Fig. 102.
One product has been observed in uranium, four in thorium, four in actinium and seven in radium. It is not improbable that a closer examination of the radio-elements may reveal still further changes. If any very rapid transformations exist, they would be very difficult to detect. The change of thorium X into the emanation, for example, would probably not have been discovered if the product of the change had not been gaseous in character. The electrolysis of solutions is, in many cases, a very powerful method of separating active products from one another, and its possibilities have not yet been exhausted. The main family of changes of the radio-elements, as far as they are known, have been investigated closely, and it is not likely that any product of comparatively slow rate of change has been overlooked. There is a possibility, however, that two radio-active products may in some cases arise from the disintegration of a single substance. This point is discussed further in section 260.
The remarkable way in which the disintegration theory can be applied to unravel the intricacies of the succession of radio-active changes is very well illustrated in the case of radium. Without its aid, it would not have been possible to disentangle the complicated processes which occur. We have already seen that this analysis has been instrumental in showing that the substances polonium, radio-tellurium and radio-lead are in reality products of radium.
After the radio-active substances have undergone the succession of changes traced above, a final stage is reached where the atoms are either permanently stable, or change so slowly that it is difficult to detect their presence by means of their radio-activity. It is probable, however, that the process of transformation still continues through further slow stages.
There is now considerable evidence that the elements uranium, radium and actinium are intimately connected together. The two latter probably result from the breaking up of uranium. The evidence in support of this idea is given in [section 262], but there still remains much work to be done to bridge over the gaps which at present appear to separate these elements from one another.
After the series of transformations have come to an end, there will probably remain a product or products which will be inactive, or active only to a minute extent. In addition, since the α particles, expelled during the transformation, are material in nature, and are non-radio-active, they must collect in some quantity in radio-active matter. The probability that the α particles consist of helium is considered later in [section 268].
The value of T, the time for a product to be half-transformed, may be taken as a comparative measure of the stability of the different metabolons. The stability of the products varies over a very wide range. For example, the value of T for radium D is 40 years, and for the actinium emanation 3·9 secs. This corresponds to a range of stability measured by 3·8 × 108. The range of stability is still further extended, when it is remembered that the atoms of the radio-elements themselves are very slowly changing.
The only two metabolons of about the same stability are thorium X and the radium emanation. In each case, the transformation is half completed in about four days. I consider that the approximate agreement of the numbers is a mere coincidence, and that the two types of matter are quite distinct from one another; for, if the metabolons were identical, it would be expected that the changes which follow would take place in the same way and at the same rate, but such is not the case. Moreover, Th X and the radium emanation have chemical and physical properties quite distinct from one another.
It is very remarkable that the three radio-active substances, radium, thorium and actinium, should exhibit such a close similarity in the succession of changes which occur in them. Each of them at one stage of its disintegration emits a radio-active gas, and in each case this gas is transformed into a solid which is deposited upon the surface of bodies. It would appear that, after disintegration of an atom of any of these has once begun, there is a similar succession of changes, in which the resulting systems have allied chemical and physical properties. Such a connection is of interest as indicating a possible origin of the recurrence of properties in the atoms of the elements, as exemplified by the periodic law. The connection between thorium and actinium is especially close both as regards the number and nature of the products. The period of transformation of the successive products, though differing in magnitude, rises and falls in a very analogous manner. This indicates that the atoms of these two elements are very similarly constituted.