A general method for using lichens is suggested by Dr. Westring of Sweden, in his "Experiments on Lichens for Dyeing Wools and Silks." He says:
"The Lichens should be gathered after some days of rain, they can then be more easily detached from the rocks. They should be well washed, dried and reduced to a fine powder: 25 parts pure river water are added to 1 of powdered lichen, and 1 part of fresh quick lime to 10 parts powdered lichen. To 10 lbs. lichen ½ lb. sal ammoniac is sufficient when lime and sal ammoniac are used together. The vessel containing them should be kept covered for the first 2 or 3 days. Sometimes the addition of a little common salt or salt-petre will give greater lustre to the colours."[7]
This method can be followed by anyone wishing to experiment with Lichens. Dr. Westring did not use a mordant as a rule. Where the same species of Lichen grows on both rocks and trees, the specimens taken from rocks give the better colours.
Orchil or Archil and Cudbear are substantive or non mordant dyes, obtained from Lichens of various species of Roccella growing on rocks in the Canary Islands and other tropical and sub-tropical countries. They used to be made in certain parts of Great Britain from various lichens, but the manufacture of these has almost entirely disappeared. They have been known from early times as dyes. They give beautiful purples and reds, but the colour is not very fast. The dye is produced by the action of ammonia and oxygen upon the crushed Lichens or weeds as they are called. The early way of producing the colour was by treating the Lichen with stale urine and slaked lime, and this method was followed in Scotland. Orchil is applied to wool by the simple process of boiling it in a neutral or slightly acid solution of the colouring matter. 3% Sulphuric acid is a useful combination. Sometimes alum and tartar are used. It dyes slowly and evenly. It is used as a bottom for Indigo on wool and also for compound shades on wool and silk. For cotton and linen dyeing it is not used. It is rarely used by itself as the colour is fugitive, but by using a mordant of tin, the colour is made much more permanent.
"Archil is in general a very useful ingredient in dyeing; but as it is rich in colour, and communicates an alluring bloom, dyers are often tempted to abuse it, and to exceed the proportions that can add to the beauty, without, at the same time, injuring in a dangerous manner the permanence of the colours. Nevertheless, the colour obtained when solution of tin is employed, is less fugitive than without this addition."[8]
Many of the British lichens produce colours by the same treatment as is used for producing Orchil. Large quantities were manufactured in Scotland from lichens gathered in the Shetland Islands and Western Highlands. This was called Cudbear. The species used by the Scottish Cudbear makers were generally Lecanora tartarea and Urceolaria calcarea; but the following lichens also give the purple colour on treatment with ammonia.—Evernia prunastri, Lecanora pallescens, Umbilicaria vellea, U. pustulata, Parmelia perlata; whilst several others give colours of similar character, but of little commercial value. The manufacture of Archil and Cudbear from the various lichens is simple in principle. In all cases the plant is reduced to a pulp with water and ammonia, and the mass kept at a moderate heat and allowed to ferment, the process taking two or three weeks to complete. The ammonia used to be added in the form of stale urine, and additions of slaked lime were made from time to time.[9] The general mode of treatment for the development from the dye lichens of orchil and cudbear consists of the following steps:—
- 1.—Careful washing, drying and cleaning, to separate earthy and other impurities.
- 2.—Pulverisation into a coarse or fine pulp with water.
- 3.—Regulated addition of ammonia of a certain strength and derived from various sources (putrid urine, gas liquor, etc.)
- 4.—Frequent stirring of the fermenting mass so as to ensure full exposure of every part thereof to the action of atmospheric oxygen.
- 5.—Addition of alkalis in some cases (e.g. potash or soda) to heighten or modify the colour; and of chalk, gypsum and other substances, to impart consistence. Various accessories are employed, e.g. the application of continued, moderate and carefully regulated heat during the process of fermentation.[10]
RECIPES FOR DYEING WITH LICHENS.
To dye Brown with Crotal.