De Re Metallica, Translated from the First Latin Edition of 1556

by Georg Agricola

The cement should be placed, alternately with the gold, in new and clean pots in which no water has ever been poured. In the bottom the cement is levelled with an iron implement, and afterward the gold granules or leaves are placed one against the other, so that they may touch it on all sides; then, again, a handful of the cement, or more if the pots are large, is thrown in and levelled with an iron implement; the granules and leaves are laid over this in the same manner, and this is repeated until the pot is filled. Then it is covered with a lid, and the place where they join is smeared over with artificial lute, and when this is dry the pots are placed in the furnace.

The gold granules or leaves and the cement, alternately placed in the pots, are heated by a gentle fire, gradually increasing for twenty-four hours, if the furnace was heated for two hours before the full pots were stood in it, and if this was not done, then for twenty-six hours. The fire should be increased in such a manner that the pieces of gold and the cement, in which is the potency to separate the silver and copper from the gold, may not melt, for in this case the labour and cost will be spent in vain; therefore, it is ample to have the fire hot enough that the pots always remain red. After so many hours all the burning wood should be drawn out of the furnace. Then the refractory bricks or tiles are removed from the top of the furnace, and the glowing pots are taken out with the tongs. The lids are removed, and if there is time it is well to allow the gold to cool by itself, for then there is less loss; but if time cannot be spared for that operation, the pieces of gold are immediately placed separately into a wooden or bronze vessel of water and gradually quenched, lest the cement which absorbs the silver should exhale it. The pieces of gold, and the cement adhering to them, when cooled or quenched, are rolled with a little mallet so as to crush the lumps and free the gold from the cement. Then they are sifted by a fine sieve, which is placed over a bronze vessel; in this manner the cement containing the silver or the copper or both, falls from the sieve into the bronze vessel, and the gold granules or leaves remain on it. The gold is placed in a vessel and again rolled with the little mallet, so that it may be cleansed from the cement which absorbs silver and copper.

The particles of cement, which have dropped through the holes of the sieve into the bronze vessel, are washed in a bowl, over a wooden tub, being shaken about with the hands, so that the minute particles of gold which have fallen through the sieve may be separated. These are again washed in a little vessel, with warm water, and scrubbed with a piece of wood or a twig broom, that the moistened cement may be detached. Afterward all the gold is again washed with warm water, and collected with a bristle brush, and should be washed in a copper full of holes, under which is placed a little vessel. Then it is necessary to put the gold on an iron plate, under which is a vessel, and to wash it with warm water. Finally, it is placed in a bowl, and, when dry, the granules or leaves are rubbed against a touchstone at the same time as a touch-needle, and considered carefully as to whether they be pure or alloyed. If they are not pure enough, the granules or the leaves, together with the cement which attracts silver and copper, are arranged alternately in layers in the same manner, and again heated; this is done as often as is necessary, but the last time it is heated as many hours as are required to cleanse the gold.

Some people add another cement to the granules or leaves. This cement lacks the ingredients of metalliferous origin, such as verdigris and vitriol, for if these are in the cement, the gold usually takes up a little of the base metal; or if it does not do this, it is stained by them. For this reason some very rightly never make use of cements containing these things, because brick dust and salt alone, especially rock salt, are able to extract all the silver and copper from the gold and to attract it to themselves.

It is not necessary for coiners to make absolutely pure gold, but to heat it only until such a fineness is obtained as is needed for the gold money which they are coining.

The gold is heated, and when it shows the necessary golden yellow colour and is wholly pure, it is melted and made into bars, in which case they are either prepared by the coiners with chrysocolla, which is called by the Moors borax, or are prepared with salt of lye made from the ashes of ivy or of other salty herbs.

The cement which has absorbed silver or copper, after water has been poured over it, is dried and crushed, and when mixed with hearth-lead and de-silverized lead, is smelted in the blast furnace. The alloy of silver and lead, or of silver and copper and lead, which flows out, is again melted in the cupellation furnace, in order that the lead and copper may be separated from the silver. The silver is finally thoroughly purified in the refining furnace, and in this practical manner there is no silver lost, or only a minute quantity.

There are besides this, certain other cements[20] which part gold from silver, composed of sulphur, stibium and other ingredients. One of these compounds consists of half an uncia of vitriol dried by the heat of the fire and reduced to powder, a sixth of refined salt, a third of stibium, half a libra of prepared sulphur (not exposed to the fire), one sicilicus of glass, likewise one sicilicus of saltpetre, and a drachma of sal-ammoniac.[21] The sulphur is prepared as follows: it is first crushed to powder, then it is heated for six hours in sharp vinegar, and finally poured into a vessel and washed with warm water; then that which settles at the bottom of the vessel is dried. To refine the salt it is placed in river water and boiled, and again evaporated. The second compound contains one libra of sulphur (not exposed to fire) and two librae of refined salt. The third compound is made from one libra of sulphur (not exposed to the fire), half a libra of refined salt, a quarter of a libra of sal-ammoniac, and one uncia of red-lead. The fourth compound consists of one libra each of refined salt, sulphur (not exposed to the fire) and argol, and half a libra of chrysocolla which the Moors call borax. The fifth compound has equal proportions of sulphur (not exposed to the fire), sal-ammoniac, saltpetre, and verdigris.

The silver which contains some portion of gold is first melted with lead in an earthen crucible, and they are heated together until the silver exhales the lead. If there was a libra of silver, there must be six drachmae of lead. Then the silver is sprinkled with two unciae of that powdered compound and is stirred; afterward it is poured into another crucible, first warmed and lined with tallow, and then violently shaken. The rest is performed according to the process I have already explained.