The amount of vanillin was stated by Haarmann and Tiemann to be 1·69 per cent. in Mexican vanillin, from 1·9 to 2·48 in the Bourbon variety, and 2·75 in that from Java. The so-called Vanillon affords only 0·4 to 0·7 per cent. of vanillin.
From the above-mentioned ethereal solution (e), after it has been deprived of vanillin, vanillate of sodium may be removed by a dilute solution of carbonate of sodium. On acidulating the aqueous solution crystals of vanillic acid,
 | OCH₃ | |
| C₆H₃ | OH. | |
| COOH |
are precipitated. If the ether of the solution (e), after it has been treated with carbonate of sodium, is allowed to evaporate, a mixture of fatty substances and a resin are obtained. The latter has a peculiar odour, somewhat suggestive of castoreum; vanillic acid is almost inodorous.
Leutner (1872) also found in vanilla fatty and waxy matter 11·8, resin 4·0, gum and sugar 16·5 per cent.; and obtained by incineration of the drug 4·6 per cent. of ash.
Production and Commerce—The chief seats of vanilla-production in Mexico are the slopes of the Cordilleras, north-west of Vera Cruz, the centre of the culture being Jicaltepec, in the vicinity of Nautla.[2453] The finest specimens were contributed in 1878 to the Paris Exhibition from Agapito, Fonticilla, Misantla, Papantla, also from Teziutlan, province of Puebla. There are likewise “Baynillales,” plantations of vanilla, on the western declivity of the Cordilleras in the State of Oaxaca, and in lesser quantity in those of Tabasco, Chiapas, and Yucatan. The eastern parts of Mexico exported in 1864, by way of Vera Cruz and Tampico, about 20,000 kilo. of vanilla, chiefly to Bordeaux. Since then the production seems to have much declined, the importation into France having been only 6,896 kilo. in 1871, and 1,938 in 1872.[2454]
The cultivation of vanilla in the small French colony of Réunion or Bourbon (40 miles long by 27 miles broad), introduced by Marchant in 1817 from Mauritius, has of late been very successful, notwithstanding many difficulties occasioned by the severe cyclones which sweep periodically over the island, and by microscopic fungi which greatly injured the plant. In 1849 the export of vanilla from Réunion was 3 kilogrammes, in 1877 it reached 30,973 kilogrammes. The neighbouring island of Mauritius also produces vanilla, of which it shipped in 1872 7,139 lbs., in 1877 the quantity was 20,481 lbs. There is likewise a very extensive cultivation of vanilla in Java.
Vanilla comes into the market chiefly by way of France, which country, according to the official statistics, imported in 1871, 29,914 kilo. (65,981 lbs.); in 1872, 26,587 (58,643 lbs.); in 1874 that quantity amounted to 34,906 kilo.
Uses—Vanilla has long ceased to be used in medicine, at least in this country, but is often sold by druggists for flavouring chocolate, ices, creams, and confectionery.