The expulsion of a β particle with great velocity from an atom of radio-active matter also results in a transformation of the atom. For example radium E emits a β particle, and, in consequence, gives rise to a distinct substance radium F (polonium). A case of this kind, where the expulsion of a β particle with great velocity causes a complete rearrangement of the parts of an atom, is probably quite distinct from the process which occurs during ionization, where a slow speed electron escapes from the atom without apparently affecting the stability of the atom left behind.
The only direct experimental evidence of the transformation of matter has been derived from a study of the radio-active bodies. If the disintegration theory, advanced to account for the phenomena of radio-activity, is correct in the main essentials, then the radio-elements are undergoing a spontaneous and continuous process of transformation into other and different kinds of matter. The rate of transformation is slow in uranium and thorium, but is fairly rapid in radium. It has been shown that the fraction of a mass of radium which is transformed per year is about ¹⁄₂₀₀₀ of the total amount present. In the case of uranium and thorium probably a million years would be required to produce a similar amount of change. Thus the process of transformation in uranium and thorium is far too slow to be detected within a reasonable time by the use of the balance or spectroscope, but the radiations which accompany the transformation can easily be detected. Although the process of change is slow it is continuous, and in the course of ages the uranium and thorium present in the earth must be transformed into other types of matter.
Those who have considered the possibility of atoms undergoing a process of transformation have generally thought that the matter as a whole would undergo a progressive change, with a gradual alteration of physical and chemical properties of the whole mass of substance. On the theory of disintegration this is not the case. Only a minute fraction of the matter present breaks up in unit time, and in each of the successive stages through which the disintegrated atoms pass, there is in most cases a marked alteration in the chemical and physical properties of the matter. The transformation of the radio-elements is thus a transformation of a part per saltum, and not a progressive change of the whole. At any time after the process of transformation has been in progress there will thus remain a part of the matter which is unchanged, and, mixed with it, the products which have resulted from the transformation of the remainder.
The question naturally arises whether the process of degradation of matter is confined to the radio-elements or is a universal property of matter. It will be shown in [chapter XIV] that all matter, so far examined, exhibits the property of radio-activity to a slight degree. It is very difficult, however, to make certain that the observed radio-activity is not due to the presence in the matter of a slight trace of a radio-element. If ordinary matter is radio-active, it is certain that its activity is much less than that of uranium, and consequently that its rate of transformation must be excessively slow. There is, however, another possibility to be considered. The changes occurring in the radio-elements would probably never have been detected if the change had not been accompanied by the expulsion of charged particles with great velocity. It does not seem unlikely that an atom may undergo disintegration without projecting a part of its system with sufficient velocity to ionize the gas. In fact, we have seen that, even in the radio-elements, several of the series of changes in both thorium, radium, and actinium are unaccompanied by ionizing rays. The experimental results given in [Appendix A] strongly support this point of view. It may thus be possible that all matter is undergoing a slow process of transformation, which has so far only been detected in the radio-elements on account of the expulsion of charged particles with great velocity during the change. This process of degradation of matter continuing for ages must reduce the constituents of the earth to the simpler and more stable forms of matter.
The idea that helium is a transformation product of radium suggests the probability that helium is one of the more elementary substances of which the heavier atoms are composed. Sir Norman Lockyer, in his interesting book on “Inorganic Evolution,” has pointed out that the spectra of helium and of hydrogen predominate in the hottest stars. In the cooler stars the more complex types of matter appear. Sir Norman Lockyer has based his theory of evolution of matter on evidence of a spectroscopic examination of the stars, and considers that temperature is the main factor in breaking up matter into its simpler forms. The transformation of matter occurring in the radio-elements is on the other hand spontaneous, and independent of temperature over the range examined.
CHAPTER XIV.
RADIO-ACTIVITY OF THE ATMOSPHERE AND OF ORDINARY MATERIALS.
273. Radio-activity of the atmosphere. The experiments of Geitel[[384]] and C. T. R. Wilson[[385]] in 1900 showed that a positively or negatively charged conductor placed inside a closed vessel gradually lost its charge. This loss of charge was shown to be due to a small ionization of the air inside the vessel. Elster and Geitel also found that a charged body exposed in the open air lost its charge rapidly, and that the rate of discharge was dependent on the locality and on atmospheric conditions. A more detailed description and discussion of these results will be given later in section 284.
In the course of these experiments, Geitel observed that the rate of discharge increased slightly for some time after the vessel had been closed. He considered that this might possibly be due to the existence of some radio-active substances in the air, which produced excited activity on the walls of the vessel and so increased the rate of dissipation of the charge. In 1901 Elster and Geitel[[386]] tried the bold experiment of seeing whether it were possible to extract a radio-active substance from the air. The experiments of the writer had shown that the excited radio-activity from the thorium emanation could be concentrated on the negative electrode in a strong electric field. This result indicated that the carriers of the radio-activity had a positive charge of electricity. Elster and Geitel therefore tried an experiment to see whether positively charged carriers, possessing a similar property, were present in the atmosphere. For this purpose a cylinder of wire-netting, charged negatively to 600 volts, was exposed for several hours in the open air. The cylinder was then removed, and quickly placed in a large bell-jar, inside which was placed an electroscope to detect the rate of discharge. It was found that the rate of discharge was increased to a slight extent. In order to multiply the effect a wire about 20 metres in length was exposed at some height from the ground, and was kept charged to a high potential by connecting it to the negative terminal of an influence machine. After exposure for some hours, this wire was removed and placed inside the dissipation vessel. The rate of discharge was found to be increased many times by the presence of the wire. No increase was observed when the wire was charged positively instead of negatively. The results also showed that the radio-active matter could be removed from the wire in the same way as from a wire made active by exposure in the presence of the thorium emanation. A piece of leather moistened with ammonia was rubbed over the active wire. On testing the leather, it was found to be strongly radio-active. When a long wire was used, the amount of activity obtained on the leather was comparable with that possessed by a gram of uranium oxide.
The activity produced on the wire was not permanent, but disappeared to a large extent in the course of a few hours. The amount of activity produced on a wire of given size, exposed under similar conditions, was independent of the material of the wire. Lead, iron and copper wires gave about equal effects.
The amount of activity obtained was greatly increased by exposing a negatively charged wire in a mass of air which had been undisturbed for a long time. Experiments were made in the great cave of Wolfenbüttel, and a very large amount of activity was observed. By transferring the activity to a piece of leather it was found that the rays could appreciably light up a screen of barium platinocyanide in the dark[[387]]. The rays also darkened a photographic plate through a piece of aluminium 0·1 mm. in thickness.