Joly found that the effect could not be explained by any direct action due to the movement of the ions in an electric field. The recoil, due to the expulsion of α particles from one side of the vane, is far too small to account for the movement observed.
This effect can, I think, be simply accounted for by taking into consideration the difference in conductivity of the gas on the two sides of the radium coated vane. If a small vane, coated uniformly with radium on both sides, and mounted on an insulating support, be brought near a charged body kept at a constant potential, it acts like a water dropper and rapidly acquires very nearly the average potential which existed at that point before the vane was brought up. The mechanical force acting on the vane will, in consequence, be small. If, however, the vane is only coated with radium on the side near the charged body, the ionization and consequently the conductivity of the gas is much greater between the vane and the charged body than on the opposite side. Suppose, for simplicity, the body is charged to a positive potential. On account of the greater conductivity of the gas on the side facing the charged body, it will rapidly acquire a positive charge, and the potential of the vane will reach a higher value than existed at that place before the vane was introduced. This will result in a repulsion of the vane. This also accounts for the attraction observed in the experiment with the Coulomb’s balance already referred to. Suppose that one sphere is positively charged and the other earthed, and the two vanes metallically connected together. The vane next to the charged body will become charged positively, but this charge will be dissipated rapidly on account of the ionization of the gas close to the opposite vane, and, in most conditions, this loss of charge will be so rapid that the potential of the vane is unable to reach the value which would exist at that place in the field, if the vane were removed. There will, in consequence, be an attracting force acting on the vane towards the sphere.
The repulsion observed by Joly is thus only an indirect result of the ionization in the gas produced by the radium, and should be shown under conditions where similar unequal distribution of ionization is produced by any other sources.
Since radium gives out heat at a fairly rapid rate, a radiometer in which the vanes were coated on one side with radium instead of lampblack, should rotate at low pressure of the gas, even if no source of light is brought near it. This should evidently be the case, since the face coated with radium should reach a slightly higher temperature than the other. This experiment has been tried, but the effect seems too small to produce rotation of the vanes.
Chemical actions.
123. Rays from active radium preparations change oxygen into ozone[[210]]. Its presence can be detected by the smell or by the action on iodide of potassium paper. This effect is due to the α and β rays from the radium, and not to the luminous rays from it. Since energy is required to produce ozone from oxygen, this must be derived from the energy of the radiations.
The Curies found that radium compounds rapidly produced coloration in glass. For moderately active material the colour is violet, for more active material it is yellow. Long continued action blackens the glass, although the glass may have no lead in its composition. This coloration gradually extends through the glass, and is dependent to some extent on the kind of glass used.
Giesel[[211]] found that he could obtain as much coloration in rock-salt and fluor-spar by radium rays, as by exposure to the action of cathode rays in a vacuum tube. The coloration, however, extended much deeper than that produced by the cathode rays. This is to be expected, since the radium rays have a higher velocity, and consequently greater penetrating power, than the cathode rays produced in an ordinary vacuum tube. Goldstein observed that the coloration is far more intense and rapid when the salts are melted or heated to a red heat. Melted potassium sulphate, under the action of a very active preparation of radium, was rapidly coloured a strong greenish blue which gradually changed into a dark green. Salomonsen and Dreyer[[212]] found that plates of quartz were coloured by exposure to radium rays. When examined minutely, plates cut perpendicular to the optic axis showed the presence of lines and striae, parallel to the binary axes. Adjacent portions of the striated system differed considerably in intensity of coloration and clearly revealed the heterogeneity of structures of the crystal.
The cause of these colorations by cathode and radium rays has been the subject of much discussion. Elster and Geitel[[213]] observed that a specimen of potassium sulphate, coloured green by radium rays, showed a strong photo-electric action, i.e. it rapidly lost a negative charge of electricity when exposed to the action of ultra-violet light. All substances coloured by cathode rays show a strong photo-electric action, and, since the metals sodium and potassium themselves show photo-electric action to a very remarkable degree, Elster and Geitel have suggested that the colorations are caused by a solid solution of the metal in the salt.
Although the coloration due to radium rays extends deeper than that due to the cathode rays, when exposed to light the colour fades away at about the same rate in the two cases.