As you have already surmised, liquid air is a product of intense cold. Any method that will reduce the temperature of the air to 312 degrees Fahrenheit below zero will liquefy it. Great pressure will not do this, for we may compress air in a strong vessel until the pressure on every square inch of the vessel is 12,000 pounds, or six tons, and still it will not liquefy unless the temperature is brought down to the required degree of coldness. If this is done it will change from a gas to a liquid, but will occupy as much space as before, if it is condensed to a pressure of six tons to the square inch.
Until twenty years ago it was supposed that oxygen and atmospheric air (the latter a mixture of oxygen and nitrogen) were fixed gases and could not be liquefied. In 1877, it is said that Raoul Pictet obtained the first liquid oxygen, but only a few drops. About fifteen years later Professor Dewar of the Royal Institution, London, succeeded in liquefying not only oxygen but atmospheric air. And besides liquefying the air he made ice of it.
In 1892 I visited London, where I met Professor Dewar, who invited me to witness an exhibition of the manufacture of liquid oxygen—and incidentally liquid air—at the Royal Institution. To me it was a most wonderfully interesting event. I saw air, taken from the room, gradually liquefy in a small glass test tube open at the top. When the tube was withdrawn from the refrigerating chamber it boiled by the heat of the room, and rapidly evaporated. We lighted a splinter of wood and blew it out, leaving a live spark on the end of it, and held it over the mouth of the tube, knowing that if anything like pure oxygen were evaporating the splinter would relight and blaze (an old experiment with oxygen gas). At first the splinter would not relight, because the evaporating gases were a mixture of oxygen and nitrogen in the proportions to form air. But owing to the fact that nitrogen evaporates sooner than oxygen, a second trial was successful, for the splinter immediately began to blaze, showing that the gas evaporating then was pure, or nearly pure, oxygen.
When the liquid oxygen was poured into a saucer and brought into proximity with the poles of a powerful magnet the liquid immediately rushed out of the saucer and clung to the magnet poles; showing that oxygen is magnetic.
Since that time other experimenters have succeeded in making liquid air on a comparatively large scale, and the process is simple when we consider some of the old methods.
Mr. Tripler of New York, who has made liquid air in great quantities, does it substantially as follows: First, he compresses air to about 2500 pounds to the square inch. Of course the air is very hot when it is first compressed because all the air in the tank has been reduced in bulk about 166 times, and all the heat that was in the whole bulk of air is concentrated into one-166th of the space it occupied before it was compressed. It is 166 times hotter. There are two sets of pipes running from the compressor to a long upright tank called the liquefier. These pipes pass through running water, so that the compressed air is quickly cooled down to the temperature of the water (about 50 degrees Fahrenheit). The pipes—at least one set of them—run the whole length of the liquefier, and most likely are coiled. This set of pipes contains the air to be liquefied. A second set of pipes runs to the bottom of the liquefier, where there is a valve. By opening this valve a jet of compressed air is allowed to play on the other set of pipes, when intense cold is produced by the sudden expansion of the air. This cold air rushes up around the pipe containing the air to be liquefied and escapes at the top, thus absorbing the heat until the temperature is reduced to 312 degrees below zero. Then the air liquefies and runs into a receptacle, where it may be drawn off at pleasure.
It will be seen that a large part of the compressed air is wasted in cooling the remainder sufficiently to liquefy.
The use to which liquid air may be put, advantageously, is an unsolved problem; but no doubt it will have a place in time. All great discoveries do. Electricity had to wait a long time for recognition; but what a part it plays now in the everyday life of the whole civilized world!
Curious effects are produced by this intense cold. Meat may be frozen so hard that it will give off a musical tone when struck. Here is a pointer for the seeker of novelties in the line of musical instruments.
Liquid air furnishes a beautiful illustration of the fact that a burning gas jet is continually forming water as well as giving out heat and light. If we put liquid air into a tea kettle and hold it over a gas jet, ice will form on the bottom from the water created by the flame, and it will freeze so hard that the flame will make no impression upon it, other than to make the ice cake grow larger.