The colouring matter both of limestone and flint was probably owing to the flesh of peculiar animals, as well as the siliceous acid, which converted some of the limestone into flint; or to some strata of shell- fish having been overwhelmed when alive with new materials, while others dying in their natural situations would lose their fleshy parts, either by its putrid solution in the water or by its being eaten by other sea- insects. I have some calcareous fossil shells which contain a black coaly matter in them, which was evidently the body of the animal, and others of the same kind filled with spar instead of it. The Labradore stone has I suppose its colours from the nacre or mother-pearl shells, from which it was probably produced. And there is a stratum of calcareous matter about six or eight inches thick at Wingerworth in Derbyshire over the iron-beds, which is replete with shells of fresh- water muscles, and evidently obtains its dark colour from them, as mentioned in note XVI. Many nodules of flint resemble in colour as well as in form the shell of the echinus or sea-urchin; others resemble some coralloids both in form and colour; and M. Arduini found in the Monte de Pancrasio, red flints branching like corals, from whence they seem to have obtained both their form and their colour. Ferber's Travels in Italy, p. 42.
6. NODULES OF FLINT IN CHALK-BEDS.
As the nodules of flint found in chalk-beds possess no marks of having been rounded by attrition or solution, I conclude that they have gained their form as well as their dark colour from the flesh of the shell-fish from which they had their origin; but which have been so compleatly fused by heat, or heat and water, as to obliterate all vestiges of the shell, in the same manner as the nodules of agate and onyx were produced from parts of vegetables, but which had been so completely fused as to obliterate all marks of their organization, or as many iron-nodules have obtained their form and origin from peculiar vegetables.
Some nodules in chalk-beds consist of shells of echini filled up with chalk, the animal having been dissolved away by putrescence in water, or eaten by other sea-insects; other shells of echini, in which I suppose the animal's body remained, are converted into flint but still retain the form of the shell. Others, I suppose as above, being more completely fused, have become flint coloured by the animal flesh, but without the exact form either of the flesh or shell of the animal. Many of these are hollow within and lined with crystals, like the Scot's-pebbles above described; but as the colouring matter of animal bodies differs but little from each other compared with those of vegetables, these flints vary less in their colours than those above mentioned. At the same time as they cooled in concentric spheres like the Scot's-pebbles, they often possess faint rings of colours, and always break in conchoide forms like them.
This idea of the production of nodules of flint in chalk-beds is countenanced from the iron which generally appears as these flints become decomposed by the air; which by uniting with the iron in their composition reduces it from a vitrescent state to that of calx, and thus renders it visible. And secondly, by there being no appearance in chalk- beds of a string or pipe of siliceous matter connecting one nodule with another, which must have happened if the siliceous matter, or its acid, had been injected from without according to the idea of Dr. Hutton. And thirdly, because many of them have very large cavities at their centres, which should not have happened had they been formed by the injection of a material from without.
When shells or chalk are thus converted from calcareous to siliceous matter by the flesh of the animal, the new flint being heavier than the shell or chalk occupies less space than the materials it was produced from; this is the cause of frequent cavities within them, where the whole mass has not been completely fused and pressed together. In Derbyshire there are masses of coralloid and other shells which have become siliceous, and are thus left with large vacuities sometimes within and sometimes on the outside of the remaining form of the shell, like the French millstones, and I suppose might serve the same purpose; the gravel of the Derwent is full of specimens of this kind.
Since writing the above I have received a very ingenious account of chalk-beds from Dr. MENISH of Chelmsford. He distinguishes chalk-beds into three kinds; such as have been raised from the sea with little disturbance of their strata, as the cliffs of Dover and Margate, which he terms intire chalk. Another state of chalk is where it has suffered much derangement, as the banks of the Thames at Gravesend and Dartford. And a third state where fragments of chalk have been rounded by water, which he terms alluvial chalk. In the first of these situations of chalk he observes, that the flint lies in strata horizontally, generally in distinct nodules, but that he has observed two instances of solid plates or strata of flint, from an inch to two inches in thickness, interposed between the chalk-beds; one of these is in a chalk-bank by the road side at Berkhamstead, the other in a bank on the road from Chatham leading to Canterbury. Dr. Menish has further observed, that many of the echini are crushed in their form, and yet filled with flint, which has taken the form of the crushed shell, and that though many flint nodules are hollow, yet that in some echini the siliceum seems to have enlarged, as it passed from a fluid to a solid state, as it swells out in a protuberance at the mouth and anus of the shell, and that though these shells are so filled with flint yet that in many places the shell itself remains calcareous. These strata of nodules and plates of flint seem to countenance their origin from the flesh of a stratum of animals which perished by some natural violence, and were buried in their shells.
7. ANGLES OF SILICEOUS SAND.
In many rocks of siliceous sand the particles retain their angular form, and in some beds of loose sand, of which there is one of considerable purity a few yards beneath the marl at Normington about a mile south of Derby. Other siliceous sands have had their angles rounded off, like the pebbles in gravel-beds. These seem to owe their globular form to two causes; one to their attrition against each other, when they may for centuries have lain at the bottom of the sea, or of rivers; where they may have been progressively accumulated, and thus progressively at the same time rubbed upon each other by the dashing of the water, and where they would be more easily rolled over each other by their gravity being so much less than in air. This is evidently now going on in the river Derwent, for though there are no limestone rocks for ten or fifteen miles above Derby, yet a great part of the river-gravel at Derby consists of limestone nodules, whose angles are quite worn off in their descent down the stream.
There is however another cause which must have contributed to round the angles both of calcareous and siliceous fragments; and that is, their solubility in water; calcareous earth is perpetually found suspended in the waters which pass over it; and the earth of flints was observed by Bergman to be contained in water in the proportion of one grain to a gallon. Kirwan's Mineralogy, p. 107. In boiling water, however, it is soluble in much greater proportion, as appears from the siliceous earth sublimed in the distillation of fluor acid in glass vessels; and from the basons of calcedony which surrounded the jets of hot water near mount Heccla in Iceland. Troil on Iceland. It is probable most siliceous sands or pebbles have at some ages of the world been long exposed to aqueous steams raised by subterranean fires. And if fragments of stone were long immersed in a fluid menstrum, their angular parts would be first dissolved, on account of their greater surface.