The Magician's Own Book, or, the Whole Art of Conjuring / Being a complete hand-book of parlor magic, and containing over one thousand optical, chemical, mechanical, magnetical, and magical experiments, amusing transmutations, astonishing sleights and subtleties, celebrated card deceptions, ingenious tricks with numbers, curious and entertaining puzzles, together with all the most noted tricks of modern performers.

by George Arnold; Frank Cahill

Again, many animal and vegetable substances consist for the most part of carbon or charcoal, united with oxygen and hydrogen in the proportion which forms water. Now oil of vitriol (strong sulphuric acid) has so powerful an affinity, or so great a thirst for water, that it will abstract it from almost any body in which it exists; if you then pour some of this acid on a lump of sugar, or place a chip of wood in it, the sugar or wood will speedily become quite black, or be charred, as it is called, in consequence of the oxygen and hydrogen being removed by the sulphuric acid, and only the carbon, or charcoal, left.

When Cleopatra dissolved pearls of wondrous value in vinegar, she was exhibiting unwittingly an instance of chemical elective affinity; the pearl being simply carbonate of lime, which was decomposed by the greater affinity or fondness of lime for its new acquaintance, (the acetic acid of the vinegar,) than for the carbonic acid, with which it had been united all its life; an example of inconstancy in strong contrast with the conduct of its owner, who chose death rather than become the mistress of her lover's conqueror.

EXPERIMENTS ON COMBUSTION.

Into an ordinary wine bottle put some pieces of granulated zinc, and pour on them a mixture of sulphuric acid and water, in the proportion of about one part of acid to four of water, then close the bottle with a cork having a hole bored through the middle, in which a piece of glass tube is inserted; wait some minutes that the atmospheric air in the bottle may be expelled by the hydrogen gas set free by the decomposition of the water, then apply a lighted taper to the end of the tube, when the gas will inflame, giving out so little light as to be barely visible by daylight, but producing so intense a heat that a piece of platinum wire instantly becomes white hot when held in the flame. If you hold a glass tumbler inverted over the flame, it becomes covered with minute drops of water, the result of the union of the hydrogen with the oxygen of the air, and in this case water is the only product.

If a piece of charcoal, which is pure carbon or nearly so, be ignited, and introduced into a jar, containing oxygen or common atmospheric air, the product will be carbonic acid gas only. As most combustible bodies contain both carbon and hydrogen, the result of their combination is carbonic acid and water. This is the case with the gas used for illumination; and in order to prevent the water so produced from spoiling goods in shops, various plans have been devised for carrying off the water when in the state of steam. This is generally accomplished by suspending over the burners glass bells, communicating with tubes opening into the chimney, or passing outside the house.

To show that oxygen, or some equivalent, is necessary for the support of combustion, fix two or three pieces of wax taper on flat pieces of cork, and set them floating on water in a soup-plate, light them, and invert over them a glass jar; as they burn, the heat produced may perhaps at first expand the air so as to force a small quantity out of the jar, but the water will soon rise in the jar, and continue to do so until the tapers expire, when you will find that a considerable portion of the air has disappeared, and what remains will no longer support flame; that is, the oxygen has been converted partly into water, and partly into carbonic acid gas, by uniting with the carbon and hydrogen of which the taper consists, and the remaining air is principally nitrogen, with some carbonic acid: the presence of the latter may be proved by decanting some of the remaining air into a bottle, and then shaking some lime-water with it, which will absorb the carbonic acid and form chalk.

Into an ale-glass, two thirds full of water at about 140°, drop one or two pieces of phosphorus about the size of peas, and they will remain unaltered. Then take a bladder containing oxygen gas, to which is attached a stop-cock and a long fine tube; pass the end of the tube to the bottom of the water, turn the stop-cock, and press the bladder gently; as the gas reaches the phosphorus it will take fire, and burn under the water with a brilliant flame, filling the glass with brilliant flashes of light dashing through the water.

Into another glass put some cold water; introduce carefully some of the salt called chlorate of potassa, upon that drop a piece of phosphorus; then let some strong sulphuric acid (oil of vitriol) trickle slowly down the side of the glass, or introduce it by means of a dropping bottle. As soon as it touches the salt it decomposes it, and liberates a gas which ignites the phosphorus, producing much the same appearance as in the last experiment.

Into the half of a broken phial put some chlorate of potassa, and pour in some oil of vitriol. The phial will soon be filled with a heavy gas of a deep yellow color. Tie a small test tube at right angles to the end of a stick not less than a yard long, put a little ether into the tube, and pour it gently into the phial of gas, when an instantaneous explosion will take place, and the ether will be set on fire. This experiment should be performed in a place where there are no articles of furniture to be damaged, as the ingredients are often scattered by the explosion, and the oil of vitriol destroys all animal and vegetable substances.