Kainit.—Of the products derived from the Stassfurt salt industry for agricultural use, the two requiring special consideration are “kainit,” a natural mixture of the several chlorid minerals in varying proportions; and “high-grade sulfate.” Being a natural product, “kainit” is the cheapest source of potash available to the farmer; but on account of its variability in composition it must be sold and purchased on guaranteed assay. On account of its large content of chlorin it is not desirable in the production of certain crops, especially in the arid region, where alkali soils, and even those not visibly alkaline, often contain already large amounts of chlorin. Moreover, kainit usually contains a considerable proportion of common salt. For the arid region therefore the sulfate is generally preferable, although it is somewhat higher in price for the same amount of potash. The potash content of commercial kainit (calculated as K₂O) ranges from 16 to 35%, while the sulphate frequently ranges from 80 up to 95% of the pure sulfate; thus costing materially less in freight charges than the lower-grade kainit. Its potash content ranges from 43 to over 50% of K₂O.
Potash Salts in Alkali Soils.—The sulfates and chlorids of potassium, however, occur not only in connection with rock-salt deposits, but are also found in the alkali soils of the arid region. They are, in fact, never absent where such salts occur at all, and their percentage in the total of salts ranges all the way from about 4 to as much as 20% of potash sulphate. In numerous cases it has been found that the content of this salt to the depth of four feet amounts to from 1200 to 1500 pounds per acre. In such lands, of course, additional fertilization with potash salts is totally uncalled for, the more as such soils invariably contain, besides the water-soluble potash, an unusually large percentage of the same in the form of easily decomposable silicates, or zeolites.
Farmyard or Stable Manure.—In connection with the subject of mineral fertilizers, it will be proper to discuss briefly the uses and special merits of stable manure, composts, etc. Up to within the last century, these were practically the only fertilizers known and used, and the exclusive use of this manure might have continued indefinitely but for the discovery that as time progressed, stable manure and with it grain crops, for the production of which it was necessary, became less and less in amount, so as to threaten bread famines. The cause of this diminution was, of course, the incompleteness of the return of the soil-ingredients taken off by the crops, when these were exported to feed the cities or foreign countries. Thus the attention of chemists, and notably that of Liebig, was attracted to the solution of the problem of keeping up production even with an insufficient supply of stable manure; and the discovery of the use of mineral fertilizers was the result of their activity.
The chemical composition of stable manure does not, alone, suffice to explain its remarkable efficacy and the difficulty of replacing it by any other material. The composition of manure of course differs not only with different animals but also with the different feeds consumed by them; but the average composition of farmyard manure is approximately given thus by Wolff and others:
| ANALYSES OF VARIOUS FARMYARD MANURES. | |||||
|---|---|---|---|---|---|
| 1. | 2. | 3. | 4. | 5. | |
| Water | 71.00 | 75.00 | 79.00 | 79.95 | 72.33 |
| Dry Matter | 29.00 | 25.00 | 21.00 | 20.05 | 27.67 |
| Ash ingredients | 4.40 | 5.80 | 6.50 | 5.87 | |
| Potash | 0.52 | 0.63 | 0.50 | 0.84[23] | 0.69 |
| Lime | 0.57 | 0.70 | 0.88 | 0.85 | |
| Magnesia | 0.14 | 0.18 | 0.18 | 0.14 | |
| Phosphoric acid | 0.21 | 0.26 | 0.30 | 0.40 | 0.30 |
| Ammonia | 0.02 | ||||
| Total Nitrogen | 0.45 | 0.50 | 0.58 | 0.78 | 0.46 |
1. Average composition of fresh farm manure (Wolff).
2. Average composition of moderately rotted farm manure (Wolff).
3. Average composition of very thoroughly rotted farm manure (Wolff).
4. Mixed cow and horse manure from a bed two feet thick, accumulated during the winter in a large covered yard, and packed solid by the tramping of cattle (The analysis by F. E. Furry).
5. “Box Manure,” consisting of mixed manure of bullocks, horses, and pigs (Way, Royal Agric. Soc. Journ., 1850, II., 769).