In 1859 Kirchoff, on repeating Frauenhofer’s experiment, found that, if a spirit lamp with salt in the flame were placed in the path of the light, the black D line is intensified. He also found that, if he used a limelight instead of the sunlight and passed it through the flame with salt, the spectrum showed the D line black; or the vapour of sodium absorbs the same light that it radiates. This proved to him the existence of sodium in the sun’s atmosphere.[[4]] Iron, calcium, and other elements were soon detected in the same way.
Extensive laboratory researches (still incomplete) have been carried out to catalogue (according to their wave-length on the undulatory theory of light) all the lines of each chemical element, under all conditions of temperature and pressure. At the same time, all the lines have been catalogued in the light of the sun and the brighter of the stars.
Another method of obtaining spectra had long been known, by transmission through, or reflection from, a grating of equidistant lines ruled upon glass or metal. H. A. Rowland developed the art of constructing these gratings, which requires great technical skill, and for this astronomers owe him a debt of gratitude.
In 1842 Doppler[[5]] proved that the colour of a luminous body, like the pitch or note of a sounding body, must be changed by velocity of approach or recession. Everyone has noticed on a railway that, on meeting a locomotive whistling, the note is lowered after the engine has passed. The pitch of a sound or the colour of a light depends on the number of waves striking the ear or eye in a second. This number is increased by approach and lowered by recession.
Thus, by comparing the spectrum of a star alongside a spectrum of hydrogen, we may see all the lines, and be sure that there is hydrogen in the star; yet the lines in the star-spectrum may be all slightly displaced to one side of the lines of the comparison spectrum. If towards the violet end, it means mutual approach of the star and earth; if to the red end, it means recession. The displacement of lines does not tell us whether the motion is in the star, the earth, or both. The displacement of the lines being measured, we can calculate the rate of approach or recession in miles per second.
In 1868 Huggins[[6]] succeeded in thus measuring the velocities of stars in the direction of the line of sight.
In 1873 Vogel[[7]] compared the spectra of the sun’s East (approaching) limb and West (receding) limb, and the displacement of lines endorsed the theory. This last observation was suggested by Zöllner.
FOOTNOTES:
[1] In the Encyclopaedia Britannica, article “Telescope,” and in Grant’s Physical Astronomy, good reasons are given for awarding the honour to Lipperhey.