Rice, wheat, rye, barley and corn are more frequently employed than other grains. Wheat gives a malt which is as rich in diastase as barley. Barley and buckwheat are added to these in some proportions. Oats, owing to their high price, are rarely used. Rice, of all the grain is the most productive to the distillers, but on account of its value as a food is not much used for the production of alcohol, unless damaged. Corn is the cereal most largely used for the production of industrial alcohol.
Great care should be exercised in making choice of grain for fermentation where the best results are desired. Wheat should be farinaceous, heavy and dry. Barley should be free from chaff, quite fresh and in large uniform grains of a bright color (see Malting, [Chapter VI]).
Rice should be dull white in color, slightly transparent, without odor, and of a fresh, farinaceous taste.
The flour or farinaceous part of grain is composed of starch, gluten, albumen, mucilage, and some sugar. The following table gives the proportions of these substances in the commonest grains.
Under certain conditions the albumen or gluten in the grain has the power of converting starch into saccharine matter. This is better effected by an acid such as sulphuric acid, or by a diastase. This latter substance is a principle developed during the germination of all cereals but especially of barley. It has the property of reacting upon starchy matters, converting them first into a gummy substance called dextrine, and then into glucose or grape sugar, see [Chapter II].
The action of diastase upon starch or flour made into a paste is remarkable, 50 grains of diastase being sufficient to convert 220 lbs. (100 kilogrammes) of starch into glucose. The rapidity of this change depends on the quantity of water employed, and the degree of heat adopted in the operation.
TABLE IV.
Proportions of Starch, Gluten, Etc., in Principal Grains.
| Grains. | Starch. | Gluten and other Azotized Substances. | Dextrin, Glucose, and similar Substances. | Fatty Matter. | Cellulose. | Inorganic Salts. (Silica, Phosphates, &c.) |
| Wheat (average of five varieties) | 65.99 | 18.03 | 7.63 | 2.16 | 3.50 | 2.69 |
| Rye | 65.65 | 13.50 | 12.00 | 2.15 | 4.10 | 2.60 |
| Barley | 65.43 | 13.96 | 10.00 | 2.76 | 4.75 | 3.10 |
| Oats | 60.59 | 14.39 | 9.25 | 5.50 | 7.06 | 3.25 |
| Indian Corn | 67.55 | 12.50 | 4.00 | 8.80 | 5.90 | 1.25 |
| Rice | 89.15 | 7.05 | 1.00 | 0.80 | 1.10 | 0.90 |
Inasmuch as barley germinates very readily, and develops a larger proportion of diastase than any other grain, except wheat, it is generally used as a producer of diastase. Barley germinated according to proper methods is called malt, and its preparation is fully described in [Chapter VI].