108. Peganum Harmala,
The seeds of which afford a red colour, has been investigated by the French, but described as inferior to existing reds both in brilliancy and stability.
109. Persulphomolybdates.
The metallic compounds formed by the combination of persulphomolybdic acid with a base are pulverulent, in many cases of a red colour, and for the most part insoluble in water. With barium, the acid furnishes a yellowish-red powder, insoluble in, but made denser by water, which imparts to it a cinnabar colour. With calcium it is said to yield a scarlet, sparingly soluble in water. With chromium, uranium, lead, platinum, and copper, it gives a dark red; that from the last metal turning brown when collected on a filter. It likewise produces reds with zinc, cadmium, iron, mercury, and tin; of which the last is slightly soluble in water.
Molybdenum being a rare metal, and persulphomolybdate of potash, the salt used in the foregoing reactions, difficult to prepare, it is unlikely that the colours named will rank among the pigments of this generation. Nevertheless, as we have observed before, such fancy products should not be altogether ignored, it being quite as well to have some knowledge of our resources, even though those resources be not at present available. All the rare metals afford coloured compounds: tantalum, niobium, pelopium, vanadium, tellurium, titanium, yttrium, lanthanum, didymium, glucinum, cerium, thorinum, zirconium, palladium, rhodium, iridium, ruthenium, osmium, indium, thallium, &c.; and it is just possible that some of these may one day scrape acquaintance with the palette.
110. Red Chalk,
The colouring matter of which is sesquioxide of iron, is used as a crayon. Some specimens are excessively hard, so much so that they are difficult to crush, even in an iron mortar; while others have the consistence of the softest iron-ochres. They vary too in tint from a fawn colour to the softest brick-red, occasionally being almost as bright as a mixture of equal weights of vermilion and Venetian red. The amount of iron oxide present has been found to range from four to thirty-seven per cent, according to the depth and hardness of the samples. When a specimen of red chalk tolerably rich, but not too rich, in iron oxide is finely powdered and strongly ignited, it offers a remarkable change of colour, becoming a dull sage-green. Perhaps this, if it were permanent, might prove useful in foliage tints.
111. Red Precipitate,
Or mercuric oxide, may be obtained either of a brick-red or orange-yellow colour. It is destroyed by impure air, and on exposure to sunshine gradually turns black, being superficially decomposed into oxygen and metallic mercury or mercurous oxide.