| Stamp | Stamper | Pilum |
| Stamp-stem | Lifter | Pilum |
| Shoes | Stamp-heads | Capita |
| Mortar-box | Box | Capsa |
| Cam-shaft | Barrell | Axis |
| Cams | Caps | Dentes |
| Tappets | Tongues | Pili dentes |
| Screen | Crate | Laminae foraminum plenae |
| Settling pit | Catchers | Lacus |
| Jigging sieve | Dilleugher | Cribrum angustum |
[2] Agricola uses four Latin verbs in connection with heat operations at temperatures under the melting point: Calefacio, uro, torreo, and cremo. The first he always uses in the sense of "to warm" or "to heat," but the last three he uses indiscriminately in much the same way as the English verbs burn, roast, and calcine are used; but in general he uses the Latin verbs in the order given to indicate degrees of heat. We have used the English verbs in their technical sense as indicated by the context.
It is very difficult to say when roasting began as a distinct and separate metallurgical step in sulphide ore treatment. The Greeks and Romans worked both lead and copper sulphides (see note on p. [391], and note on p. [403]), but neither in the remains of old works nor in their literature is there anything from which satisfactory details of such a step can be obtained. The Ancients, of course, understood lime-burning, and calcined several salts to purify them or to render them more caustic. Practically the only specific mention is by Pliny regarding lead ores (see p. [391]). Even the statement of Theophilus (1050-1100, A.D.), may refer simply to rendering ore more fragile, for he says (p. 305) in regard to copper ore: "This stone dug up in abundance is placed upon a pile and burned (comburitur) after the manner of lime. Nor does it change colour, but loses its hardness and can be broken up, and afterward it is smelted." The Probierbüchlein casually mentions roasting prior to assaying, and Biringuccio (III, 2) mentions incidentally that "dry and ill-disposed ores before everything must be roasted in an open oven so that the air can get in." He gives no further information; and therefore this account of Agricola's becomes practically the first. Apparently roasting, as a preliminary to the treatment of copper sulphides, did not come into use in England until some time later than Agricola, for in Col. Grant Francis' "Smelting of Copper in the Swansea District" (London, 1881, p. 29), a report is set of the "Doeinges of Jochim Ganse"—an imported German—at the "Mynes by Keswicke in Cumberland, A.D., 1581," wherein the delinquencies of the then current practice are described: "Thei never coulde, nether yet can make (copper) under XXII. tymes passinge thro the fire, and XXII. weekes doeing thereof ane sometyme more. But now the nature of these IX. hurtfull humors abovesaid being discovered and opened by Jochim's way of doeing, we can, by his order of workeinge, so correct theim, that parte of theim beinge by nature hurtfull to the [Pg 268]copper in wasteinge of it, ar by arte maide freindes, and be not onely an encrease to the copper, but further it in smeltinge; and the rest of the other evill humors shalbe so corrected, and their humors so taken from them, that by once rosteinge and once smeltinge the ure (which shalbe done in the space of three dayes), the same copper ure shall yeeld us black copper." Jochim proposed by 'rostynge' to be rid of "sulphur, arsineque, and antimony."
[Pg 273][3] Orpiment and realgar are the red and yellow arsenical sulphides. (See note on p. [111]).
