Fig. 53.—Field’s Alcoholometer.
A quick, if not always very exact, method consists in determining the point at which the liquor boils. The boiling point of absolute alcohol being once determined, it is obvious that the more it is diluted with water the nearer will the boiling point of the mixture approach that of water; moreover, it has been proved that the presence of saccharine and other solid matters has but an almost inappreciable effect upon this point. Field’s alcoholometer, since improved by Ure, is based upon this principle. It is shown in Fig. [53], and consists, roughly speaking, of a cylindrical vessel A, to contain the spirit; this vessel is heated from beneath by a spirit lamp, which fits into the case B. A delicate thermometer C, the bulb of which is introduced into the spirit, is attached to a scale divided into 100 divisions, of which each represents one degree over-or under-proof. This method is liable to several small sources of error, but when a great many determinations have to be made, and speed is an object rather than extreme accuracy, this instrument becomes exceedingly useful. It does not answer well with spirits above proof, because the variation in their boiling points are so slight as not to be easily observed with accuracy. But for liquors under-proof, and especially for wines, beer, and other fermented liquors, it gives results closely approximating to those obtained by distillation, and quite accurate enough for all ordinary purposes. Strong liquors should therefore be tested with twice their bulk, and commercial spirits with an equal bulk, of water, the result obtained being multiplied by two or three, as the case may be.
Another very expeditious, but somewhat rough, method was invented by Geisler. It consists in measuring the tension of the vapor of the spirit, by causing it to raise a column of mercury in a closed tube. The very simple apparatus is shown in Fig. [54]. A is a small glass bulb, fitted with a narrow tube and stop-cock. This vessel is completely filled with the spirit, and is then screwed upon a long, narrow tube B, bent at one end and containing mercury. This tube is attached to a graduated scale showing the percentage of absolute alcohol above or below proof. To make the test the cock is opened, and the bulb, together with the lower part of the tube, is immersed in boiling water, which gradually raises the spirit to its boiling-point. When this is reached, the vapor forces the mercury up the tube, and, when stationary, the degree on the scale to which it has ascended gives directly the percentage of alcohol.
Fig. 54.—Geisler’s Apparatus.
Another method, which is not to be relied on for very weak liquors, but which answers well for cordials, wines, and strong ales, is that known as Brande’s method. The liquor is poured into a long, narrow glass tube, graduated centesimally, until it is half-filled. About 12 or 15 per cent. of subacetate of lead, or finely powdered litharge, is then added, and the whole is shaken until all the color is destroyed. Powdered anhydrous carbonate of potash is next added until it sinks undissolved in the tube, even after prolonged agitation. The tube is then allowed to rest, when the alcohol is observed to float upon the surface of the water in a well-defined layer. The quantity read off on the scale of the tube and doubled, gives the percentage by volume of alcohol in the original liquid. The whole operation may be performed in about five minutes, and furnishes reliable approximative results. In many cases it is necessary to add the lead salt for the purpose of decolorizing the liquid.
For the investigation of the amount of sugar in, or the concentration of the mash, or beer, a specially scaled hydrometer is used which is termed a saccharometer. Sugar possesses a higher degree of specific gravity than water, and hence it follows that the greater the amount of sugar in the mash the higher will be the specific gravity. The less the hydrometer sinks into the fluid the greater the amount of sugar present. Saccharometers are provided with thermometers whereby the reading may be corrected to a standard temperature, usually 59° F. The saccharometer is correct for solutions containing sugar alone but it is only approximately correct for mash liquor which contains a variety of other matters in variable quantities.