Let a body be supposed to have its integrant parts separated from each other by some fluid; if a part of this fluid be taken away, these integrant parts will approach together: and, as the quantity of intervening fluid diminishes, they will at last touch and unite. They may also unite when they come so near to each other, that their mutual tendency shall be capable of overcoming the distance betwixt them. If, besides, they have time and liberty to unite with each other by the sides most disposed to this union, they will form masses of a figure constantly uniform and similar. For the same reason, when the interposed fluid is hastily taken away, so that the integrant parts shall be approximated, and be brought into contact before they have taken the position of their natural tendency, then they will join confusedly by such sides as chance presents to them; they will, in such circumstances, form solid masses, whose figures will not be determinate, but irregular and various.
Different salts assume different figures in crystallization, and are, by these means, easily distinguished from one another. But besides the large crystals produced in this way, each salt is capable of producing a very different appearance of the crystalline kind, when only a drop of the saline solution is made use of, and the crystallization viewed through a microscope. For our knowledge of this species of crystallization, we are indebted to Mr. Henry Baker, who was presented by the Royal Society with a gold medal for the discovery, in the year 1744. These microscopical crystals he distinguishes from the larger ones by the name of configurations; but this term seems inaccurate, and the distinction may be properly preserved by calling the large ones the COMMON, and the small ones the MICROSCOPICAL, crystals of the salt.
It has not yet been shewn by any writer on the subject, why salts should assume any regular figure, much less why every one should have a form peculiar to itself. Sir Isaac Newton endeavoured to account for this, by supposing the particles of salt to be diffused through the solvent fluid, at equal distances from each other; and that then the power of the attraction between the saline particles could not fail to bring them together in regular figures, as soon as the diminution of heat suffered them to act on each other. But it is certain some other agent must be concerned in this operation, besides mere attraction, otherwise all salts would crystallize in the same manner. Others have, therefore, had recourse to some kind of polarity in the particles of each salt, which determined them to arrange themselves in such a certain form; but unless we give a reason for this polarity, we only explain crystallization by itself. One thing seems to have been overlooked by those who have endeavoured to investigate this subject, namely, that the saline particles do not only attract one another, but they also attract some part of the water which dissolves them.
Did they only attract each other, the salt, instead of crystallizing, would fall to the bottom as a powder; whereas, a saline crystal is composed of salt and water, as certainly as the body of an animal is composed of flesh and blood, or a vegetable of solid matter and sap; if a saline crystal be deprived of its aqueous part, it will as certainly lose its crystalline form, as if it were deprived of the saline part. It is, therefore, not improbable, that crystallization is a species of vegetation, and is accomplished by the same powers to which the growth of plants and animals is to be ascribed. Some kinds of crystallization resemble vegetation so much, that we can scarce avoid attributing them to the same cause.
It has been imagined, that all the great operations in nature may be reduced to two principles, those of crystallization and organization; but that often they are so concealed, as to be invisible. Hence crystallized substances have been frequently mistaken for organized ones, and vice versa. They differ, however, essentially in their growth and origin. Organized beings spring from a germ, in which all the essential parts are concentrated, and they grow by intusception; whereas crystallized substances increase by the successive apposition of certain molecules of a determined figure, which unite in one common mass. Thus crystallized beings do not grow, properly speaking, though their substance is augmented, they are not preformed, but formed daily.
The phænomena of crystallization have much engaged the attention of modern chemists, and a vast number of experiments has been made with a view to determine exactly the different figures assumed by salts in passing from a fluid to a solid form. It does not, however, appear, from all that has yet been done, that any certain rule can be laid down in these cases, as the figure of saline crystals may be varied by the slightest circumstances. Thus, sal ammoniac, when prepared by a mixture of pure volatile alkali with spirit of salt, shoots into crystals resembling feathers; but if, instead of a pure alkali, we make use of one just distilled from bones, and containing a great quantity of animal oil, we shall, after some crystallizations of the feathery kind, obtain the very same salt in the form of cubes.
Such salts as are sublimeable crystallize not only in the aqueous way by solution and evaporation, but also by sublimation; and the difference betwixt the figures of these crystals is often very remarkable. Thus, sal ammoniac, by sublimation never exhibits any appearance of feathery crystals, but always forms cubes or parallelopipeds. This method of crystallizing salts by sublimation has not as yet been investigated by chemists; nor indeed does the subject seem capable of investigation without much trouble, as the least augmentation of the heat beyond the proper degree would make the crystals run into a solid cake, while a diminution of it would cause them to fall into powder. In aqueous solutions, too, the circumstances which determine the shapes of the crystals are innumerable; and the degree of heat, the quantity of salt contained in the liquor, nay, the quantity of the liquor itself, and the various constitutions of the atmosphere at the time of crystallization, often occasion such differences as seem quite unaccountable and surprizing.
Mr. Bergman has given a dissertation on the various forms of crystals; which, he observes, always resemble geometrical figures more or less regular. Their variety at first appears infinite; but by a careful examination it will be found, that a great number of crystals, seemingly very different from each other, may be produced by the combination of a small number of original figures, which therefore he thinks may be called primitive. On this principle he explains the formation of the crystalline gems, as well as salts.[145]
[145] Encycl. Britan. Vol. V. p. 583.
It has been already shewn, [page 163], how to prepare the various salts for microscopical observations. The beautiful crystallizations represented in [Plates XXXI.] and [XXXII.] were produced in the manner there described.