[4] Cadmia bituminosa. The description of this substance by Agricola, given below, indicates that it was his term for the complex copper-zinc-arsenic-cobalt minerals found in the well-known, highly bituminous, copper schists at Mannsfeld. The later Mineralogists, Wallerius (Mineralogia, Stockholm, 1747), Valmont De Bomare (Mineralogie, Paris, 1762), and others assume Agricola's cadmia bituminosa to be "black arsenic" or "arsenic noir," but we see no reason for this assumption. Agricola's statement (De Nat. Foss., p. 369) is "... the schistose stone dug up at the foot of the Melibocus Mountains, or as they are now called the Harz (Hercynium), near Eisleben, Mannsfeld, and near Hettstedt, is similar to spinos (a bituminous substance described by Theophrastus), if not identical with it. This is black, bituminous, and cupriferous, and when first extracted from the mine it is thrown out into an open space and heaped up in a mound. Then the lower part of the mound is surrounded by faggots, on to which are likewise thrown stones of the same kind. Then the faggots are kindled and the fire soon spreads to the stones placed upon them; by these the fire is communicated to the next, which thus spreads to the whole heap. This easy reception of fire is a characteristic which bitumen possesses in common with sulphur. Yet the small, pure and black bituminous ore is distinguished from the stones as follows: when they burn they emit the kind of odour which is usually given off by burning bituminous coal, and besides, if while they are burning a small shower of rain should fall, they burn more brightly and soften more quickly. Indeed, when the wind carries the fumes so that they descend into nearby standing waters, there can be seen floating in it something like a bituminous liquid, either black, or brown, or purple, which is sufficient to indicate that those stones were bituminous. And that genus of stones has been recently found in the Harz in layers, having occasionally gold-coloured specks of pyrites adhering to them, representing various flat sea-fish or pike or perch or birds, and poultry cocks, and sometimes salamanders."
[Pg 274][5] Atramentum sutorium rubrum. Literally, this would be red vitriol. The German translation gives rot kupferwasser, also red vitriol. We must confess that we cannot make this substance out, nor can we find it mentioned in the other works of Agricola. It may be the residue from leaching roasted pyrites for vitriol, which would be reddish oxide of iron.
[6] The statement "elsewhere" does not convey very much more information. It is (De Nat. Fos., p. 253): "When Goslar pyrites and Eisleben (copper) schists are placed on the pyre and roasted for the third time, they both exude a certain substance which is of a greenish colour, dry, rough, and fibrous (tenue). This substance, like asbestos, is not consumed by the fire. The schists exude it more plentifully than the pyrites." The Interpretatio gives federwis, as the German equivalent of amiantus (asbestos). This term was used for the feathery alum efflorescence on aluminous slates.
[Pg 278][7] Bearing in mind that bituminous cadmia contained arsenical-cobalt minerals, this substance "resembling pompholyx" would probably be arsenic oxide. In De Natura Fossilium (p. 368). Agricola discusses the pompholyx from cadmia at length and pronounces it to be of remarkably "corrosive" quality. (See also note on p. [112].)
[Pg 279][8] Historical Note on Crushing and Concentration of Ores. There can be no question that the first step in the metallurgy of ores was direct smelting, and that this antedates human records. The obvious advantages of reducing the bulk of the material to be smelted by the elimination of barren portions of the ore, must have appealed to metallurgists at a very early date. Logically, therefore, we should find the second step in metallurgy to be concentration in some form. The question of crushing is so much involved with concentration that we have not endeavoured to keep them separate. The earliest indication of these processes appears to be certain inscriptions on monuments of the IV Dynasty (4,000 B.C.?) depicting gold washing (Wilkinson, The Ancient Egyptians, London, 1874, II, p. 137). Certain stelae of the XII Dynasty (2,400 B.C.) in the British Museum (144 Bay 1 and 145 Bay 6) refer to gold washing in the Sudan, and one of them appears to indicate the working of gold ore as distinguished from alluvial. The first written description of the Egyptian methods—and probably that reflecting the most ancient technology of crushing and concentration—is that of Agatharchides, a Greek geographer of the second Century B.C. This work is lost, but the passage in question is quoted by Diodorus Siculus (1st Century B.C.) and by Photius (died 891 A.D.). We give Booth's translation of Diodorus (London, 1700, p. 89), slightly amended: "In the confines of Egypt and the neighbouring countries of Arabia and Ethiopia there is a place full of rich gold mines, out of which with much cost and pains of many labourers gold is dug. The soil here is naturally black, but in the body of the earth run many white veins, shining like white marble, surpassing in lustre all other bright things. Out