Carbonated water a universal solvent.—While limestones are the rocks most obviously acted upon by carbonated water, few if any resist it altogether. Even quartz rocks of the ordinary kinds are attacked by it; only the purest white crystalline quartzite may be considered as sensibly proof against it. Granite and the rocks related to it are rather quickly acted upon, because of the presence of the feldspar minerals containing potash, soda and lime as bases[10] together with alumina.
The results of this action are highly important; one being the formation of clay, so essential as a physical ingredient of soils; the other the setting-free of potash, one of the most essential nutrients of plants. Hornblende and the related minerals are similarly acted upon so far as they contain the same substances. In all cases, of course, the silica (silicic acid) set free by the carbonic acid remains partially or wholly in the resulting soils, as such. Lime also at first mostly remains behind in the form of the carbonate; but potash and especially soda compounds, being mostly readily soluble in water, are largely carried away by the latter.
The effect of carbonated water upon silicate minerals is greatly increased by the presence of ammonia (ammonic carbonate), which always exists in atmospheric water to a greater or less extent. This effect may readily be noted on the windows of stables, or other places where animal offal decays, by the dimming of the glass surfaces; also in glass bottles containing solution of ammonic carbonate.
Action of Oxygen.—The effects of atmospheric oxygen on rocks are of course confined to those containing substances capable of farther oxidation. Chief among these are ferrous (iron monoxid) and ferroso-ferric oxid the latter imparting bottle-green, bluish and black tints to so many minerals and rocks that these colors may usually be taken as indicating its presence. By taking up more oxygen the ferrous and ferroso-ferric oxids are converted into ferric oxid or its hydrate (rust), the tints mentioned passing thereby into brick-red or rust color, according as the former or the latter (or sometimes their intermixtures) is formed. In either case there is an increase in bulk; and this when taking place in the cracks or crevices of minerals or rocks, tends, like the freezing of water, to widen the cracks and thus to increase the surface exposed to attack. Since ferrous compounds, when soluble in water, are injurious to plant growth, this oxidation is of no little importance, and in soils must be carefully maintained against a possible reversal.
It is hardly necessary to insist that the action of all these chemical agents continues in the soils themselves, and that owing to the fineness of the material, resulting in an enormously increased surface exposed to attack, such action acquires increased intensity. This is the more true as in soils bearing vegetation there are always superadded the effects of the humus-acids resulting from the decay of vegetable matter, as well as of the acid secretions of the living plants.
Action of Plants and their Remnants
in Soil Formation.
(a) Mechanical action.—The direct action of plants in forcing their roots into the crevices of rocks and minerals and thus both widening them by wedging, and by exposing new surfaces to weathering, has already been alluded to. That the mechanical force exerted by root growth is very great, may readily be judged from their effects in forcing apart, even to rupture, the walls of rock crevices; but actual measurement has shown the force with which the root, e. g., of the garden pea penetrates, to be equal to from seven to ten atmospheres, say from 200 to over 300 pounds per square inch. Such a force, exerted under the protection of the corky layer protecting the root tips, often produces surprising effects.
(b) Chemical action.—Vegetation takes a most important part, from a chemical point of view, both in the first formation of soils and in their subsequent relations to vegetable life. The lower forms of vegetation are usually the first to take possession of rock surfaces; foremost among these are the lichens. In humid climates we find these crust-like plants incrusting more or less all exposed rock surfaces, sometimes with a solid mantle that can be peeled off in wet weather, showing the corroded rock-surface, and the beginnings of soil clustering amid the root-fibrils beneath. A microscopic examination of the substance of these lichens often shows as a prominent ingredient, crystals of oxalate of lime, the lime having of course been derived from the rock, while the oxalic acid has been formed by the plant and used in the corrosion of the rock minerals. When it is remembered that this acid is comparable in strength to hydrochloric and nitric acids, the energy of the attack of the lichens is explained. Its progress can often be traced, even beyond the visible root fibers, by a change in the color of the rock; e. g., from rust-color to brick red.
When by the action of the lichens a certain depth of loosened rock or half-formed soil has been produced, the next step is usually the advent of various mosses, which gradually shade out the crust-like lichens, while the erect kinds persist for some time. Eventually the mosses, after having increased still farther the soil layer on the rock surface, are themselves partially or wholly displaced by the hardier species of ferns; and with these the higher flowering plants, such as the stonecrops and saxifrages (the latter deriving their name from their “rock-breaking” effect), the heather, and many other or shallow-rooted plants, gradually take possession. The roots of all plants secrete carbonic acid; and many of them, much stronger vegetable acids, such as oxalic and citric. In the crevices of rocks we commonly find the roots forming a dense network over the surfaces, the marks of which show plainly the solvent effect produced on the rock by the root secretions. This is most readily observable on a polished marble surface, or on feldspathic rocks. Of course the progress of soil-formation is very much more rapid when, as in the case of powdered lava (volcanic ash) and rock debris resulting from the effects of frost etc., the surface is very much increased. In tropical climates, where both vegetative and chemical action is most intense, it takes some of the higher plants only a few years after a volcanic eruption to take possession of portions of the “ash” surfaces; thus helping to form a soil on which after a few more years agricultural plants such as the vine and olive yield paying returns.
To this direct action of the higher plants is always added, to a greater or less extent, that of innumerable bacteria, as well as molds; whose vegetative and secretory action materially assists that of the roots, and the weathering process in general.