Metals of the Alkalies.
Potassium has a bright, almost silvery, appearance, and is so greatly attracted by oxygen that it cannot be kept anywhere if that element be present—not even in water, for combustion will immediately ensue on water; and in air it is rapidly tarnished. It burns with a beautiful violet colour, and a very pretty experiment may easily be performed by throwing a piece upon a basin of water. The fragment combines with the oxygen of the water, the hydrogen is evolved, and burns, and the potassium vapour gives the gas its purple or violet colour. The metal can be procured by pulverizing carbonate of potassium and charcoal, and heating them in an iron retort. The vapour condenses into globules in the receiver, which is surrounded by ice in a wire basket. It must be collected and kept in naphtha, or it would be oxidised. Potassium was first obtained by Sir Humphrey Davy in 1807. Potash is the oxide of potassium, and comes from the “ashes” of wood.
Fig. 397.—Preparation of potassium.
The compounds of potassium are numerous, and exist in nature, and by burning plants we can obtain potash (“pearlash”). Nitrate of potassium, or nitre (saltpetre), (KNO3), is a very important salt. It is found in the East Indies. It is a constituent of gunpowder, which consists of seventy-five parts of nitre, fifteen of charcoal, and ten of sulphur. The hydrated oxide of potassium, or “caustic potash” (obtained from the carbonate), is much used in soap manufactories. It is called “caustic” from its property of cauterizing the tissues. Iodide, bromide, and cyanide of potassium, are used in medicine and photography.
Fig. 398.—Machine for cutting soap in bars.
Soap is made by combining soda (for hard soap), or potash (for soft soap), with oil or tallow. Yellow soap has turpentine, and occasionally palm oil, added. Oils and fats combine with metallic oxides, and oxide of lead with olive oil and resin forms the adhesive plaister with which we are all familiar when the mixture is spread upon linen. Fats boiled with potash or soda make soaps; the glycerine is sometimes set free and purified as we have it. Sometimes it is retained for glycerine soap. Fancy soap is only common soap coloured. White and brown Windsor are the same soap—in the latter case browned to imitate age! Soap is quite soluble in spirits, but in ordinary water it is not so greatly soluble, and produces a lather, owing to the lime in the water being present in more or less quantity, to make the water more or less “hard.”
Fig. 399.—Soap-boiling house.