of these laborious mines, those appointed overseers cause the gold to be dug up by the labour of a vast multitude of people. For the Kings of Egypt condemn to these mines notorious criminals, captives taken in war, persons sometimes falsely accused, or against whom the King is incens'd; and not only they themselves, but sometimes all their [Pg 280]kindred and relations together with them, are sent to work here, both to punish them, and by their labour to advance the profit and gain of the Kings. There are infinite numbers upon these accounts thrust down into these mines, all bound in fetters, where they work continually, without being admitted any rest night or day, and so strictly guarded that there is no possibility or way left to make an escape. For they set over them barbarians, soldiers of various and strange languages, so that it is not possible to corrupt any of the guard by discoursing one with another, or by the gaining insinuations of familiar converse. The earth which is hardest and full of gold they soften by putting fire under it, and then work it out with their hands. The rocks thus soften'd and made more pliant and yielding, several thousands of profligate wretches break in pieces with hammers and pickaxes. There is one artist that is the overseer of the whole work, who marks out the stone, and shows the labourers the way and manner how he would have it done. Those that are the strongest amongst them that are appointed to this slavery, provided with sharp iron pickaxes, cleave the marble-shining rock by mere force and strength, and not by arts or sleight-of-hand. They undermine not the rock in a direct line, but follow the bright shining vein of the mine. They carry lamps fastened to their foreheads to give them light, being otherwise in perfect darkness in the various windings and turnings wrought in the mine; and having their bodies appearing sometimes of one colour and sometimes of another (according to the nature of the mine where they work) they throw the lumps and pieces of the stone cut out of the rock upon the floor. And thus they are employed continually without intermission, at the very nod of the overseer, who lashes them severely besides. And there are little boys who penetrate through the galleries into the cavities and with great labour and toil gather up the lumps and pieces hewed out of the rock as they are cast upon the ground, and carry them forth and lay them upon the bank. Those that are over thirty years of age take a piece of the rock of such a certain quantity, and pound it in a stone mortar with iron pestles till it be as small as a vetch; then those little stones so pounded are taken from them by women and older men, who cast them into mills that stand together there near at hand in a long row, and two or three of them being employed at one mill they grind a certain measure given to them at a time, until it is as small as fine meal. No care at all is taken of the bodies of these poor creatures, so that they have not a rag so much as to cover their nakedness, and no man that sees them can choose but commiserate their sad and deplorable condition. For though they are sick, maimed, or lame, no rest nor intermission in the least is allowed them; neither the weakness of old age, nor women's infirmities are any plea to excuse them; but all are driven to their work with blows and cudgelling, till at length, overborne with the intolerable weight of their misery, they drop down dead in the midst of their insufferable labours; so that these miserable creatures always expect the future to be more terrible than even the present, and therefore long for death as far more desirable than life.
"At length the masters of the work take the stone thus ground to powder, and carry it away in order to perfect it. They spread the mineral so ground upon a broad board, somewhat sloping, and pouring water upon it, rub it and cleanse it; and so all the earthy and drossy part being separated from the rest by the water, it runs off the board, and the gold by reason of its weight remains behind. Then washing it several times again, they first rub it lightly with their hands; afterward they draw off any earthy and drossy matter with slender sponges gently applied to the powdered dust, till it be clean, pure gold. At last other workmen take it away by weight and measure, and these put it into earthen pots, and according to the quantity of the gold in every pot they mix with it some lead, grains of salt, a little tin and barley bran. Then, covering every pot close, and carefully daubing them over with clay, they put them in a furnace, where they abide five days and nights together; then after a convenient time that they have stood to cool, nothing of the other matter is to be found in the pots but only pure, refined gold, some little thing diminished in the weight. And thus gold is prepared in the borders of Egypt, and perfected and completed with so many and so great toils and vexations. And, therefore, I cannot but conclude that nature itself teaches us, that as gold is got with labour and toil, so it is kept with difficulty; it creates everywhere the greatest cares; and the use of it is mixed both with pleasure and sorrow."