On studying the properties of the elements in a transformation series in connection with the ray emission which produced them, it was seen that these properties were determined in each case by the nature of the ray emitted from the preceding transformation product or parent element.
Atomic Weight Losses
Each alpha particle emitted means a loss of 4 in the atomic weight. This is the mass of a helium atom. Thus from uranium with an atomic weight of 238 to radium there is a loss of three alpha particles. Therefore, 12 must be subtracted from 238, leaving 226, which agrees closely with the atomic weight of radium as actually determined by the ordinary methods. Uranium X1, then, would have an atomic weight of 234 and that of ionium would be 230. The other intermediate elements, whose formation is due to the loss of beta particles only, show no decrease in atomic weight.
Lead the End Product
From uranium to lead there is a loss of 8 alpha particles, or 32 units in atomic weight. This would give for the final product an atomic weight of 206. The atomic weight of lead is 207.17. It is not at all certain that the final product of this series is ordinary lead. The facts are such that they would lead one to think that it is not. It is known only that the end product would probably be some element closely resembling lead chemically and hence difficult or impossible to separate from it. Several accurate determinations of lead coming from uranium minerals, which always carry this element and in an approximately definite ratio to the amount of uranium present, show atomic weights of 206.40; 206.36; and 206.54. Even the most rigid methods of purification fail to change these results. The lead in these minerals might therefore be considered as coming in the main from the disintegration of the uranium atom and, though chemically resembling lead, as being in reality a different element with different atomic weight.
Furthermore, in the thorium series 6 alpha particles are lost before reaching the end product, which again is perhaps the chemical analogue of lead. The atomic weight here should be 232 less 24, or 208. Determinations of the atomic weight of lead from thorite, a thorium mineral nearly free from uranium, gave 208.4.
The end product of the actinium series is also an element resembling lead, but both the beginning and ending of this series are still in obscurity.
Changes of Position in the Periodic System
The loss of 4 units in the atomic weight of an element on the expulsion of an alpha particle is accompanied by a change of chemical properties which removes the new element two groups toward the positive side in the Periodic System.
Thus ionium is so closely related to thorium and so resembles it chemically that it is properly classed along with thorium as a quadrivalent element in the fourth group. Ionium expels an alpha particle and becomes radium, which is a bivalent element resembling barium belonging to the second group. Radium then expels an alpha particle and becomes the gas, radium emanation, which is an analogue of argon and belongs to the zero group. Other instances might be cited which go to show that in all cases the loss of an alpha particle makes a change of two places toward the left or positive side of the System.