The denitrated fibres thus prepared very closely resemble silk in their lustre; they are not quite so soft and supple, nor are they in any way so strong as ordinary silk fibre of the same diameter.
Artificial silk can be dyed in the same manner as ordinary silk.
ACTION OF OXIDISING AGENTS ON CELLULOSE OR COTTON
Cellulose resists fairly well the action of weak oxidising agents; still too prolonged an action of weak oxidising agents has some influence upon the cotton fibre, and it may be worth while to point out the action of some bodies having an oxidising effect.
Nitric acid of about 1.15 specific gravity has little action in the cold, and only slowly on it when heated. The action is one of oxidation, the cellulose being transformed into a substance known as oxycellulose. This oxycellulose is white and flocculent. It tends to form gelatinous hydrates with water, and has a composition corresponding to the formula C6H10O6. It is soluble in a mixture of nitric and sulphuric acids, and on diluting this solution with water a tri-nitrate precipitates out. A weak solution of soda dissolves this oxycellulose with a yellow colour, while strong sulphuric acid forms a pink colouration. It is important to note that
nitric acid of the strength given does not convert all the cellulose into oxycellulose, but there are formed also carbonic and oxalic acids. When cotton is passed into strong solutions of bleaching powder and of alkaline hypochlorites and then dried, it is found to be tendered very considerably. This effect of bleaching powder was first observed some thirteen years ago by George Witz, who ascribed the tendering of the cotton to the formation of an oxycellulose. Although the composition of this particular oxycellulose so formed has not yet been ascertained, there is reason to think that it differs somewhat from the oxycellulose formed by the action of the weak nitric acid. A notable property of the oxycellulose now under consideration is its affinity for the basic coal-tar dyes, which it will absorb directly. The oxycellulose is soluble in alkaline solutions.
In the ordinary bleaching process there is considerable risk of the formation of oxycellulose by the employment of the bleaching solutions of too great a strength, or in allowing the goods to lie too long before the final washing off. The presence of any oxycellulose in bleached cotton may be readily determined by immersing it in a weak solution of Methylene blue, when, if there be any oxycellulose present, the fibre will take up some of the dye-stuff.
Permanganate of potash is a very powerful oxidising agent. On cellulose neutral solutions have but little action, either in the cold or when heated. They may, therefore, be used for the bleaching of cotton or other cellulose fibres.
Alkaline solutions of permanganate convert the cellulose into oxycellulose, which resembles the oxycellulose obtained by the action of the nitric acid.
Chromic acid, when used in the form of a solution, has but little action on cellulose. In the presence of mineral acids, and used warm or boiling, chromic acid oxidises cellulose into oxycellulose and other products.