible, the necessity of such caution the lamp has been considerably modified since first invented, the speed of the ventilating currents not now allowing of the use of the simple Davy lamp, but the principle is the same.
During the progress of Sir Humphrey Davy's experiments, he found that when fire-damp was diluted with 85 per cent. of air, and any less proportion, it simply ignited without explosion. With between 85 per cent. and 89 per cent. of air, fire-damp assumed its most explosive form, but afterwards decreased in explosiveness, until with 94-1/4 per cent. of air it again simply ignited without explosion. With between 11 and 12 per cent. of fire-damp the mixture was most dangerous. Pure fire-damp itself, therefore, is not dangerous, so that when a small quantity enters the gauze which surrounds the Davy lamp, it simply burns with its characteristic blue flame, but at the same time gives the miner due notice of the danger which he was running.
[Illustration: FIG. 32.—Gas Jet and Davy Lamp.]
With the complicated improvements which have since been made in the Davy lamp, a state of almost absolute safety can be guaranteed, but still from time to time explosions are reported. Of the cause of many we are absolutely ignorant, but occasionally a light is thrown upon their origin by a paragraph appearing in a daily paper. Two men are charged before the magistrates with being in the possession of keys used exclusively for unlocking their miners' safety-lamps. There is no defence. These men know that they carry their lives in their hands, yet will risk their own and those of hundreds of others, in order that they may be able to light their pipes by means of their safety-lamps. Sometimes in an unexpected moment there is a great dislodgement of coal, and a tremendous quantity of gas is set free, which may be sufficient to foul the passages for some distance around. The introduction or exposure of a naked light for even so much as a second is sufficient to cause explosion of the mass; doors are blown down, props and tubbing are charred up, and the volume of smoke, rushing up by the nearest shaft and overthrowing the engine-house and other structures at the mouth, conveys its own sad message to those at the surface, of the dreadful catastrophe that has happened below. Perhaps all that remains of some of the workers consists of charred and scorched bodies, scarcely recognisable as human beings. Others escape with scorched arms or legs, and singed hair, to tell the terrible tale to those who were more fortunately absent; to speak of their own sufferings when, after having escaped the worst effects of the explosion, they encountered the asphyxiating rush of the after-damp or choke-damp, which had been caused by the combustion of the fire-damp. "Choke-damp" in very truth it is, for it is principally composed of our old acquaintance carbonic acid gas (carbon dioxide), which is well known as a non-supporter of combustion and as an asphyxiator of animal life.
It seems a terrible thing that on occasions the workings and walls themselves of a coal-mine catch fire and burn incessantly. Yet such is the case. Years ago this happened in the case of an old colliery near Dudley, at the surface of which, by means of the heat and steam thus afforded, early potatoes for the London market, we are told, were grown; and it was no unusual thing to see the smoke emerging from cracks and crevices in the rocks in the vicinity of the town.
From fire on the one hand, we pass, on the other, to the danger which awaits miners from a sudden inrush of water. During the great coal strike of 1893, certain mines became unworkable in consequence of the quantity of water which flooded the mines, and which, continually passing along the natural fractures in the earth's crust, is always ready to find a storage reservoir in the workings of a coal-mine. This is a difficulty which is always experienced in the sinking of shafts, and the shutting off of water engages the best efforts of mining engineers.