II. The Carbon Dioxide Theory. At about the time that the eccentricity theory was being relegated to a minor niche, a new theory was being developed which soon exerted a profound influence upon geological thought. Chamberlin,[11] adopting an idea suggested by

Tyndall, fired the imagination of geologists by his skillful exposition of the part played by carbon dioxide in causing climatic changes. Today this theory is probably more widely accepted than any other. We have already seen that the amount of carbon dioxide gas in the atmosphere has a decided climatic importance. Moreover, there can be little doubt that the amount of that gas in the atmosphere varies from age to age in response to the extent to which it is set free by volcanoes, consumed by plants, combined with rocks in the process of weathering, dissolved in the ocean or locked up in the form of coal and limestone. The main question is whether such variations can produce changes so rapid as glacial epochs and historical pulsations.

Abundant evidence seems to show that the degree to which the air can be warmed by carbon dioxide is sharply limited. Humphreys, in his excellent book on the Physics of the Air, calculates that a layer of carbon dioxide forty centimeters thick has practically as much blanketing effect as a layer indefinitely thicker. In other words, forty centimeters of carbon dioxide, while having no appreciable

effect on sunlight coming toward the earth, would filter out and thus retain in the atmosphere all the outgoing terrestrial heat that carbon dioxide is capable of absorbing. Adding more would be like adding another filter when the one in operation has already done all that that particular kind of filter is capable of doing. According to Humphreys' calculations, a doubling of the carbon dioxide in the air would in itself raise the average temperature about 1.3°C. and further carbon dioxide would have practically no effect. Reducing the present supply by half would reduce the temperature by essentially the same amount.

The effect must be greater, however, than would appear from the figures given above, for any change in temperature has an effect on the amount of water vapor, which in turn causes further changes of temperature. Moreover, as Chamberlin points out, it is not clear whether Humphreys allows for the fact that when the 40 centimeters of CO2 nearest the earth has been heated by terrestrial radiation, it in turn radiates half its heat outward and half inward. The outward half is all absorbed in the next layer of carbon dioxide, and so on. The process is much more complex than this, but the end result is that even the last increment of CO2, that is, the outermost portions in the upper atmosphere, must apparently absorb an infinitesimally small amount of heat. This fact, plus the effect of water vapor, would seem to indicate that a doubling or halving of the amount of CO2, would have an effect of more than 1.3°C. A change of even 2°C. above or below the present level of the earth's mean temperature would be of very appreciable climatic significance, for it is commonly believed that during the height of the glacial period the mean temperature was only 5° to 8°C. lower than now.

Nevertheless, variations in atmospheric carbon dioxide do not necessarily seem competent to produce the relatively rapid climatic fluctuations of glacial epochs and historic pulsations as distinguished from the longer swings of glacial periods and geological eras. In Chamberlin's view, as in ours, the elevation of the land, the modification of the currents of the air and of the ocean, and all that goes with elevation as a topographic agency constitute a primary cause of climatic changes. A special effect of this is the removal of carbon dioxide from the air by the enhanced processes of weathering. This, as he carefully states, is a very slow process, and cannot of itself lead to anything so sudden as the oncoming of glaciation. But here comes Chamberlin's most distinctive contribution to the subject, namely, the hypothesis that changes in atmospheric temperature arising from variations in atmospheric carbon dioxide are able to cause a reversal of the deep-sea oceanic circulation.

According to Chamberlin's view, the ordinary oceanic circulation of the greater part of geological time was the reverse of the present circulation. Warm water descended to the ocean depths in low latitudes, kept its heat while creeping slowly poleward, and rose in high latitudes producing the warm climate which enabled corals, for example, to grow in high latitudes. Chamberlin holds this opinion largely because there seems to him to be no other reasonable way to account for the enormously long warm periods when heat-loving forms of life lived in what are now polar regions of ice and snow. He explains this reversed circulation by supposing that an abundance of atmospheric carbon dioxide, together with a broad distribution of the oceans, made the atmosphere so warm that the evaporation in low latitudes was far more rapid than now. Hence the surface water of the ocean became

a relatively concentrated brine. Such a brine is heavy and tends to sink, thereby setting up an oceanic circulation the reverse of that which now prevails. At present the polar waters sink because they are cold and hence contract. Moreover, when they freeze a certain amount of salt leaves the ice and thereby increases the salinity of the surrounding water. Thus the polar water sinks to the depths of the ocean, its place is taken by warmer and lighter water from low latitudes which moves poleward along the surface, and at the same time the cold water of the ocean depths is forced equatorward below the surface. But if the equatorial waters were so concentrated that a steady supply of highly saline water kept descending to low levels, the direction of the circulation would have to be reversed. The time when this would occur would depend upon the delicate balance between the downward tendencies of the cold polar water and of the warm saline equatorial water.

Suppose that while such a reversed circulation prevailed, the atmospheric CO2 should be depleted, and the air cooled so much that the concentration of the equatorial waters by evaporation was no longer sufficient to cause them to sink. A reversal would take place, the present type of circulation would be inaugurated, and the whole earth would suffer a chill because the surface of the ocean would become cool. The cool surface-water would absorb carbon dioxide faster than the previous warm water had done, for heat drives off gases from water. This would hasten the cooling of the atmosphere still more, not only directly but by diminishing the supply of atmospheric moisture. The result would be glaciation. But ultimately the cold waters of the higher latitudes would absorb all the carbon dioxide they could hold, the slow equatorward creep would at length permit

the cold water to rise to the surface in low latitudes. There the warmth of the equatorial sun and the depleted supply of carbon dioxide in the air would combine to cause the water to give up its carbon dioxide once more. If the atmosphere had been sufficiently depleted by that time, the rising waters in low latitudes might give up more carbon dioxide than the cold polar waters absorbed. Thus the atmospheric supply would increase, the air would again grow warm, and a tendency toward deglaciation, or toward an inter-glacial condition would arise. At such times the oceanic circulation is not supposed to have been reversed, but merely to have been checked and made slower by the increasing warmth. Thus inter-glacial conditions like those of today, or even considerably warmer, are supposed to have been produced with the present type of circulation.