The best starting point for a bromoil print, however, especially for the beginner, is and must be a bromide print as nearly perfect as possible.
A suggestion for the certain obtaining of such prints may be added here. When we are working with a negative with strong high lights, judgment as to the freedom of the bromide print from fog by comparison with an unexposed edge is not difficult. This is not the case with negatives which show no well marked high lights. In such cases it is advisable to determine what is underexposure by making test strips in which details in the high lights and middle tones are lacking and, working from this point, determine by gradual increase of exposure the correct time which gives a perfectly clean print.
The Choice of the Paper.—One of the most important problems is to find a suitable paper for the process. Not all of the bromide papers which are on the market will give satisfactory results. It is only possible to use papers whose swelling power has not been too completely removed in process of manufacture by the use of hardeners. The principle of the bromoil process is that a tanning of the gelatine shall occur simultaneously with the bleaching of the silver bromide image. As we have already remarked, this does not affect the high lights and leaves them still absorbent, while the shadows are tanned and therefore become incapable of taking up water. The half-tones are tanned or hardened to an intermediate degree and therefore can take up a certain amount of water. Therefore, in place of the vanished silver image, we get a totally or partially invisible tanned image in the gelatine film.
The variously hardened parts of the gelatine film, corresponding to the various portions of the vanished bromide image, display the property acquired through different degrees of tanning by the fact that the portions of the gelatine which remain unhardened and which correspond to the high lights of the silver image formerly present, absorb water greedily. Consequently they swell up and acquire a certain shininess, because of their water content; in addition they generally rise above the other parts of the gelatine film, which contain little or no water, and give a certain amount of relief when they are fully swelled. The portions of the film in which the deep shadows of the bromide image lay are completely tanned through, can therefore take up no water, and remain matt and sunken. This graded swelling of the gelatine film becomes more apparent, the higher the temperature of the water in which the film is swollen.
If, however, the paper was strongly tanned in the process of manufacture, the gelatine has already lost all or most of its swelling power before it is printed and, although the bleaching solution in such cases can indeed remove the silver image, it can no longer develop the differences of absorptive power which are necessary for a bromoil print; for, although the bleaching solution can harden an untanned gelatine layer, it cannot bring back the lost power of swelling to a film which is already hardened through and through.
Therefore bromide papers which have already been very thoroughly hardened in manufacture show no trace of relief after bleaching, and very slight, if any, shininess in the lights. This is the case especially with those white, smooth, matt, heavyweight papers which are especially used for postcard printing. When such papers are taken out of the solutions, as a rule, these run off quickly and leave an almost dry surface. It is generally not possible to make satisfactory bromoil prints on such papers. It is true that the image can be inked by protracted labor; it is, however, muddy and flat and, as a rule, cannot be essentially improved even by the use of very warm water. Other types of bromide paper which have not been so thoroughly hardened may show no relief after bleaching, yet, after the surface water has been removed, they do show a certain small amount of shininess in the high lights when carefully inspected sidewise. With such papers the necessary differences of swelling can generally be developed if, as will later be more completely described, they are soaked in very warm water or in an ammoniacal solution. It is rare to find in commerce silver bromide papers which have not been hardened at all, or only very slightly hardened, in their manufacture. Such papers, because their films are very susceptible to mechanical injury, are not likely to stand the wear and tear of the various baths. On the other hand, as a rule, they usually produce a strong relief even in cold water, and therefore tend to produce hard prints. The greatest adaptability for bromoil printing may be anticipated from bromide papers which are moderately hardened during manufacture.
To determine whether a given brand of bromide paper is suitable for bromoil work, an unexposed sheet of the paper should be dipped in water at a temperature of about 30° C. (86° F.) and the behavior of the gelatine film observed. If this swells up considerably and becomes slippery and shiny, the paper has the necessary swelling power and can be used with success.
On account of the great variety of bromide papers which are on the market, we have a very wide choice as regards the thickness and color of the paper and the structure of its surface. It may be remarked here that papers of any desired surface, even rough and coarse grained papers, can be used for bromoil printing, as easily as papers with a smooth surface. The difficulties experienced with very rough surfaced papers in some other processes do not exist in bromoil. Because of the elasticity of its hairs, the brush carries the ink as easily into the hollows of the surface as to its high points.
The thickness of the paper is of no importance in bromoil printing, except that the handling of the thicker papers is easier, because they lie flatter during the work and distort less on drying; also, as a rule, thick papers are easier to ink.