A more complete discussion of the radio-active and other properties of actinium is given in later chapters.
19. Polonium. Polonium was the first of the active substances obtained from pitchblende. It has been investigated in detail by its discoverer Mme Curie[[32]]. The pitchblende was dissolved in acid and sulphuretted hydrogen added. The precipitated sulphides contained an active substance, which, after separation of impurities, was found associated with bismuth. This active substance, which has been named polonium, is so closely allied in chemical properties to bismuth that it has so far been found impossible to effect a complete separation. Partial separation of polonium can be made by successive fractionations based on one of the following modes of procedure:
(1) Sublimation in a vacuum. The active sulphide is more volatile than that of bismuth. It is deposited as a black substance at those parts of the tube, where the temperature is between 250 and 300° C. In this way polonium of activity 700 times that of uranium was obtained.
(2) Precipitation of nitric acid solutions by water. The precipitated sub-nitrate is much more active than the part that remains in solution.
(3) Precipitation by sulphuretted hydrogen in a very acid hydrochloric acid solution. The precipitated sulphides are much more active than the salt which remains in solution.
For concentration of the active substance Mme Curie[[33]] has made use of method (2). The process is, however, very slow and tedious, and is made still more complicated by the tendency to form precipitates insoluble either in strong or weak acids. After a large number of fractionations, a small quantity of matter was obtained, enormously active compared with uranium. On examination of the substance spectroscopically, only the bismuth lines were observed. A spectroscopic examination of the active bismuth by Demarçay and by Runge and Exner has led to the discovery of no new lines. On the other hand Sir William Crookes[[34]] states that he found one new line in the ultra-violet, while Berndt[[35]], working with polonium of activity 300, observed a large number of new lines in the ultra-violet. These results await further confirmation.
The polonium prepared by Mme Curie differs from the other radio-active bodies in several particulars. In the first place the radiations include only very easily absorbable rays. The two penetrating types of radiation given out by uranium, thorium, and radium are absent. In the second place the activity does not remain constant, but diminishes continuously with the time. Mme Curie states that different preparations of polonium had somewhat different rates of decay. In some cases, the activity fell to half value in about six months, and in others, about half value in eleven months.
20. The gradual diminution of the activity of polonium with time seemed at first sight to differentiate it from such substances as uranium and radium, the activity of which appeared fairly permanent. This difference in behaviour is, however, one of degree rather than of kind. We shall show later that there is present in pitchblende a number of radio-active substances, the activity of which is not permanent. The time taken for these bodies to lose half of their activity varies in different cases from a few seconds to several hundreds of years. In fact, this gradual loss of activity is an essential feature of our theory of regarding the phenomena of radio-activity. No radio-active substance, left to itself, can continue to radiate indefinitely; it must ultimately lose its activity. In the case of bodies like uranium and radium, the loss of activity is so slow that no sensible alteration has been observed over a period of several years, but it can be deduced theoretically that the activity of radium will eventually decrease to half value in a period of about 1000 years, while in the case of a feebly radio-active substance like uranium, more than a 100 million years must elapse before the diminution of the activity becomes appreciable.
It may be of interest here to consider briefly the suggestions advanced at various times to account for the temporary character of the activity of polonium. Its association with bismuth led to the view that polonium was not a new active substance, but merely radio-active bismuth, that is, bismuth which in some way had been made active by admixture with radio-active bodies. It was known that a body placed in the vicinity of thorium or radium became temporarily active. The same action was supposed to take place when inactive matter was in solution with active matter. The non-active matter was supposed to acquire activity by “induction,” as it was called, in consequence of its intimate contact with the active material.
There is no proof, however, that such is the case. The evidence points rather to the conclusion that the activity is due, not to an alteration of the inactive body itself, but to an admixture with it of a very small quantity of intensely active matter. This active matter is present in pitchblende and is separated with the bismuth but differs from it in chemical properties.