PRUSSIATE OF POTASH.
Prussiate of potash is the commercial name given to what chemists call “ferrocyanide of potassium,” it is used largely for the production of Prussian blue, and also in the art of electro-plating, which, of late, has greatly increased the demand for its manufacture, and many patents have been taken out for various modifications in the form of production, the result, however, is the same, and it occurs in commerce in magnificent crystals of a square form, with bevelled edges, and of a yellow color; there is, however, another kind called the “red prussiate,” which is much used in the process of calico printing. Prussiate of potash is made by heating together carbonate of potash, scraps of iron, and any kind of animal refuse, as blood, horns and hoofs, clippings of skin or old woollen rags; these are stirred together, and the heat raised, till they form a sort of paste of a black color, which, when cold, is thrown into water and all the soluble parts washed out; this fluid is filtered till quite clear, evaporated, and set aside that crystals may form; these are dissolved and again crystallized. The red prussiate is made by passing chlorine over the yellow prussiate in powder dissolving and crystallizing.
The most deadly of all poisons, prussic or hydrocyanic acid, is obtained from the ferrocyanide of potassium, or prussiate of potash, by adding diluted sulphuric acid and distilling the vapour into an ice-cold receiver. This experiment should never be made by any but those well conversant with such matters.
SULPHATE OF IRON.
Also called “Green Vitriol” and “Green Copperas,” is a combination of sulphuric acid and oxide of iron, and may be made by putting iron filings or pieces of iron into a mixture of sulphuric acid and water, and when all action has ceased evaporating the liquid, and setting it by till crystals form—these are of a pale green color. The sulphate of iron of commerce is formed by exposing the iron pyrites found in the coal districts to the air till it falls to powder; water is then poured over this substance, and the fluid collected and evaporated. Sulphate of iron is used chiefly to form the black dye so much in demand to dye cloth, and also in making writing ink.
SULPHATE OF COPPER.
This substance is also known by the names, “Blue Vitriol” and “Blue Stone.” It is a combination of sulphuric acid with oxide of copper, and may be made by uniting those substances; but what is used on a large scale for commercial purposes is obtained from the waters which flow into copper mines where “copper pyrites” abound; this water is evaporated, and the sulphate of copper crystallizes. Sulphate of copper has of late been in great demand for the electro-deposition of copper.